BR0318111A - Solução de resole aquosa de alto peso molecular, processo de fabricação da mesma, e resinas de ligação - Google Patents
Solução de resole aquosa de alto peso molecular, processo de fabricação da mesma, e resinas de ligaçãoInfo
- Publication number
- BR0318111A BR0318111A BR0318111-1A BR0318111A BR0318111A BR 0318111 A BR0318111 A BR 0318111A BR 0318111 A BR0318111 A BR 0318111A BR 0318111 A BR0318111 A BR 0318111A
- Authority
- BR
- Brazil
- Prior art keywords
- high molecular
- manufacturing process
- molecular weight
- phenol
- resin solution
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title abstract 4
- 239000011347 resin Substances 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- 150000007965 phenolic acids Chemical class 0.000 abstract 1
- -1 phenolic carboxylate Chemical class 0.000 abstract 1
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical class OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/32—Chemically modified polycondensates by organic acids or derivatives thereof, e.g. fatty oils
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
"SOLUçãO DE RESOLE AQUOSA DE ALTO PESO MOLECULAR, PROCESSO DE FABRICAçãO DA MESMA, E RESINAS DE LIGAçãO". A presente invenção está orientada a composições e processos que conduzem a resoles de fenol-formaldeído incolores ou levemente coloridos. Diferente das tecnologias anteriores, as referidas composições conduzem a resinas claras, estáveis em armazenamento, de rápida cura, e de alto peso molecular. Os referidos materiais são também capazes de produzir painéis de madeira compósitos com resultados de testes superiores de absorção de água e de espessura de dilatação quando embebidos em água. A presente invenção essencialmente consiste em um copolímero aquoso de fenol formaldeído e um carboxilato fenólico (por exemplo, ácido salicílico). Metilol fenóis são formados sob condições alcalinas na presença de agentes quelantes de metal. Os referidos são então condensados em um polímero sob condições alcalinas, neutras ou acídicas. A solução de polímero aquosa acabada é então acidificada ao pH desejado usando ácido benzóico ou um ácido fenol-carboxílico.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/365,873 US6699958B1 (en) | 2003-02-13 | 2003-02-13 | Colorless phenol-formaldehyde resins that cure colorless |
| PCT/US2003/007064 WO2004074339A1 (en) | 2003-02-13 | 2003-03-04 | Colorless phenol-formaldehyde resins that cure colorless |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0318111A true BR0318111A (pt) | 2006-02-07 |
| BR0318111B1 BR0318111B1 (pt) | 2013-04-24 |
Family
ID=31715616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0318111-1A BR0318111B1 (pt) | 2003-02-13 | 2003-03-04 | soluÇço de resole aquosa de alto peso molecular, processo para a preparaÇço de uma soluÇço de resole aquosa de alto peso molecular, resina de ligaÇço, resina curada e resina aquosa clara. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6699958B1 (pt) |
| EP (1) | EP1592725B1 (pt) |
| CN (1) | CN101087825B (pt) |
| AR (1) | AR043152A1 (pt) |
| AU (1) | AU2003218011B2 (pt) |
| BR (1) | BR0318111B1 (pt) |
| NO (1) | NO20052357L (pt) |
| NZ (1) | NZ539894A (pt) |
| PL (1) | PL376615A1 (pt) |
| RU (1) | RU2298018C2 (pt) |
| WO (1) | WO2004074339A1 (pt) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2437869B (en) * | 2005-01-21 | 2010-06-16 | Fairmount Minerals Ltd | Soluble diverting agents |
| GB0612760D0 (en) * | 2006-06-28 | 2006-08-09 | Bac2 Ltd | Conductive polymer |
| CA2711678A1 (en) * | 2008-01-09 | 2009-07-16 | Molecular Insight Pharmaceuticals, Inc. | Inhibitors of carbonic anhydrase ix |
| US8241599B2 (en) * | 2009-06-01 | 2012-08-14 | Afton Chemical Corporation | Method of using volatile organometallics as biomass gasification catalysts |
| US8617720B2 (en) | 2009-12-21 | 2013-12-31 | E I Du Pont De Nemours And Company | Electroactive composition and electronic device made with the composition |
| JP6325813B2 (ja) | 2012-12-27 | 2018-05-16 | 栗田工業株式会社 | ピッチ抑制剤、ピッチ抑制方法、及び脱墨パルプの製造方法 |
| CN111825818B (zh) | 2013-10-17 | 2023-11-21 | Si集团有限公司 | 原位烷基苯酚-醛树脂 |
| EP3058004A1 (en) * | 2013-10-17 | 2016-08-24 | SI Group, Inc. | Modified alkylphenol-aldehyde resins stabilized by a salicylic acid |
| WO2018053001A2 (en) * | 2016-09-14 | 2018-03-22 | Hexion Inc. | Method for bonding lignocellulosic material with phenolic resin and gaseous carbon dioxide |
| EP4389789A1 (en) * | 2022-12-21 | 2024-06-26 | Prefere Resins Holding GmbH | Use of hydroxybenzoic acid to modify a benzyl ether type resin |
| WO2026139443A1 (en) * | 2024-12-23 | 2026-07-02 | Prefere Resins Holding Gmbh | Use of aromatic carboxylic acids as modifying agents for aldehyde based resins for the production of mineral wool |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL133772C (pt) | 1960-02-17 | 1900-01-01 | ||
| US3624038A (en) | 1970-11-05 | 1971-11-30 | Johnson & Johnson | Phenol formaldehyde resin consisting of an aryl or alkyl substituted phenol-hcho condensate and an alkaline earth metal carboxylate salt of a hydroxy ring substituted aromatic or phenyl substituted aliphatic acid |
| US3905935A (en) | 1973-01-15 | 1975-09-16 | Hercules Inc | Dye laking resins for printing inks |
| US4173684A (en) | 1977-09-06 | 1979-11-06 | The Mead Corporation | Production of novel metal modified novolak resins and their use in pressure sensitive papers |
| US4226962A (en) | 1977-09-06 | 1980-10-07 | The Mead Corporation | Production of novel metal modified novolak resins and their use in pressure sensitive papers |
| DE2741484A1 (de) | 1977-09-15 | 1979-03-22 | Bayer Ag | Kondensationsprodukte |
| US4200706A (en) | 1978-05-30 | 1980-04-29 | Conoco, Inc. | Curing of phenol-formaldehyde resins |
| US4264671A (en) * | 1978-08-02 | 1981-04-28 | Weyerhaeuser Company | Phenol formaldehyde resoles and laminates |
| US4281098A (en) | 1978-10-25 | 1981-07-28 | Bp Chemicals Limited | Control of phenol/aldehyde condensation reactions |
| JPS55155013A (en) | 1979-05-21 | 1980-12-03 | Sumitomo Bakelite Co Ltd | Preparation of quick-curing phenol resin |
| DE2944090A1 (de) | 1979-10-31 | 1981-05-14 | Bayer Ag, 5090 Leverkusen | Formaldehyd-kondensate, ihre herstellung und verwendung als fixiermittel |
| US4612254A (en) | 1985-03-07 | 1986-09-16 | Occidental Chemical Corporation | Aromatic carboxylic acid and metal-modified phenolic resins and methods of preparation |
| JPH0623226B2 (ja) | 1986-11-25 | 1994-03-30 | 住友デュレズ株式会社 | 速硬化フエノ−ル樹脂の製造方法 |
| US5262495A (en) | 1990-08-02 | 1993-11-16 | Borden, Inc. | Retarders for curing phenolic resole resins containing an aggregate material |
| US5208274A (en) | 1990-08-02 | 1993-05-04 | Borden, Inc. | Retarders for hardening phenolic resins |
| US5145913A (en) | 1990-08-02 | 1992-09-08 | Borden, Inc. | Retarders for curing phenolic resole resins |
| US5096983A (en) | 1990-08-02 | 1992-03-17 | Borden, Inc. | Method for making a phenolic resole resin composition having extended work life |
| DE4028534A1 (de) | 1990-09-07 | 1992-03-12 | Bayer Ag | Armomatische kondensationsprodukte |
| WO1992017528A1 (en) * | 1991-04-05 | 1992-10-15 | Barry William Ryan | Improved phenol formaldehyde resins |
| EP0588013B1 (de) | 1992-09-17 | 1998-07-15 | Bakelite AG | Wässrige Resollösung, Verfahren zu ihrer Herstellung und Verwendung |
| US5364902A (en) | 1992-12-15 | 1994-11-15 | Borden, Inc. | Resorcinol-glutaraldehyde resin as an accelerator for curing phenol-formaldehyde resins |
| CA2101765C (en) | 1993-05-17 | 1999-03-16 | Earl K. Phillips | Method for bonding lignocellulosic material with phenol-formaldehyde resin and carbon dioxide |
| AUPO867197A0 (en) | 1997-08-19 | 1997-09-11 | Ryan, Barry William | Phenol formaldehyde resins |
| US6113729A (en) | 1998-08-10 | 2000-09-05 | Borden Chemical, Inc. | Wax sizing and resin bonding of a lignocellulosic composite |
| IT1313700B1 (it) * | 1999-12-17 | 2002-09-09 | 3V Sigma Spa | Composizioni anti-incrostazione e loro impiego nei processi dipolimerizzazione. |
-
2003
- 2003-02-13 US US10/365,873 patent/US6699958B1/en not_active Expired - Fee Related
- 2003-03-04 PL PL376615A patent/PL376615A1/pl not_active Application Discontinuation
- 2003-03-04 BR BRPI0318111-1A patent/BR0318111B1/pt active IP Right Grant
- 2003-03-04 WO PCT/US2003/007064 patent/WO2004074339A1/en not_active Ceased
- 2003-03-04 CN CN038259591A patent/CN101087825B/zh not_active Expired - Lifetime
- 2003-03-04 NZ NZ539894A patent/NZ539894A/en not_active IP Right Cessation
- 2003-03-04 AU AU2003218011A patent/AU2003218011B2/en not_active Expired
- 2003-03-04 RU RU2005128516/04A patent/RU2298018C2/ru active
- 2003-03-04 EP EP03713990.4A patent/EP1592725B1/en not_active Expired - Lifetime
-
2004
- 2004-02-11 AR ARP040100424A patent/AR043152A1/es active IP Right Grant
-
2005
- 2005-05-12 NO NO20052357A patent/NO20052357L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1592725A1 (en) | 2005-11-09 |
| NZ539894A (en) | 2007-01-26 |
| RU2298018C2 (ru) | 2007-04-27 |
| PL376615A1 (pl) | 2006-01-09 |
| AR043152A1 (es) | 2005-07-20 |
| BR0318111B1 (pt) | 2013-04-24 |
| NO20052357D0 (no) | 2005-05-12 |
| CN101087825A (zh) | 2007-12-12 |
| US6699958B1 (en) | 2004-03-02 |
| EP1592725B1 (en) | 2013-05-08 |
| WO2004074339A1 (en) | 2004-09-02 |
| AU2003218011B2 (en) | 2008-09-04 |
| EP1592725A4 (en) | 2006-12-20 |
| NO20052357L (no) | 2005-09-12 |
| RU2005128516A (ru) | 2006-01-27 |
| CN101087825B (zh) | 2012-01-04 |
| AU2003218011A1 (en) | 2004-09-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 24/04/2013, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25D | Requested change of name of applicant approved | ||
| B25D | Requested change of name of applicant approved |