BR0317851A - Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos - Google Patents

Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos

Info

Publication number
BR0317851A
BR0317851A BR0317851-0A BR0317851A BR0317851A BR 0317851 A BR0317851 A BR 0317851A BR 0317851 A BR0317851 A BR 0317851A BR 0317851 A BR0317851 A BR 0317851A
Authority
BR
Brazil
Prior art keywords
transition
processes
chromium
polymerization catalysts
catalyst systems
Prior art date
Application number
BR0317851-0A
Other languages
English (en)
Inventor
Kersten Anne Terry
Mark G Goode
Dan E Wente
John Chirillo
Simon Mawson
Jose Fernando Cevallos-Candau
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR0317851A publication Critical patent/BR0317851A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"PROCESSOS PARA REALIZAR A TRANSIçãO ENTRE CATALISADORES DE POLIMERIZAçãO BASEADOS EM CROMO E MISTOS". A presente invenção refere-se a processos para realizar a transição entre sistemas catalisadores de polimerização, preferivelmente sistemas catalisadores que são incompatíveis entre si. Particularmente, processos para realizar a transição entre reações de polimerização de olefina utilizando sistemas catalisadores de cromato de silila e sistemas catalisadores metaloceno.
BR0317851-0A 2002-12-31 2003-12-02 Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos BR0317851A (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US43720402P 2002-12-31 2002-12-31
US10/715,651 US6841630B2 (en) 2002-12-31 2003-11-17 Processes for transitioning between chrome-based and mixed polymerization catalysts
PCT/US2003/038236 WO2004060929A1 (en) 2002-12-31 2003-12-02 Processes for transitioning between chrome-based and mixed polymerization catalysts

Publications (1)

Publication Number Publication Date
BR0317851A true BR0317851A (pt) 2005-12-06

Family

ID=32717882

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0317851-0A BR0317851A (pt) 2002-12-31 2003-12-02 Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos

Country Status (9)

Country Link
US (1) US6841630B2 (pt)
EP (1) EP1578807B1 (pt)
JP (1) JP2006512450A (pt)
AR (1) AR042689A1 (pt)
AU (1) AU2003293226A1 (pt)
BR (1) BR0317851A (pt)
CA (1) CA2508284A1 (pt)
DE (1) DE60335658D1 (pt)
WO (1) WO2004060929A1 (pt)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1767549A1 (en) 2005-09-20 2007-03-28 Ineos Europe Limited Polymerisation catalysts
CA2529920C (en) * 2005-12-13 2013-08-20 Nova Chemicals Corporation On the fly catalyst transitions
CA2672389C (en) * 2006-12-28 2014-11-18 Mitsubishi Chemical Corporation Deposit deactivation treatment method
BRPI0916813A2 (pt) * 2008-07-23 2020-08-11 Basell Polyolefine Gmbh método para transição de sistemas incompatíveis de catalisador de polimerização de olefina
WO2010072367A1 (en) * 2008-12-23 2010-07-01 Basell Polyolefine Gmbh Method for transitioning between incompatible olefin polymerization catalyst systems
US9914794B2 (en) 2014-05-27 2018-03-13 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
CN109328200B (zh) * 2016-06-23 2022-08-19 博里利斯股份公司 催化剂失活的方法
CN109996822A (zh) 2016-11-18 2019-07-09 埃克森美孚化学专利公司 使用含铬催化剂的聚合方法
US10023666B2 (en) 2016-12-13 2018-07-17 Chevron Phillips Chemical Company Lp Process for transitioning between low percentage chrome and high percentage chrome catalysts
EP3601386A1 (en) 2017-03-21 2020-02-05 ExxonMobil Chemical Patents Inc. Processes for preparing a catalyst system and polymerizing olefins
US10870716B2 (en) 2017-03-23 2020-12-22 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
US11021552B2 (en) 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US12202917B2 (en) 2019-03-21 2025-01-21 Exxonmobil Chemical Patents Inc. Methods for improving gas phase polymerization
WO2020190511A1 (en) 2019-03-21 2020-09-24 Exxonmobil Chemical Patents Inc. Methods for improving production in gas phase polymerization
WO2021118715A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Low aromatic polyolefins
CN115551904B (zh) 2020-04-28 2024-03-22 埃克森美孚化学专利公司 具有良好应力开裂性能的聚合物的密度和化学组成控制
CN115989275B (zh) 2020-08-25 2025-03-25 埃克森美孚化学专利公司 具有优异物理性能的高密度聚乙烯组合物
WO2022108971A1 (en) 2020-11-23 2022-05-27 Exxonmobil Chemical Patents Inc. Toluene free supported methylalumoxane precursor
WO2022108972A1 (en) 2020-11-23 2022-05-27 Exxonmobil Chemical Patents Inc. Improved process to prepare catalyst from in-situ formed alumoxane
EP4347670A1 (en) 2021-05-24 2024-04-10 ExxonMobil Chemical Patents Inc. Biphasic polymerization processes
WO2023044215A1 (en) 2021-09-14 2023-03-23 Exxonmobil Chemical Patents Inc. Catalyst feeder and processes thereof
US20250206859A1 (en) 2022-03-31 2025-06-26 Exxonmobil Chemical Patents Inc. Linear low density polyethylenes, polymerizations thereof, and films thereof
EP4526360A1 (en) 2022-05-18 2025-03-26 ExxonMobil Chemical Patents Inc. Polyethylene compositions and processes for their production
KR20250029161A (ko) 2022-06-24 2025-03-04 엑손모빌 케미칼 패턴츠 인코포레이티드 계내 mao 담지화의 저비용 공정 및 유도되어 완성된 폴리올레핀 촉매
CN119768442A (zh) 2022-08-22 2025-04-04 埃克森美孚化学专利公司 聚乙烯组合物和由其制备的膜
CN119855843A (zh) 2022-09-07 2025-04-18 埃克森美孚化学专利公司 聚乙烯及其制品
CN121420001A (zh) 2023-05-23 2026-01-27 埃克森美孚技术与工程公司 聚乙烯、用于它们的聚合的催化剂及其膜
WO2024242933A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
EP4716705A1 (en) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Low density polethylenes, films thereof, and methods and catalysts for production thereof
EP4716704A1 (en) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Polyethylenes having improved processability and films thereof
EP4716706A1 (en) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Catalysts, polyethylenes, polymerizations thereof, and films thereof
EP4716708A1 (en) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
WO2024253831A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Non-coordinated alkylaluminum free anion modified alumoxanes and methods thereof
WO2025250307A1 (en) 2024-05-30 2025-12-04 ExxonMobil Technology and Engineering Company Methods for improving gas phase polymerization
WO2026024387A1 (en) 2024-07-22 2026-01-29 ExxonMobil Technology and Engineering Company Polyethylene sealing layer resins
WO2026024926A1 (en) 2024-07-25 2026-01-29 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins
WO2026024944A1 (en) 2024-07-25 2026-01-29 ExxonMobil Technology and Engineering Company Metallocene catalyst compounds for producing polyolefins

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0004417B2 (en) 1978-03-23 1990-02-28 Imperial Chemical Industries Plc Gas-phase olefin polymerisation system and process for operating it
US4460755A (en) * 1982-09-30 1984-07-17 Union Carbide Corporation Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst
JPS5981308A (ja) * 1982-09-30 1984-05-11 ユニオン・カ−バイド・コ−ポレ−シヨン チ−グラ−型触媒による触媒重合反応のクロム基材触媒による触媒重合反応への直接転換
DE3305782A1 (de) 1983-02-19 1984-08-30 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur polymerisation und copolymerisation von ethylen
US4834947A (en) 1983-09-01 1989-05-30 Mobil Oil Corporation Reactor system for rapid kill gas injection to gas phase polymerization reactors
US5201055A (en) * 1989-11-03 1993-04-06 Compaq Computer Corporation Multiprocessing system includes interprocessor encoding and decoding logic used for communication between two cards through reduced addressing lines
FR2665704B1 (fr) * 1990-08-07 1994-04-08 Bp Chemicals Snc Procede pour arreter une reaction de (co-)polymerisation effectuee a l'aide d'un catalyseur a base d'oxyde de chrome.
US5204751A (en) 1990-08-17 1993-04-20 Hughes Display Products Target support for projection cathode ray tube
GB9103527D0 (en) 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
US5227438A (en) 1991-09-24 1993-07-13 Union Carbide Chemicals & Plastics Technology Corporation Process for the slowdown or termination of polymerization
US5270408A (en) 1992-01-29 1993-12-14 Union Carbide Chemicals & Plastics Technology Corporation Method and apparatus for stopping reaction in a gas phase polymerization reactor system
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5371053A (en) 1993-05-18 1994-12-06 Exxon Chemical Patents Inc. Process for deactivating Ziegler-Natta and metallocene catalysts
US5442019A (en) 1994-03-25 1995-08-15 Exxon Chemical Company Process for transitioning between incompatible polymerization catalysts
NO301331B1 (no) 1996-03-05 1997-10-13 Borealis As Fremgangsmåte for skifting av katalysator ved suspensjonspolymerisasjon av olefiner
JP3836219B2 (ja) 1996-09-12 2006-10-25 三井化学株式会社 オレフィン気相重合の停止方法、オレフィン気相重合の開始方法およびオレフィンの気相重合装置
JP3727426B2 (ja) * 1996-09-18 2005-12-14 三井化学株式会社 オレフィンの気相重合方法
JP2002514248A (ja) 1997-01-13 2002-05-14 イーストマン ケミカル カンパニー 重合反応の一時的アイドリング
US5844054A (en) * 1997-03-21 1998-12-01 Samples; Paul Kevin Process control in the presence of chromium based catalysts
EP0959081A1 (en) 1998-05-19 1999-11-24 Bp Chemicals S.N.C. Gas phase polymerisation process
GB0008770D0 (en) * 2000-04-10 2000-05-31 Bp Chem Int Ltd Polymerisation process
US6388027B1 (en) * 2000-10-24 2002-05-14 Union Carbide Chemicals & Plastics Technology Corporation Transition strategy for the production of sticky polymers
JP2002265507A (ja) * 2001-03-09 2002-09-18 Sumitomo Chem Co Ltd オレフィンの気相流動床式重合反応におけるシーティング防止
US6523104B2 (en) * 2001-07-13 2003-02-18 Mips Technologies, Inc. Mechanism for programmable modification of memory mapping granularity

Also Published As

Publication number Publication date
AR042689A1 (es) 2005-06-29
CA2508284A1 (en) 2004-07-22
US20040143076A1 (en) 2004-07-22
EP1578807B1 (en) 2011-01-05
AU2003293226A1 (en) 2004-07-29
US6841630B2 (en) 2005-01-11
JP2006512450A (ja) 2006-04-13
EP1578807A4 (en) 2006-02-01
DE60335658D1 (de) 2011-02-17
WO2004060929A1 (en) 2004-07-22
EP1578807A1 (en) 2005-09-28

Similar Documents

Publication Publication Date Title
BR0317851A (pt) Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos
BR0317845A (pt) Processos para a transição entre vários catalisadores de polimerização
BR0317830A (pt) Processos para efetuar transição entre catalisadores de polimerização metalocênicos e ziegler-natta
AR002335A1 (es) Proceso de transicion y conversion entre reacciones de polimerizacion catalizadas por catalizadores incompatibles entre si
DE69737368D1 (de) Katalysatorkomponenten für die olefinpolymerisation, polymerisationskatalysatoren und verfharen zur olefinpolymerisierung unter verwendung derselben
ATE291030T1 (de) Substituierte metallocenverbindungen für olefinpolymerisationkatalysatorsystemen, deren zwischenverbindungen und verfahren zu ihrer herstellung
BR9506039A (pt) Componentes e catalisadores para a polímerização de olefinas
BR0215743A (pt) Processos para produção de um catalisador de polimerização de olefinas, para converter uma solução, e para (co) polimerização de uma olefina, catalisador para (co) polimerização de uma olefina, uso do componente catalisador, e, poliolefinas
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE69914278D1 (de) Katalysatorbestandteile für die olefinpolymerisation
BR9813438B1 (pt) processo para polimerizaÇço de olefinas, pelÍcula e polÍmero de etileno-alfa-olefina.
DE69935137D1 (de) Polymerträgerkatalysatoren für olefinpolymerisation
ATE232878T1 (de) Imidochromverbindungen in katalysatorsystemen für die olefinpolymerisation
ATE282641T1 (de) Vorpolymerisierte katalysatorbestandteile für die olefinpolymerisation
ES2167488T3 (es) Catalizadores ziegler-natta con metalocenos para la polimerizacion de olefinas.
AU2003302033A1 (en) Multiple catalyst system for olefin polymerization and polymers produced therefrom
AU2003257448A1 (en) Catalyst system for the polymerization of olefins
DE69829644D1 (de) Katalysatorzusammensetzung für die olefinpolymerisation mit erhöhter aktivität
ES2196529T3 (es) Composicion de catalizadores para la produccion de polimeros de olefina.
DE69823988D1 (de) Gruppe 8-10 übergangsmetallkatalysator für die polymerisation von olefinen
WO2008036591A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
BRPI0515844A (pt) métodos para prolongar a utilização de um catalisador
DE60130096D1 (de) Übergangsmetallverbindungen, polymerisationskatalysatoren für olefine, olefinpolymere und verfahren zu deren herstellung
BR0317761A (pt) Processos para transição entre catalisadores de polimerização de sìtio único com base em alumoxano e ziegler-natta
DE19981705T1 (de) y-Oxo-Bis-Metallocen-Komplexvrbindungen und Katalysatoren, die dieselben für die Polymerisation von Olefinen verwenden, sowie Polymerisationsverfahren

Legal Events

Date Code Title Description
B08F Application fees: application dismissed [chapter 8.6 patent gazette]

Free format text: REFERENTE 7A. E 8A. ANUIDADE(S).

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2129 DE 25/10/2011.