BR0102294A - Processo para a preparação de elastÈmero de etileno propileno - Google Patents
Processo para a preparação de elastÈmero de etileno propilenoInfo
- Publication number
- BR0102294A BR0102294A BR0102294-6A BR0102294A BR0102294A BR 0102294 A BR0102294 A BR 0102294A BR 0102294 A BR0102294 A BR 0102294A BR 0102294 A BR0102294 A BR 0102294A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- elastomers
- ethylene propylene
- propylene elastomer
- propylene
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 229920000181 Ethylene propylene rubber Polymers 0.000 title 1
- 229920001971 elastomer Polymers 0.000 abstract 4
- 239000000806 elastomer Substances 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical compound C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- -1 monosubstituted nitrogen Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"PROCESSO PARA A PREPARAçãO DE ELASTÈMERO DE ETILENO PROPILENO". Processo de polimerização em solução, para a preparação de elastómeros de etileno propileno (dieno) elastoméricos, caracterizado pelo uso de a) um catalisador sem ponte com um ligante ciclopentadienil e um ligante nitrogênio monossubstituído; e b) um ativador de boro. Elastómeros de elevado peso molecular podem ser preparados de maneira barata pelo processo desta invenção. Os elastómeros são adequados para a fabricação de folhas ou membranas de borracha e de peças para automóveis, como vedações, correias, mangueiras e flancos de pneus.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002311068A CA2311068C (en) | 2000-06-08 | 2000-06-08 | Process to prepare ethylene propylene elastomer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0102294A true BR0102294A (pt) | 2002-04-23 |
| BR0102294B1 BR0102294B1 (pt) | 2010-11-30 |
Family
ID=4166428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0102294-6A BR0102294B1 (pt) | 2000-06-08 | 2001-06-07 | processo para a preparação de elastÈmero de etileno propileno. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6486276B1 (pt) |
| EP (1) | EP1162214B1 (pt) |
| JP (1) | JP2002020416A (pt) |
| KR (1) | KR100773663B1 (pt) |
| CN (1) | CN1185265C (pt) |
| AT (1) | ATE444976T1 (pt) |
| BR (1) | BR0102294B1 (pt) |
| CA (1) | CA2311068C (pt) |
| DE (1) | DE60140102D1 (pt) |
| ES (1) | ES2333405T3 (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2347410C (en) * | 2001-05-11 | 2009-09-08 | Nova Chemicals Corporation | Solution polymerization process catalyzed by a phosphinimine catalyst |
| EP2261269B1 (en) | 2003-07-09 | 2016-11-09 | Arlanxeo Netherlands B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene |
| US7956140B2 (en) | 2004-03-17 | 2011-06-07 | Dsm Ip Assets B.V. | Polymerization catalyst comprising amidine ligand |
| KR100586922B1 (ko) * | 2004-11-18 | 2006-06-08 | 금호폴리켐 주식회사 | 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법 |
| US7064096B1 (en) * | 2004-12-07 | 2006-06-20 | Nova Chemicals (International) Sa | Dual catalyst on a single support |
| KR20080008421A (ko) * | 2005-05-12 | 2008-01-23 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리아미드 수지 조성물 |
| JP2007063409A (ja) * | 2005-08-31 | 2007-03-15 | Asahi Kasei Chemicals Corp | 環状オレフィン系共重合体の製造方法 |
| EP1764379A1 (en) * | 2005-09-19 | 2007-03-21 | DSM IP Assets B.V. | Polymerization catalyst comprising an amidine ligand |
| ATE549361T1 (de) * | 2006-07-17 | 2012-03-15 | Dow Global Technologies Llc | Verfahren zur korrelierung von uv-vis-spektren einer norbonenverbindung, polymerisierungsverfahren damit sowie entsprechende reinigungsverfahren und - zusammensetzungen |
| WO2008148499A1 (en) * | 2007-06-06 | 2008-12-11 | Dsm Ip Assets B.V. | Imine catalyst |
| WO2008151776A1 (en) * | 2007-06-12 | 2008-12-18 | Dsm Ip Assets B.V. | Imine catalyst |
| EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
| EP2508540A1 (en) * | 2011-04-01 | 2012-10-10 | Lanxess Elastomers B.V. | Borane activated titanium catalyst system comprising guanidine and diene ligands |
| EP2508539A1 (en) * | 2011-04-01 | 2012-10-10 | Lanxess Elastomers B.V. | Titanium-catalyst system comprising substituted cyclopentadienyl, guanidine and diene ligands |
| CN104163882B (zh) * | 2014-07-24 | 2017-11-07 | 大连理工大学 | 二元稀土乙丙橡胶及其制备方法 |
| WO2016110795A1 (en) * | 2015-01-08 | 2016-07-14 | Nova Chemicals (International) S.A. | Optimized agitator system for production of polyolefin |
| JP7125569B2 (ja) * | 2020-06-29 | 2022-08-24 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法、及びノルボルネン単量体とエチレンとの共重合用の触媒組成物 |
| DE112021005199T5 (de) * | 2020-10-02 | 2023-08-24 | Polyplastics Co., Ltd. | Transparenter Gegenstand |
| CN115043965B (zh) * | 2022-07-27 | 2023-04-21 | 中国科学技术大学 | 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| KR900009719A (ko) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | 신규 에틸렌-프로필렌 공중합체 |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5491207A (en) | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| US5696213A (en) | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| CA2206944C (en) * | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
| CA2215444C (en) * | 1997-09-15 | 2005-08-02 | Stephen John Brown | Catalyst having a ketimide ligand |
| CA2225708A1 (en) * | 1997-12-22 | 1999-06-22 | Nova Chemicals Ltd. | Solution catalyst having a bulky nitrogen ligand |
| CA2243726C (en) * | 1998-07-21 | 2006-12-12 | Nova Chemicals Ltd. | Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand |
| CA2243775C (en) * | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
| CA2245375C (en) * | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
| CA2254841C (en) * | 1998-11-26 | 2007-02-06 | Nova Chemicals Ltd. | Nitrogen substituted phosphinimine ligand |
-
2000
- 2000-06-08 CA CA002311068A patent/CA2311068C/en not_active Expired - Lifetime
-
2001
- 2001-05-21 US US09/862,189 patent/US6486276B1/en not_active Expired - Lifetime
- 2001-05-31 AT AT01304824T patent/ATE444976T1/de not_active IP Right Cessation
- 2001-05-31 ES ES01304824T patent/ES2333405T3/es not_active Expired - Lifetime
- 2001-05-31 DE DE60140102T patent/DE60140102D1/de not_active Expired - Lifetime
- 2001-05-31 EP EP01304824A patent/EP1162214B1/en not_active Expired - Lifetime
- 2001-06-05 KR KR1020010031480A patent/KR100773663B1/ko not_active Expired - Lifetime
- 2001-06-07 CN CNB011228865A patent/CN1185265C/zh not_active Expired - Lifetime
- 2001-06-07 BR BRPI0102294-6A patent/BR0102294B1/pt not_active IP Right Cessation
- 2001-06-07 JP JP2001171850A patent/JP2002020416A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE60140102D1 (de) | 2009-11-19 |
| EP1162214A1 (en) | 2001-12-12 |
| CN1328066A (zh) | 2001-12-26 |
| CN1185265C (zh) | 2005-01-19 |
| ES2333405T3 (es) | 2010-02-22 |
| KR100773663B1 (ko) | 2007-11-05 |
| KR20020002209A (ko) | 2002-01-09 |
| BR0102294B1 (pt) | 2010-11-30 |
| ATE444976T1 (de) | 2009-10-15 |
| US6486276B1 (en) | 2002-11-26 |
| CA2311068A1 (en) | 2001-12-08 |
| JP2002020416A (ja) | 2002-01-23 |
| EP1162214B1 (en) | 2009-10-07 |
| CA2311068C (en) | 2010-03-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B15G | Petition not considered as such [chapter 15.7 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/06/2001, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B24B | Patent annual fee: requirement for complementing annual fee | ||
| B24D | Patent annual fee: restoration after fee payment | ||
| B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 07.06.2021 |