BR0016215A - Processo para a isomerização de álcoois alila - Google Patents
Processo para a isomerização de álcoois alilaInfo
- Publication number
- BR0016215A BR0016215A BR0016215-9A BR0016215A BR0016215A BR 0016215 A BR0016215 A BR 0016215A BR 0016215 A BR0016215 A BR 0016215A BR 0016215 A BR0016215 A BR 0016215A
- Authority
- BR
- Brazil
- Prior art keywords
- amino
- alcohols
- allyl alcohols
- isomerization
- ligands
- Prior art date
Links
- 150000004808 allyl alcohols Chemical class 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- 238000006317 isomerization reaction Methods 0.000 title abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 5
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- 239000001301 oxygen Substances 0.000 abstract 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 3
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 abstract 2
- KPRZOPQOBJRYSW-UHFFFAOYSA-N o-hydroxybenzylamine Natural products NCC1=CC=CC=C1O KPRZOPQOBJRYSW-UHFFFAOYSA-N 0.000 abstract 2
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical compound [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 abstract 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 abstract 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 abstract 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 abstract 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 1
- MLFXJCXPSODAIS-UHFFFAOYSA-N 2-[[2-[(2-hydroxyphenyl)methylamino]ethylamino]methyl]phenol Chemical compound OC1=CC=CC=C1CNCCNCC1=CC=CC=C1O MLFXJCXPSODAIS-UHFFFAOYSA-N 0.000 abstract 1
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 abstract 1
- BKMMTJMQCTUHRP-UHFFFAOYSA-N 2-aminopropan-1-ol Chemical compound CC(N)CO BKMMTJMQCTUHRP-UHFFFAOYSA-N 0.000 abstract 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 abstract 1
- 239000005792 Geraniol Substances 0.000 abstract 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 abstract 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000284 extract Substances 0.000 abstract 1
- 229940113087 geraniol Drugs 0.000 abstract 1
- -1 linalool Chemical class 0.000 abstract 1
- 229930007744 linalool Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA A ISOMERIZAçãO DE áLCOOIS ALILA". A invenção refere-se ao método para isomerizar álcoois alila extratos a álcoois alila produtos na presença de complexos oxo tungstênio (VI), contendo ligandos que contêm oxigênio adicional em temperaturas entre 50 e 300<198>C. Método citado é caracterizado em que álcoois amino, tais como trietanolamina, dietanolamina, monoetanolamina, tripropanolamina, dipropanolamina, 3-amino-1-propanol, 1-amino-2-propanol, 2-amino-1propanol, butildietanolamina, metildiisopropanolamina, N,N'-bis-(2-hidroxibenzil)-1,2-diaminoetano ou N-(2-hidroxi-benzil)-amina estão contidos no catalisador como ligandos que contêm oxigênio adicional, além das bases de oxigênio conhecidas como ligandos contendo oxigênio adicional ou em lugar dessas bases de oxigênio. O método é particularmente apropriado para produzir álcoois alila produto terciário, tais como linalool, através de isomerização de álcoois alila primário ou secundário tais como geraniol e nerol.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19958603A DE19958603A1 (de) | 1999-12-06 | 1999-12-06 | Verfahren zur Isomerisierung von Allylalkoholen |
| PCT/EP2000/011580 WO2001042177A1 (de) | 1999-12-06 | 2000-11-21 | Verfahren zur isomerisierung von allylalkoholen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0016215A true BR0016215A (pt) | 2002-09-10 |
Family
ID=7931495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0016215-9A BR0016215A (pt) | 1999-12-06 | 2000-11-21 | Processo para a isomerização de álcoois alila |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6566564B1 (pt) |
| EP (1) | EP1235775B1 (pt) |
| JP (1) | JP4477276B2 (pt) |
| CN (1) | CN1171838C (pt) |
| AR (1) | AR026721A1 (pt) |
| AT (1) | ATE267156T1 (pt) |
| BR (1) | BR0016215A (pt) |
| DE (2) | DE19958603A1 (pt) |
| ES (1) | ES2221866T3 (pt) |
| WO (1) | WO2001042177A1 (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10160147A1 (de) * | 2001-12-07 | 2003-06-18 | Basf Ag | Verfahren zur Isomerisierung von Allylalkoholen |
| DE10160146A1 (de) | 2001-12-07 | 2003-06-18 | Basf Ag | Verfahren zur Isomerisierung von Allylalkoholen |
| CN101605748B (zh) * | 2007-02-09 | 2013-04-03 | 帝斯曼知识产权资产管理有限公司 | 戊-1-烯-3-醇的异构化工艺 |
| JP5392623B2 (ja) * | 2007-02-16 | 2014-01-22 | ディーエスエム アイピー アセッツ ビー．ブイ． | 第一級アリルアルコールとの新規な反応 |
| EP2657216B1 (de) | 2012-04-27 | 2014-06-25 | Symrise AG | Verfahren zum Umsetzen von Farnesol zu Nerolidol in Gegenwart von alpha-Bisabolol |
| CN105218312B (zh) * | 2015-11-03 | 2017-04-26 | 山东新和成药业有限公司 | 一种烯丙基醇经异构化法连续制备芳樟醇的方法 |
| CN111087343B (zh) * | 2019-11-29 | 2022-02-18 | 万华化学集团股份有限公司 | 一种羟基吡啶配体及其制备方法和催化应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1599581A (pt) | 1968-12-30 | 1970-07-15 | ||
| DE2516698A1 (de) | 1974-04-22 | 1975-10-30 | Kuraray Co | Neue wolframverbindungen |
-
1999
- 1999-12-06 DE DE19958603A patent/DE19958603A1/de not_active Withdrawn
-
2000
- 2000-11-21 DE DE50006532T patent/DE50006532D1/de not_active Expired - Lifetime
- 2000-11-21 ES ES00987276T patent/ES2221866T3/es not_active Expired - Lifetime
- 2000-11-21 CN CNB008165351A patent/CN1171838C/zh not_active Expired - Fee Related
- 2000-11-21 JP JP2001543480A patent/JP4477276B2/ja not_active Expired - Fee Related
- 2000-11-21 WO PCT/EP2000/011580 patent/WO2001042177A1/de not_active Ceased
- 2000-11-21 US US10/130,827 patent/US6566564B1/en not_active Expired - Lifetime
- 2000-11-21 BR BR0016215-9A patent/BR0016215A/pt not_active Application Discontinuation
- 2000-11-21 AT AT00987276T patent/ATE267156T1/de not_active IP Right Cessation
- 2000-11-21 EP EP00987276A patent/EP1235775B1/de not_active Expired - Lifetime
- 2000-12-05 AR ARP000106433A patent/AR026721A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE50006532D1 (de) | 2004-06-24 |
| WO2001042177A1 (de) | 2001-06-14 |
| JP2003516372A (ja) | 2003-05-13 |
| CN1171838C (zh) | 2004-10-20 |
| JP4477276B2 (ja) | 2010-06-09 |
| AR026721A1 (es) | 2003-02-26 |
| ATE267156T1 (de) | 2004-06-15 |
| ES2221866T3 (es) | 2005-01-16 |
| EP1235775A1 (de) | 2002-09-04 |
| EP1235775B1 (de) | 2004-05-19 |
| DE19958603A1 (de) | 2001-06-07 |
| US6566564B1 (en) | 2003-05-20 |
| CN1402699A (zh) | 2003-03-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |