BR9809129A - Processo de óxido de propileno usando catalisadores de prata suportados em composto de metal alcalino-terroso, contendo promotores de tungstênio e potássio - Google Patents
Processo de óxido de propileno usando catalisadores de prata suportados em composto de metal alcalino-terroso, contendo promotores de tungstênio e potássioInfo
- Publication number
- BR9809129A BR9809129A BR9809129-8A BR9809129A BR9809129A BR 9809129 A BR9809129 A BR 9809129A BR 9809129 A BR9809129 A BR 9809129A BR 9809129 A BR9809129 A BR 9809129A
- Authority
- BR
- Brazil
- Prior art keywords
- propylene oxide
- earth metal
- metal compound
- potassium
- containing tungsten
- Prior art date
Links
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title abstract 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052700 potassium Inorganic materials 0.000 title abstract 4
- 239000011591 potassium Substances 0.000 title abstract 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052721 tungsten Inorganic materials 0.000 title abstract 4
- 239000010937 tungsten Substances 0.000 title abstract 4
- 150000001341 alkaline earth metal compounds Chemical class 0.000 title abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052709 silver Inorganic materials 0.000 title abstract 2
- 239000004332 silver Substances 0.000 title abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- HFNFNEXNHWZCIJ-UHFFFAOYSA-N [Ag].C1C(C)O1 Chemical compound [Ag].C1C(C)O1 HFNFNEXNHWZCIJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical compound [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Patente de Invenção<B>"PROCESSO DE óXIDO DE PROPILENO USANDO CATALISADORES DE PRATA SUPORTADOS EM COMPOSTO DE METAL ALCALINO-TERROSO, CONTENDO PROMOTORES DE TUNGSTêNIO E POTáSSIO"<D> Oxidação direta de propileno a óxido de propileno é realizada usando-se catalisadores de prata suportados em composto de metal alcalino-terroso, contendo promotores de tungstênio e de potássio. Em uma concretização da invenção, o promotor de tungstênio e o promotor de potássio são introduzidos de maneira simultânea por meio do uso de tungstato de potássio. Catalisadores desse tipo exibem produtividade em óxido de propileno elevadas de maneira não usual, quando dióxido de carbono está presente na corrente de alimentação.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/862,457 US5861519A (en) | 1997-05-23 | 1997-05-23 | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters |
| PCT/EP1998/002422 WO1998052931A1 (en) | 1997-05-23 | 1998-04-23 | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9809129A true BR9809129A (pt) | 2000-08-01 |
Family
ID=25338534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9809129-8A BR9809129A (pt) | 1997-05-23 | 1998-04-23 | Processo de óxido de propileno usando catalisadores de prata suportados em composto de metal alcalino-terroso, contendo promotores de tungstênio e potássio |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5861519A (pt) |
| EP (1) | EP0983253B1 (pt) |
| JP (1) | JP2001527563A (pt) |
| KR (1) | KR20010012888A (pt) |
| CN (1) | CN1102929C (pt) |
| AU (1) | AU7431798A (pt) |
| BR (1) | BR9809129A (pt) |
| CA (1) | CA2287078A1 (pt) |
| DE (1) | DE69806927T2 (pt) |
| ES (1) | ES2181218T3 (pt) |
| WO (1) | WO1998052931A1 (pt) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001229525A1 (en) * | 2000-02-22 | 2001-09-03 | Arco Chemical Technology, L.P. | Direct epoxidation process using improved catalyst composition |
| DE10064301A1 (de) * | 2000-12-22 | 2002-07-04 | Basf Ag | Silberkatalysator für die Epoxidation von Alkenen |
| US6392066B1 (en) | 2001-02-22 | 2002-05-21 | Sri International | Epoxidation of olefins using lanthanide-promoted silver catalysts |
| US6509485B2 (en) | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
| AU2003278999A1 (en) | 2002-09-30 | 2004-04-23 | Shell Oil Company | Calcium carbonate carrier for making silver based epoxidation catalysts |
| EP2255876A3 (en) * | 2002-10-28 | 2011-06-29 | Shell Internationale Research Maatschappij B.V. | A process for preparing an olefin oxide, a method of using the olefin oxide and a catalyst composition |
| US20050027133A1 (en) * | 2003-07-29 | 2005-02-03 | Saudi Basic Industries Corporation | Method of making a catalyst for direct oxidation of an alkene to an alkene oxide |
| CN101160298B (zh) * | 2005-02-25 | 2011-06-22 | 住友化学株式会社 | 环氧烷烃的制备方法 |
| WO2013098855A1 (en) * | 2011-12-27 | 2013-07-04 | Council Of Scientific & Industrial Research | A process for preparation of ag-w oxide catalyst for the selective conversion of propylene to propylene oxide with molecular oxygen |
| CN113603658A (zh) | 2015-08-28 | 2021-11-05 | 利安德化学技术有限公司 | 环氧化工艺及其使用的催化剂 |
| KR101810328B1 (ko) | 2016-08-22 | 2017-12-19 | 롯데케미칼 주식회사 | 프로필렌 직접산화 반응용 촉매, 이의 제조방법 및 이를 이용한 프로필렌 직접산화 반응에 의한 프로필렌 옥사이드 제조방법 |
| EP3573962A1 (en) | 2017-01-24 | 2019-12-04 | Lyondell Chemical Technology, L.P. | Liquid phase selective oxidation to epoxides with molecular oxygen |
| CN112206798B (zh) * | 2020-10-29 | 2022-03-22 | 润和催化材料(浙江)有限公司 | 一种乙烯氧化制环氧乙烷的银催化剂及其制备方法和应用 |
| CN119701989B (zh) * | 2023-09-27 | 2025-10-14 | 中国石油化工股份有限公司 | 一种改性α-氧化铝载体及其制备方法与银催化剂及其应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1491447A (en) * | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
| US4808738A (en) * | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| US4820675A (en) * | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| EP0357293B1 (en) * | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5112795A (en) * | 1990-10-12 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Supported silver catalyst, and processes for making and using same |
| DK0480538T3 (da) * | 1990-10-12 | 1998-11-02 | Union Carbide Chem Plastic | Alkylenoxidkatalysatorer med forøget aktivitet og/eller stabilitet |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5407888A (en) * | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| DE4314304A1 (de) * | 1992-05-12 | 1993-11-18 | Basf Ag | Silberkatalysator |
| US5502020A (en) * | 1993-04-14 | 1996-03-26 | Mitsubishi Petrochemical Co., Ltd. | Catalyst for production of ethylene oxide and process for producing the catalyst |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| PH11994048580B1 (en) * | 1993-07-07 | 2001-01-12 | Shell Int Research | Epoxidation catalyst |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| DE69507160T2 (de) * | 1994-11-01 | 1999-06-24 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Verfahren zur herstellung von ethylenoxulkatalysatoren |
| US5739075A (en) * | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
| AU2507497A (en) * | 1996-03-29 | 1997-10-22 | Shell Internationale Research Maatschappij B.V. | Epoxidation oxide catalysts |
-
1997
- 1997-05-23 US US08/862,457 patent/US5861519A/en not_active Expired - Fee Related
-
1998
- 1998-04-23 DE DE69806927T patent/DE69806927T2/de not_active Expired - Fee Related
- 1998-04-23 AU AU74317/98A patent/AU7431798A/en not_active Abandoned
- 1998-04-23 KR KR1019997010854A patent/KR20010012888A/ko not_active Abandoned
- 1998-04-23 ES ES98921485T patent/ES2181218T3/es not_active Expired - Lifetime
- 1998-04-23 JP JP54985698A patent/JP2001527563A/ja not_active Ceased
- 1998-04-23 CN CN98805334A patent/CN1102929C/zh not_active Expired - Fee Related
- 1998-04-23 WO PCT/EP1998/002422 patent/WO1998052931A1/en not_active Ceased
- 1998-04-23 CA CA002287078A patent/CA2287078A1/en not_active Abandoned
- 1998-04-23 BR BR9809129-8A patent/BR9809129A/pt not_active IP Right Cessation
- 1998-04-23 EP EP98921485A patent/EP0983253B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001527563A (ja) | 2001-12-25 |
| DE69806927D1 (de) | 2002-09-05 |
| ES2181218T3 (es) | 2003-02-16 |
| EP0983253A1 (en) | 2000-03-08 |
| KR20010012888A (ko) | 2001-02-26 |
| CN1257487A (zh) | 2000-06-21 |
| CA2287078A1 (en) | 1998-11-26 |
| US5861519A (en) | 1999-01-19 |
| AU7431798A (en) | 1998-12-11 |
| DE69806927T2 (de) | 2003-03-13 |
| CN1102929C (zh) | 2003-03-12 |
| WO1998052931A1 (en) | 1998-11-26 |
| EP0983253B1 (en) | 2002-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1891 DE 03/04/2007. |