BR9405401A - Banho refratário para produzir revestimentos de moldes - Google Patents
Banho refratário para produzir revestimentos de moldesInfo
- Publication number
- BR9405401A BR9405401A BR9405401-0A BR9405401A BR9405401A BR 9405401 A BR9405401 A BR 9405401A BR 9405401 A BR9405401 A BR 9405401A BR 9405401 A BR9405401 A BR 9405401A
- Authority
- BR
- Brazil
- Prior art keywords
- carbide
- oxide
- pct
- titanium
- inorganic
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title abstract 3
- -1 chromite Chemical compound 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 2
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052845 zircon Inorganic materials 0.000 abstract 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052580 B4C Inorganic materials 0.000 abstract 1
- 229910052582 BN Inorganic materials 0.000 abstract 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 1
- 239000001095 magnesium carbonate Substances 0.000 abstract 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 1
- 235000014380 magnesium carbonate Nutrition 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000001247 metal acetylides Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011490 mineral wool Substances 0.000 abstract 1
- 229910052863 mullite Inorganic materials 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mold Materials And Core Materials (AREA)
- Paints Or Removers (AREA)
- Ceramic Products (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Materials For Medical Uses (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Paper (AREA)
- Jellies, Jams, And Syrups (AREA)
- Confectionery (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
Patente de Invenção de "BANHO REFRATóRIO PARA PRODUZIR REVESTIMENTOS DE MOLDES", cujo componente principal consiste de materiais inorgânicos granulados finíssimos com qualidades refratária até altamente refratária. O banho refratário apresenta tipicamente um teor de esferas ocas inorgânicas em uma quantidade que vai de 1 a 40% em peso em relação ao banho refratário pronto para o uso. Elas podem conter, além disso, de 0,1 a 10% em peso de fibras orgânicas ou inorgânicas em relação ao banho refratário pronto para o uso. As esferas ocas são enchidas preferecialmente com um gás inerte. Elas podem consistir de óxidos, tais como óxido de alumínio, quartzo, magnesita, mulita, cromita, óxido de zircónico e/ou óxido de titânio; de boretos, carbonetos, nitretos, tais como carboneto de silício, carboneto de titânio, boreto de titânio, nitrito de boro e/ou carboneto de boro; de carbono, vidro ou metais ou misturas dos mesmos. As fibras apresentam um diâmetro de 1 a 30 microns, preferencialmente de 3 a 10 microns e um comprimento de 10 a 5000 microns, preferencialmente de 100 a 500 microns. Quando as fibras são do tipo inorgânico, elas podem consistir de silicatos de alumínio, óxido de alúminio, óxido de titânio, carbono, carboneto de silício, carboneto de titânio, boreto de titânio, nitreto de boro, carboneto de boro, vidro, basalto ou lã mineral ou misturas dos mesmos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE9307468U DE9307468U1 (de) | 1993-05-17 | 1993-05-17 | Schlichte zur Herstellung von Formüberzügen |
| PCT/DE1994/000555 WO1994026440A1 (de) | 1993-05-17 | 1994-05-11 | Schlichte zur herstellung von formüberzügen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9405401A true BR9405401A (pt) | 1999-09-08 |
Family
ID=6893374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9405401-0A BR9405401A (pt) | 1993-05-17 | 1994-05-11 | Banho refratário para produzir revestimentos de moldes |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5573580A (pt) |
| EP (1) | EP0649356B1 (pt) |
| JP (1) | JP2938570B2 (pt) |
| KR (1) | KR950702459A (pt) |
| CN (1) | CN1109678A (pt) |
| AT (1) | ATE145573T1 (pt) |
| AU (1) | AU677661B2 (pt) |
| BG (1) | BG61438B1 (pt) |
| BR (1) | BR9405401A (pt) |
| CA (1) | CA2139871A1 (pt) |
| CZ (1) | CZ284147B6 (pt) |
| DE (2) | DE9307468U1 (pt) |
| ES (1) | ES2095164T3 (pt) |
| HU (1) | HU213910B (pt) |
| PL (1) | PL178048B1 (pt) |
| RO (1) | RO115336B1 (pt) |
| SK (1) | SK281533B6 (pt) |
| WO (1) | WO1994026440A1 (pt) |
| ZA (1) | ZA943357B (pt) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2297285A (en) * | 1995-01-25 | 1996-07-31 | T & N Technology Ltd | Investment casting mould |
| FR2755384B1 (fr) * | 1996-11-06 | 1998-11-27 | Usinor Sacilor | Enduit protecteur pour elements en materiau refractaire d'une lingotiere de coulee continue des metaux, et elements en materiau refractaire protege a l'aide de cet enduit |
| CN1049166C (zh) * | 1997-10-08 | 2000-02-09 | 冶金工业部钢铁研究总院 | 薄壁铸件铸造用涂料 |
| DE10011977C1 (de) * | 2000-03-11 | 2001-08-16 | Schaefer Chem Fab Gmbh | Schlichte zum Beschichten von Sandgußformteilen für die Fertigung von Gußteilen aus Magnesium und Magnesiumlegierungen |
| US6576330B1 (en) * | 2000-07-28 | 2003-06-10 | Rex Roto Technologies, Inc. | Boron nitride paste composition, boron nitride “shell” coated ceramic structure, and process of manufacturing |
| DE10344073A1 (de) * | 2003-09-23 | 2005-04-28 | Daimler Chrysler Ag | Kurbelwelle mit kombiniertem Antriebszahnrad sowie Verfahren zu ihrer Herstellung und deren Verwendung |
| DE102005023592A1 (de) * | 2004-05-18 | 2005-12-15 | Schuster, Lothar, Dipl.-Ing. | Wandfarbe für Innenanstriche |
| DE102004042535B4 (de) * | 2004-09-02 | 2019-05-29 | Ask Chemicals Gmbh | Formstoffmischung zur Herstellung von Gießformen für die Metallverarbeitung, Verfahren und Verwendung |
| US7507284B2 (en) * | 2004-09-17 | 2009-03-24 | The Hill And Griffith Company | Sandcasting pattern coating compositions containing graphite |
| DE102004060649A1 (de) * | 2004-12-16 | 2006-06-29 | Ashland-Südchemie-Kernfest GmbH | Hochisolierende und feuerfeste Beschichtungsmassen für Gießformen |
| DE102005041863A1 (de) * | 2005-09-02 | 2007-03-29 | Ashland-Südchemie-Kernfest GmbH | Borsilikatglashaltige Formstoffmischungen |
| CN100347257C (zh) * | 2006-03-16 | 2007-11-07 | 沈阳金安铸造材料厂 | 一种无污染水基浸涂涂料 |
| JP2008119727A (ja) * | 2006-11-13 | 2008-05-29 | Honda Motor Co Ltd | 鋳造用金型及びその製造方法 |
| DE102006058123A1 (de) * | 2006-12-09 | 2008-06-19 | Mahle International Gmbh | Formkörper zur Herstellung eines Hohlraumes |
| CN101157561B (zh) * | 2007-09-05 | 2011-08-31 | 江苏国窑科技有限公司 | 耐磨耐火可塑料 |
| DE102008025311A1 (de) * | 2008-05-27 | 2009-12-03 | Ashland-Südchemie-Kernfest GmbH | Geruchs- und schadstoffadsorbierende Beschichtungsmasse für den kastengebundenen Metallguss |
| DE102009032668A1 (de) | 2009-07-09 | 2011-01-13 | Hüttenes-Albertus Chemische Werke GmbH | Schlichte zur Herstellung von Formüberzügen |
| DK2364795T3 (da) * | 2010-03-08 | 2012-10-22 | Foseco Int | Coatingsammensætning til støbegods |
| KR101105487B1 (ko) * | 2010-03-24 | 2012-01-13 | 임호열 | 집진기에서 채취되는 뮬라이트·코란덤계 세라믹주물사의 분진을 내화기재로 사용한 주형도형재 |
| CN102336575B (zh) * | 2010-06-17 | 2016-08-03 | 旭硝子陶瓷株式会社 | 绝热浇注料用粉末组合物和使用其的绝热浇注料 |
| CN102527954B (zh) * | 2010-12-31 | 2013-12-11 | 江西稀有稀土金属钨业集团有限公司 | 水冷锭模系统的模板保护套和保护方法 |
| CN102249713A (zh) * | 2011-05-31 | 2011-11-23 | 浙江大学 | 一种镁钛空心球及其制备方法 |
| CN102249716A (zh) * | 2011-05-31 | 2011-11-23 | 傅晓云 | 一种耐高温空心球及其制备方法 |
| CN102249717A (zh) * | 2011-05-31 | 2011-11-23 | 浙江大学 | 一种镁铝钙空心球及其制备方法 |
| CN102249712A (zh) * | 2011-05-31 | 2011-11-23 | 浙江大学 | 一种镁钙空心球及其制备方法 |
| CN102295462A (zh) * | 2011-05-31 | 2011-12-28 | 浙江大学 | 一种镁铬空心球及其制备方法 |
| CN102249714A (zh) * | 2011-05-31 | 2011-11-23 | 浙江大学 | 一种铝钛空心球及其制备方法 |
| CN102249715A (zh) * | 2011-05-31 | 2011-11-23 | 浙江大学 | 一种铬刚玉空心球及其制备方法 |
| CN102295463A (zh) * | 2011-05-31 | 2011-12-28 | 浙江大学 | 一种锆刚玉空心球及其制备方法 |
| CN102372490A (zh) * | 2011-08-08 | 2012-03-14 | 河南三兴热能技术有限公司 | 耐火纤维反辐射抗冲刷涂料 |
| RU2521540C2 (ru) * | 2012-10-19 | 2014-06-27 | Общество с ограниченной ответственностью "Синтез-Плюс" | Термостойкий керамический композит |
| DE102012113074A1 (de) * | 2012-12-22 | 2014-07-10 | Ask Chemicals Gmbh | Formstoffmischungen enthaltend Metalloxide des Aluminiums und Zirkoniums in partikulärer Form |
| CN103551496B (zh) * | 2013-10-29 | 2015-09-02 | 新疆华莎能源股份有限公司 | 无水水基镁橄榄石粉状涂料 |
| CN103639359B (zh) * | 2013-11-01 | 2018-02-16 | 南昌航空大学 | 一种基于复合纤维增强熔模精铸型壳的制备方法 |
| US9192983B2 (en) * | 2013-11-26 | 2015-11-24 | General Electric Company | Silicon carbide-containing mold and facecoat compositions and methods for casting titanium and titanium aluminide alloys |
| CN104874722A (zh) * | 2015-05-20 | 2015-09-02 | 柳州市百田机械有限公司 | 耐高温铸造涂料 |
| CN105057578A (zh) * | 2015-08-11 | 2015-11-18 | 张燕 | 钒铁渣-火电厂粉煤灰消失模铸造涂料及其制备方法 |
| CN105057579A (zh) * | 2015-08-11 | 2015-11-18 | 张燕 | 钒铁渣-蓝晶石尾矿消失模铸造涂料及其制备方法 |
| CN105170886A (zh) * | 2015-09-06 | 2015-12-23 | 张燕 | 钒铁渣-煤矸石消失模铸造涂料及其制备方法 |
| CN105170885A (zh) * | 2015-09-06 | 2015-12-23 | 张燕 | 钒铁渣-石棉尾矿消失模铸造涂料及其制备方法 |
| CN105418097B (zh) * | 2015-12-23 | 2018-06-29 | 云南清朗能源科技有限公司 | 耐火内衬材料及其制备方法 |
| CN105750481B (zh) * | 2016-03-31 | 2017-12-26 | 宁夏共享化工有限公司 | 一种防止大型铸钢件橘皮缺陷的水基涂料 |
| CN105817608B (zh) * | 2016-04-29 | 2019-01-18 | 南京宝泰特种材料股份有限公司 | 一种钛合金熔炼浇铸方法 |
| CN106563773B (zh) * | 2016-10-19 | 2018-06-26 | 江苏大学 | 一种基于激光加热技术防止单晶叶片杂晶缺陷的方法 |
| CN107511449A (zh) * | 2017-09-01 | 2017-12-26 | 东风精密铸造安徽有限公司 | 一种铸造砂型用涂料 |
| CN109535924A (zh) * | 2018-10-22 | 2019-03-29 | 安徽大天铸业有限责任公司 | 一种壳型内表面涂料配方及其制备方法 |
| DE102019116702A1 (de) * | 2019-06-19 | 2020-12-24 | Ask Chemicals Gmbh | Geschlichtete Gießformen erhältlich aus einer Formstoffmischung enthaltend ein anorganisches Bindemittel und Phosphat- und oxidische Borverbindungen, ein Verfahren zu deren Herstellung und deren Verwendung |
| CN110586854B (zh) * | 2019-10-21 | 2021-07-30 | 沈阳铸造研究所有限公司 | 一种铸造用快干水基涂料及其制备方法 |
| CN112846143B (zh) * | 2020-12-31 | 2022-05-13 | 厦门市佳嘉达机械有限公司 | 一种高强韧可压铸砂芯及其制备方法及压铸件的成型工艺 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4174331A (en) * | 1972-06-23 | 1979-11-13 | The Carborundum Company | Refractory moldable composition containing ceramic fiber and colloidal silica |
| DD98625A1 (pt) * | 1972-09-11 | 1973-07-12 | ||
| US3804701A (en) * | 1973-08-06 | 1974-04-16 | Oglebay Norton Co | Insulating compositions and structures formed therefrom for use in hot topping comprising fibrous wollastonite |
| US4012262A (en) * | 1974-02-08 | 1977-03-15 | Denis Arthur John Patterson | Manufacture of thermally-insulating, refractory articles |
| JPS5841931B2 (ja) * | 1978-01-25 | 1983-09-16 | 福島製鋼株式会社 | 鋳造用鋳型 |
| GB2081246B (en) * | 1980-07-25 | 1984-03-14 | Rolls Royce | Thermal barrier coating composition |
| FR2523003A1 (fr) * | 1982-03-15 | 1983-09-16 | Battelle Memorial Institute | Moule pour la coulee d'objets de faible epaisseur en metal ou en alliage a bas point de fusion, et procede de recouvrement de la surface active de ce moule |
| DE3525847A1 (de) * | 1985-07-19 | 1987-01-22 | Didier Werke Ag | Schlichte zur herstellung von rberzuegen |
| DE3720878A1 (de) * | 1987-06-24 | 1989-01-05 | Carl Dellmann Gmbh | Ueberzugsmaterial fuer giessrinnen |
| SE463513B (sv) * | 1988-07-21 | 1990-12-03 | Eka Nobel Ab | Komposition foer beredning av en vaermeisolerande keramisk belaeggning paa en metall, foerfarande foer dess framstaellning, anvaendning av densamma samt avgasroer foersett med en belaeggning av en saadan komposition |
| JPH03291125A (ja) * | 1990-04-05 | 1991-12-20 | Hitachi Metals Ltd | 塗型剤 |
| DE4203904C1 (en) * | 1992-02-11 | 1993-04-01 | Metallgesellschaft Ag, 6000 Frankfurt, De | Ready-to-use size for coating moulds for casting - comprises fire-proof inorganic aluminium oxide particles, additives and fibres, forming agglomerate-free coating |
| US5215143A (en) * | 1992-11-16 | 1993-06-01 | American Colloid Company | Non-porous carbon molding (foundry) sand and method of casting |
-
1993
- 1993-05-17 DE DE9307468U patent/DE9307468U1/de not_active Expired - Lifetime
-
1994
- 1994-05-11 PL PL94307061A patent/PL178048B1/pl unknown
- 1994-05-11 RO RO95-00048A patent/RO115336B1/ro unknown
- 1994-05-11 CZ CZ9551A patent/CZ284147B6/cs not_active IP Right Cessation
- 1994-05-11 JP JP6524821A patent/JP2938570B2/ja not_active Expired - Lifetime
- 1994-05-11 KR KR1019950700153A patent/KR950702459A/ko not_active Withdrawn
- 1994-05-11 AT AT94914344T patent/ATE145573T1/de not_active IP Right Cessation
- 1994-05-11 BR BR9405401-0A patent/BR9405401A/pt not_active IP Right Cessation
- 1994-05-11 WO PCT/DE1994/000555 patent/WO1994026440A1/de not_active Ceased
- 1994-05-11 DE DE59401151T patent/DE59401151D1/de not_active Expired - Lifetime
- 1994-05-11 SK SK54-95A patent/SK281533B6/sk unknown
- 1994-05-11 CN CN94190284A patent/CN1109678A/zh active Pending
- 1994-05-11 HU HU9500128A patent/HU213910B/hu not_active IP Right Cessation
- 1994-05-11 ES ES94914344T patent/ES2095164T3/es not_active Expired - Lifetime
- 1994-05-11 CA CA002139871A patent/CA2139871A1/en not_active Abandoned
- 1994-05-11 EP EP94914344A patent/EP0649356B1/de not_active Expired - Lifetime
- 1994-05-11 AU AU66764/94A patent/AU677661B2/en not_active Ceased
- 1994-05-16 ZA ZA943357A patent/ZA943357B/xx unknown
- 1994-05-17 US US08/362,523 patent/US5573580A/en not_active Expired - Lifetime
-
1995
- 1995-01-09 BG BG99338A patent/BG61438B1/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE59401151D1 (de) | 1997-01-09 |
| JPH07509409A (ja) | 1995-10-19 |
| KR950702459A (ko) | 1995-07-29 |
| EP0649356A1 (de) | 1995-04-26 |
| BG61438B1 (en) | 1997-08-29 |
| PL178048B1 (pl) | 2000-02-29 |
| US5573580A (en) | 1996-11-12 |
| HUT70065A (en) | 1995-09-28 |
| BG99338A (bg) | 1995-10-31 |
| ES2095164T3 (es) | 1997-02-01 |
| JP2938570B2 (ja) | 1999-08-23 |
| WO1994026440A1 (de) | 1994-11-24 |
| HU9500128D0 (en) | 1995-03-28 |
| ATE145573T1 (de) | 1996-12-15 |
| AU6676494A (en) | 1994-12-12 |
| SK281533B6 (sk) | 2001-04-09 |
| CZ5195A3 (en) | 1995-06-14 |
| CZ284147B6 (cs) | 1998-08-12 |
| AU677661B2 (en) | 1997-05-01 |
| EP0649356B1 (de) | 1996-11-27 |
| SK5495A3 (en) | 1996-03-06 |
| CA2139871A1 (en) | 1994-11-24 |
| HU213910B (en) | 1997-11-28 |
| CN1109678A (zh) | 1995-10-04 |
| PL307061A1 (en) | 1995-05-02 |
| ZA943357B (en) | 1995-03-14 |
| RO115336B1 (ro) | 2000-01-28 |
| DE9307468U1 (de) | 1994-09-29 |
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