BR0307533A - Processo para preparação de derivados de ácido 2-(clorometil) fenil acético - Google Patents
Processo para preparação de derivados de ácido 2-(clorometil) fenil acéticoInfo
- Publication number
- BR0307533A BR0307533A BR0307533-8A BR0307533A BR0307533A BR 0307533 A BR0307533 A BR 0307533A BR 0307533 A BR0307533 A BR 0307533A BR 0307533 A BR0307533 A BR 0307533A
- Authority
- BR
- Brazil
- Prior art keywords
- acetic acid
- acid derivatives
- chloromethyl
- preparing
- phenyl acetic
- Prior art date
Links
- RFYCQJHCAPCSTA-UHFFFAOYSA-N 2-[2-(chloromethyl)phenyl]acetic acid Chemical class OC(=O)CC1=CC=CC=C1CCl RFYCQJHCAPCSTA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 150000008648 triflates Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/12—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reactions not involving the formation of oxyimino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
PROCESSO PARA PREPARAçãO DE DERIVADOS DE áCIDO 2(CLOROMETIL)FENIL ACéTICO". A invenção está relacionada a um método para a produção de derivados de ácido 2-(clorometil)fenil acético com a fórmula (I): na qual X representa um alcóxi C~ 1~-C~ 4~ ou metilamino, pela clivagem das ligações éter de compostos com a fórmula (II): na qual R representa alquila C~ 1~-C~ 4~, alcóxi C~ 1~-C~ 4~, haloalquila C~ 1~-C~ 2~, alquilcarbonila C~ 1~-C~ 4~, alquilcarbonilóxi C~ 1~-C~ 4~, halogênio, nitro ou ciano, e X possui o significado acima mencionado. O método da invenção é caracterizado pelo fato de que a transformação ocorre na presença de cloreto de hidrogênio e de um solvente inerte, e pelo fato de que é adicionado à mistura de reação um catalisador selecionado do grupo que compreende: ferro, índio ou halogenetos, óxidos ou triflatos dos mesmos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10208029 | 2002-02-26 | ||
| PCT/EP2003/001160 WO2003072538A1 (de) | 2002-02-26 | 2003-02-06 | Verfahren zur herstellung von 2-chlormethylphenylessigsäurederivaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0307533A true BR0307533A (pt) | 2004-12-21 |
Family
ID=27762430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0307533-8A BR0307533A (pt) | 2002-02-26 | 2003-02-06 | Processo para preparação de derivados de ácido 2-(clorometil) fenil acético |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7488840B2 (pt) |
| EP (1) | EP1480945B1 (pt) |
| JP (2) | JP4430943B2 (pt) |
| KR (1) | KR100934521B1 (pt) |
| CN (1) | CN1639113B (pt) |
| AT (1) | ATE304525T1 (pt) |
| AU (1) | AU2003215553B2 (pt) |
| BR (1) | BR0307533A (pt) |
| CA (1) | CA2476035A1 (pt) |
| DE (1) | DE50301191D1 (pt) |
| DK (1) | DK1480945T3 (pt) |
| EA (1) | EA006653B1 (pt) |
| ES (1) | ES2248762T3 (pt) |
| IL (1) | IL163111A (pt) |
| MX (1) | MXPA04007063A (pt) |
| PL (1) | PL205226B1 (pt) |
| SI (1) | SI1480945T1 (pt) |
| WO (1) | WO2003072538A1 (pt) |
| ZA (1) | ZA200407706B (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090177005A1 (en) * | 2002-02-26 | 2009-07-09 | Basf Aktiengesellschaft | Method For Producing 2-(chloromethyl)penylacetic acid derivatives |
| CA2476035A1 (en) * | 2002-02-26 | 2003-09-04 | Basf Aktiengesellschaft | Method for producing 2-chloromethylphenylacetic acid derivatives |
| CN102438980A (zh) * | 2009-02-05 | 2012-05-02 | 巴斯夫欧洲公司 | 制备2-卤代甲基苯基乙酸衍生物的方法 |
| CN109748792A (zh) * | 2018-12-24 | 2019-05-14 | 江苏中旗科技股份有限公司 | 啶氧菌酯中间体2-(2-氯甲基苯基)-3-甲氧基丙烯酸甲酯的制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4030038A1 (de) * | 1990-09-22 | 1992-03-26 | Basf Ag | Ortho-substituierte phenylessigsaeureamide |
| HUP0000380A3 (en) * | 1995-12-14 | 2000-12-28 | Basf Ag | 2-[(4-pirimidinyl)oxymethyl]-phenyl-acetic acid derivatives and their use for controlling harmful fungi and animal pests |
| AU2153297A (en) * | 1996-03-08 | 1997-09-22 | Basf Aktiengesellschaft | Diphenylethers, process and intermediate products for their preparation, and their use |
| IT1302108B1 (it) | 1997-10-13 | 2000-07-26 | Corob Spa | Gruppo di erogazione per una macchina dispensatrice di prodotti fluidi comprendente una camera pompante a volume variabile, e macchina |
| CA2476035A1 (en) * | 2002-02-26 | 2003-09-04 | Basf Aktiengesellschaft | Method for producing 2-chloromethylphenylacetic acid derivatives |
-
2003
- 2003-02-06 CA CA002476035A patent/CA2476035A1/en not_active Abandoned
- 2003-02-06 JP JP2003571244A patent/JP4430943B2/ja not_active Expired - Fee Related
- 2003-02-06 BR BR0307533-8A patent/BR0307533A/pt not_active IP Right Cessation
- 2003-02-06 WO PCT/EP2003/001160 patent/WO2003072538A1/de not_active Ceased
- 2003-02-06 DE DE50301191T patent/DE50301191D1/de not_active Expired - Lifetime
- 2003-02-06 PL PL371057A patent/PL205226B1/pl not_active IP Right Cessation
- 2003-02-06 AT AT03742928T patent/ATE304525T1/de not_active IP Right Cessation
- 2003-02-06 CN CN038044552A patent/CN1639113B/zh not_active Expired - Fee Related
- 2003-02-06 EA EA200401013A patent/EA006653B1/ru not_active IP Right Cessation
- 2003-02-06 DK DK03742928T patent/DK1480945T3/da active
- 2003-02-06 KR KR1020047013247A patent/KR100934521B1/ko not_active Expired - Fee Related
- 2003-02-06 US US10/505,475 patent/US7488840B2/en not_active Expired - Fee Related
- 2003-02-06 SI SI200330081T patent/SI1480945T1/sl unknown
- 2003-02-06 AU AU2003215553A patent/AU2003215553B2/en not_active Ceased
- 2003-02-06 ES ES03742928T patent/ES2248762T3/es not_active Expired - Lifetime
- 2003-02-06 MX MXPA04007063A patent/MXPA04007063A/es active IP Right Grant
- 2003-02-06 EP EP03742928A patent/EP1480945B1/de not_active Expired - Lifetime
-
2004
- 2004-07-20 IL IL163111A patent/IL163111A/en not_active IP Right Cessation
- 2004-09-23 ZA ZA200407706A patent/ZA200407706B/en unknown
-
2009
- 2009-09-29 JP JP2009224405A patent/JP5308297B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003072538A1 (de) | 2003-09-04 |
| CN1639113A (zh) | 2005-07-13 |
| ATE304525T1 (de) | 2005-09-15 |
| AU2003215553A1 (en) | 2003-09-09 |
| DK1480945T3 (da) | 2005-11-21 |
| EP1480945A1 (de) | 2004-12-01 |
| US7488840B2 (en) | 2009-02-10 |
| CA2476035A1 (en) | 2003-09-04 |
| EA006653B1 (ru) | 2006-02-24 |
| JP5308297B2 (ja) | 2013-10-09 |
| ZA200407706B (en) | 2006-06-28 |
| JP4430943B2 (ja) | 2010-03-10 |
| JP2010031027A (ja) | 2010-02-12 |
| US20050113597A1 (en) | 2005-05-26 |
| CN1639113B (zh) | 2011-06-01 |
| AU2003215553B2 (en) | 2009-05-28 |
| IL163111A (en) | 2009-08-03 |
| ES2248762T3 (es) | 2006-03-16 |
| EA200401013A1 (ru) | 2004-12-30 |
| MXPA04007063A (es) | 2004-10-29 |
| JP2005518440A (ja) | 2005-06-23 |
| PL205226B1 (pl) | 2010-03-31 |
| SI1480945T1 (sl) | 2005-12-31 |
| PL371057A1 (en) | 2005-06-13 |
| KR20040088543A (ko) | 2004-10-16 |
| EP1480945B1 (de) | 2005-09-14 |
| KR100934521B1 (ko) | 2009-12-29 |
| DE50301191D1 (de) | 2005-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 9A ANUIDADE(S). |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: NAO APRESENTADA A GUIA DE CUMPRIMENTO DE EXIGENCIA. REFERENTE A 9A ANUIDADE. |