BR0115914A - Composição catalisadora, método de polimerização e polimero do mesmo - Google Patents

Composição catalisadora, método de polimerização e polimero do mesmo

Info

Publication number
BR0115914A
BR0115914A BR0115914-3A BR0115914A BR0115914A BR 0115914 A BR0115914 A BR 0115914A BR 0115914 A BR0115914 A BR 0115914A BR 0115914 A BR0115914 A BR 0115914A
Authority
BR
Brazil
Prior art keywords
polymer
polymerization method
catalyst composition
combining
solution
Prior art date
Application number
BR0115914-3A
Other languages
English (en)
Inventor
John Francis Szul
Tae Hoon Kwalk
David James Schreck
Simon Mawson
Matthew Gary Mckee
Kersten Anne Terry
Mark Gregory Goode
Gregory T Whiteker
Eric A Lucas
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR0115914A publication Critical patent/BR0115914A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

"COMPOSIçãO CATALISADORA, MéTODO DE POLIMERIZAçãO E POLìMERO DO MESMO". A presente invenção refere-se a um processo para polimerizar olefina(s) compreendendo a combinação de uma solução, uma pasta fluida ou um sólido compreendendo um ou mais compostos de catalisador de metaloceno de ligando volumosos, um suporte, e um ou mais ativadore(s) com uma solução compreendendo um ou mais compostos de catalisador de fenóxido, e depois disso, introdução de uma ou mais olefina(s) e a combinação para dentro de um reator de polimerização. Esta invenção refere-se a um polímero de etileno em que o polímero tem uma densidade de 0,910 a 0,930 g/cc, um índice de fusão I~ 2~ de 0,3 a 2,0 dg/min, e uma película de espessura de 15 a 35 <109>m do polímero tem um brilho a 45<198> de 60 ou mais, uma turvação de 7 por cento ou menos, e um impacto de dardo de 600 g ou mais.
BR0115914-3A 2000-12-04 2001-11-28 Composição catalisadora, método de polimerização e polimero do mesmo BR0115914A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/729,557 US6897273B2 (en) 2000-12-04 2000-12-04 Catalyst composition, method of polymerization and polymer therefrom
PCT/US2001/044394 WO2002046250A2 (en) 2000-12-04 2001-11-28 Catalyst composition, method of polymerization and polymer therefrom

Publications (1)

Publication Number Publication Date
BR0115914A true BR0115914A (pt) 2004-02-25

Family

ID=24931581

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0115914-3A BR0115914A (pt) 2000-12-04 2001-11-28 Composição catalisadora, método de polimerização e polimero do mesmo

Country Status (8)

Country Link
US (2) US6897273B2 (pt)
EP (1) EP1392743A2 (pt)
JP (1) JP2004521159A (pt)
CN (1) CN1484658A (pt)
AU (1) AU2002219891A1 (pt)
BR (1) BR0115914A (pt)
CA (1) CA2430517A1 (pt)
WO (1) WO2002046250A2 (pt)

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US8497330B2 (en) 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
CA2399753A1 (en) * 2002-08-27 2004-02-27 Nova Chemicals Corporation Antistatic for gas phase single site catalyst polymerization
AU2003261617A1 (en) * 2002-08-29 2004-03-19 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
US7094848B2 (en) 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7064096B1 (en) * 2004-12-07 2006-06-20 Nova Chemicals (International) Sa Dual catalyst on a single support
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7321015B2 (en) * 2004-12-07 2008-01-22 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
WO2006066126A2 (en) * 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
CN101233143B (zh) * 2005-07-26 2014-04-16 Lg化学株式会社 制备用于环烯烃聚合的鏻化合物的方法
US8835577B2 (en) 2007-11-15 2014-09-16 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
EP2070953A1 (en) * 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Activating supports based on phosphonium complexes
EP2251361B1 (en) 2009-05-04 2013-10-02 Borealis AG Preparation of precipitated ZN PP catalysts with internal pore structure using nanoparticles
CA2757045C (en) 2009-05-14 2017-03-07 Univation Technologies, Llc Mixed metal catalyst systems having a tailored hydrogen response
CN102665909B (zh) * 2009-09-29 2014-10-08 Lg化学株式会社 包含三种化合物的负载型杂化茂金属催化剂及其制备方法
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
CA2734167C (en) * 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
US8993693B2 (en) * 2012-03-23 2015-03-31 Formosa Plastics Corporation Ethylene copolymers with a novel composition distribution and processes for making the same
RU2689991C1 (ru) * 2014-02-11 2019-05-30 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способ получения полиэтилена и полиэтилен, полученный указанным способом
CA2857456C (en) * 2014-07-22 2022-05-03 Nova Chemicals Corporation Improved control over particulate feed
WO2016145179A1 (en) * 2015-03-10 2016-09-15 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
KR101696099B1 (ko) * 2015-09-23 2017-01-13 롯데케미칼 주식회사 폴리에틸렌 중합용 촉매 조성물 및 이를 이용하여 가교도가 조절된 폴리에틸렌의 제조방법
KR102140260B1 (ko) * 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
US11028192B2 (en) 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers
CN107983410B (zh) * 2017-11-20 2020-09-04 苏州艾缇克药物化学有限公司 一种石墨烯/MOFs晶体复合孔洞催化剂的制备方法
CN116020416B (zh) * 2021-10-25 2025-06-17 中国石油化工股份有限公司 一种茂金属催化剂的脱除方法
CN118772189A (zh) * 2023-04-07 2024-10-15 中国科学院大学 一种单苯氧亚胺配体ivb族金属烷基络合物、制备方法及其在烯烃聚合中的应用

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ATE256707T1 (de) 1997-01-30 2004-01-15 Fina Technology Selektive wirkung von metallocen-katalysatoren für die herstellung von isotaktischen polyolefinen
JP3900699B2 (ja) 1998-08-12 2007-04-04 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
US6417304B1 (en) * 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6372868B1 (en) * 1999-12-07 2002-04-16 Univation Technologies, Llc Start up methods for multiple catalyst systems

Also Published As

Publication number Publication date
WO2002046250A3 (en) 2003-11-27
CA2430517A1 (en) 2002-06-13
AU2002219891A1 (en) 2002-06-18
WO2002046250A2 (en) 2002-06-13
US20020103310A1 (en) 2002-08-01
US6897273B2 (en) 2005-05-24
US20050154167A1 (en) 2005-07-14
JP2004521159A (ja) 2004-07-15
EP1392743A2 (en) 2004-03-03
CN1484658A (zh) 2004-03-24

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A E 6A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 1964 DE 26/08/2008 E CONSIDERANDO A AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS.