BR0111462A - Composição ou produto perfumante, mascarador (a), antimicrobiano (a), repelente ou que atrai inseto, método para gerar uma atividade especìfica do tipo perfumante, mascaradora, antimicrobiana, repelente ou que atrai inseto, precursor de uma molécula perfumante ativa, mascaradora, antimicrobiana, repelente ou que atrai inseto, e, superfìcie selecionada do grupo que consiste de pele ou cabelo, piso, janela, azulejo, móveis, tecido ou roupas e plantas - Google Patents

Composição ou produto perfumante, mascarador (a), antimicrobiano (a), repelente ou que atrai inseto, método para gerar uma atividade especìfica do tipo perfumante, mascaradora, antimicrobiana, repelente ou que atrai inseto, precursor de uma molécula perfumante ativa, mascaradora, antimicrobiana, repelente ou que atrai inseto, e, superfìcie selecionada do grupo que consiste de pele ou cabelo, piso, janela, azulejo, móveis, tecido ou roupas e plantas

Info

Publication number
BR0111462A
BR0111462A BR0111462-0A BR0111462A BR0111462A BR 0111462 A BR0111462 A BR 0111462A BR 0111462 A BR0111462 A BR 0111462A BR 0111462 A BR0111462 A BR 0111462A
Authority
BR
Brazil
Prior art keywords
group
antimicrobial
masking
attracting
insect repellent
Prior art date
Application number
BR0111462-0A
Other languages
English (en)
Inventor
Andreas Herrmann
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Publication of BR0111462A publication Critical patent/BR0111462A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2072—Aldehydes-ketones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/507—Compounds releasing perfumes by thermal or chemical activation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dermatology (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

"COMPOSIçãO OU PRODUTO PERFUMANTE, MASCARADOR(A), ANTIMICROBIANO(A), REPELENTE OU QUE ATRAI INSETO, MéTODO PARA GERAR UMA ATIVIDADE ESPECìFICA DO TIPO PERFUMANTE, MASCARADORA, ANTIMICROBIANA, REPELENTE OU QUE ATRAI INSETO, PRECURSOR DE UMA MOLéCULA PERFUMANTE ATIVA, MASCARADORA, ANTIMICROBIANA, REPELENTE OU QUE ATRAI INSETO, E, SUPERFìCIE SELECIONADA DO GRUPO QUE CONSISTE DE PELE OU CABELO, PISO, JANELA, AZULEJO, MóVEIS, TECIDO OU ROUPAS E PLANTAS". Um composto da fórmula (1) em que Y representa um grupo piridila ou um grupo fenila da fórmula [fórmula (Ia)] em que R~ 3~ representa um átomo de hidrogênio, um grupo CF~ 3~ ou um grupo alcóxi linear ou ramificado de C~ 1~ a C~ 12~, R~ 4~ representa um átomo de hidrogênio, um grupo alquila linear ou ramificado de C~ 1~ a C~ 4~ ou um grupo CF~ 3~, R~ 5~ representa um átomo de hidrogênio, um grupo alquila linear ou ramificado de C~ 1~ a C~ 4~ um grupo CF~ 3~ ou um grupo alcóxi linear ou ramificado de C~ 1~ a C~ 12~ e R~ 1~ e R~ 2~ são os substituintes de um alqueno terminal da fórmula (i) em que R~ 1~ representa um grupo alquila ou alquileno linear ou ramificado de C~ 1~ a C~ 35~, um grupo mono ou policicloalquila não substituído ou substituído que tem de 3 a 8 átomos de carbono ou um grupo fenila não substituído ou substituído, os ditos grupos alquila, alquileno, mono ou poli cicloalquila e fenila compreendem possivelmente um ou diversos heteroátomos selecionados do grupo que consiste de oxigênio, nitrogênio, fósforo e enxofre; e R~ 2~ representa um átomo de hidrogênio, um grupo alquila ou alquileno linear ou ramificado de C~ 1~ a C~ 35~, um grupo mono ou policicloalquila não substituído ou substituído de C~ 3~ a C~ 8~ ou um grupo fenila não substituído ou substituído, os ditos grupos alquila, alquileno, mono ou poli cicloalquila e fenila compreendem possivelmente um ou diversos heteroátomos selecionados do grupo que consiste de oxigênio, nitrogênio, fósforo e enxofre; é capaz de liberar, em uma exposição à luz, um composto ativo, tal como um perfume e pode ser vantajosamente usado no tratamento de qualquer superfície a fim de perfumá-la através da liberação controlada de uma molécula perfumada.
BR0111462-0A 2000-06-15 2001-06-11 Composição ou produto perfumante, mascarador (a), antimicrobiano (a), repelente ou que atrai inseto, método para gerar uma atividade especìfica do tipo perfumante, mascaradora, antimicrobiana, repelente ou que atrai inseto, precursor de uma molécula perfumante ativa, mascaradora, antimicrobiana, repelente ou que atrai inseto, e, superfìcie selecionada do grupo que consiste de pele ou cabelo, piso, janela, azulejo, móveis, tecido ou roupas e plantas BR0111462A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IB0000804 2000-06-15
PCT/IB2001/001021 WO2001096272A2 (en) 2000-06-15 2001-06-11 Utilisation of ketones as precursors of active compounds

Publications (1)

Publication Number Publication Date
BR0111462A true BR0111462A (pt) 2003-05-06

Family

ID=11003934

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0111462-0A BR0111462A (pt) 2000-06-15 2001-06-11 Composição ou produto perfumante, mascarador (a), antimicrobiano (a), repelente ou que atrai inseto, método para gerar uma atividade especìfica do tipo perfumante, mascaradora, antimicrobiana, repelente ou que atrai inseto, precursor de uma molécula perfumante ativa, mascaradora, antimicrobiana, repelente ou que atrai inseto, e, superfìcie selecionada do grupo que consiste de pele ou cabelo, piso, janela, azulejo, móveis, tecido ou roupas e plantas

Country Status (13)

Country Link
US (1) US6949680B2 (pt)
EP (1) EP1294671B1 (pt)
JP (1) JP5085830B2 (pt)
CN (1) CN1436161A (pt)
AR (1) AR029138A1 (pt)
AT (1) ATE411271T1 (pt)
AU (1) AU8725901A (pt)
BR (1) BR0111462A (pt)
CA (1) CA2406613A1 (pt)
DE (1) DE60136178D1 (pt)
PL (1) PL358741A1 (pt)
WO (1) WO2001096272A2 (pt)
ZA (1) ZA200208294B (pt)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004089327A1 (en) * 2003-04-11 2004-10-21 Coreana Cosmetics Co., Ltd. Medicinal cosmetical composition with areca catechu seed extract
DE102008016327A1 (de) 2008-03-28 2009-10-01 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
DE102008060886A1 (de) * 2008-12-09 2010-06-10 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
WO2010143753A2 (en) * 2009-06-11 2010-12-16 International Centre Of Insect Physiology And Ecology (Icipe) Repellant compositions for blood-feeding insects
EP2440061B1 (en) 2009-06-12 2018-12-05 Bayer Cropscience LP Methods of inhibiting, preventing, killing and/or repelling insects using simulated blends of chenopodium extracts
WO2011067707A2 (en) 2009-12-02 2011-06-09 L'oreal A cosmetic treatment method
DE102010002006A1 (de) 2010-02-17 2011-08-18 Henkel AG & Co. KGaA, 40589 Photolabile Duftspeicherstoffe
DE102010002007A1 (de) 2010-02-17 2011-08-18 Henkel AG & Co. KGaA, 40589 Photolabile Duftspeicherstoffe
DE102011078416A1 (de) 2011-06-30 2013-01-03 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
DE102011078415A1 (de) 2011-06-30 2013-01-03 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
MX2014002890A (es) 2011-09-12 2015-01-19 Bayer Cropscience Lp Metodo para mejorar la salud y/o promover el crecimiento de una planta y/o mejorar la maduracion de frutos.
DE102012210566A1 (de) * 2012-06-22 2013-12-24 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
BR112015027805A2 (pt) * 2013-05-22 2017-08-29 Firmenich & Cie Microcápsulas contendo um composto fotolábil que libera gás e uso das mesmas
DE102014203252A1 (de) 2014-02-24 2015-08-27 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
DE102014205390A1 (de) 2014-03-24 2015-09-24 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
DE102014226196A1 (de) 2014-12-17 2016-06-23 Henkel Ag & Co. Kgaa Photolabile Duftstoffvorläuferverbindung
DE102015220928A1 (de) 2015-10-27 2017-04-27 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
DE102015224955A1 (de) 2015-12-11 2017-06-14 Henkel Ag & Co. Kgaa Synthese von Ketonen freisetzenden Photocages
DE102015220926A1 (de) 2015-10-27 2017-04-27 Henkel Ag & Co. Kgaa Ketone freisetzende Photocages
DE102015220929A1 (de) 2015-10-27 2017-04-27 Henkel Ag & Co. Kgaa Photolabile Duftspeicherstoffe
JP2024540307A (ja) * 2021-11-03 2024-10-31 フイルメニツヒ ソシエテ アノニム 活性アルデヒドおよびケトンの光誘導放出のための環状アセタールおよびケタール
EP4676920A1 (en) * 2023-04-17 2026-01-14 Firmenich SA Photolabile cyclic acetals and ketals for the light-induced delivery of active aldehydes and ketones

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU67231A1 (pt) * 1973-03-16 1974-10-09
DE3161699D1 (en) * 1980-07-31 1984-01-26 Firmenich & Cie Use of phenyl-n-hexyl ketone as a perfuming agent, and perfume compositions containing the same
ES2187807T3 (es) * 1996-08-19 2003-06-16 Procter & Gamble Composiciones detergentes para la colada que comprenden profragancias beta-cetoestericas.
US6133228A (en) * 1998-05-28 2000-10-17 Firmenich Sa Slow release of fragrant compounds in perfumery using 2-benzoyl benzoates, 2-alkanoyl benzoates or α-keto esters
ZA994918B (en) * 1998-09-04 2000-02-07 Givaudan Roure Int New ketones.
EP0983990A3 (en) * 1998-09-04 2000-08-02 Givaudan Roure (International) S.A. Ketones useful as precursors for organoleptic compounds

Also Published As

Publication number Publication date
CN1436161A (zh) 2003-08-13
EP1294671B1 (en) 2008-10-15
AR029138A1 (es) 2003-06-04
EP1294671A2 (en) 2003-03-26
CA2406613A1 (en) 2001-12-20
DE60136178D1 (de) 2008-11-27
ATE411271T1 (de) 2008-10-15
JP2004503612A (ja) 2004-02-05
US20030129212A1 (en) 2003-07-10
AU8725901A (en) 2001-12-24
US6949680B2 (en) 2005-09-27
JP5085830B2 (ja) 2012-11-28
ZA200208294B (en) 2003-07-16
PL358741A1 (en) 2004-08-09
WO2001096272A3 (en) 2002-05-30
WO2001096272A2 (en) 2001-12-20

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