ES2181218T3 - Procedimiento de obtencion de oxido de propileno que usa catalizadores de plata soportados sobre compuestos de metal alcalino-terreo y que contienen promotores de wolframio y de potasio. - Google Patents
Procedimiento de obtencion de oxido de propileno que usa catalizadores de plata soportados sobre compuestos de metal alcalino-terreo y que contienen promotores de wolframio y de potasio.Info
- Publication number
- ES2181218T3 ES2181218T3 ES98921485T ES98921485T ES2181218T3 ES 2181218 T3 ES2181218 T3 ES 2181218T3 ES 98921485 T ES98921485 T ES 98921485T ES 98921485 T ES98921485 T ES 98921485T ES 2181218 T3 ES2181218 T3 ES 2181218T3
- Authority
- ES
- Spain
- Prior art keywords
- alkaline
- wolframio
- terreo
- procedure
- propylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052709 silver Inorganic materials 0.000 title abstract 3
- 239000004332 silver Substances 0.000 title abstract 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052700 potassium Inorganic materials 0.000 title abstract 2
- 239000011591 potassium Substances 0.000 title abstract 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 title 1
- 150000002736 metal compounds Chemical class 0.000 title 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 150000001339 alkali metal compounds Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para la epoxidación de propileno que comprende poner en contacto una corriente de alimentación que comprende propileno y oxígeno con un catalizador de plata soportado que comprende: (a) un soporte que comprende un compuesto de metal alcalino seleccionado del grupo que consta de carbonatos de metales alcalino-térreos, titanatos de metales alcalino- térreos, y sus mezclas; (b) una cantidad catalíticamente efectiva de plata; (c) una cantidad promotora de un promotor de wolframio; y (d) una cantidad promotora de un promotor de potasio.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/862,457 US5861519A (en) | 1997-05-23 | 1997-05-23 | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2181218T3 true ES2181218T3 (es) | 2003-02-16 |
Family
ID=25338534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98921485T Expired - Lifetime ES2181218T3 (es) | 1997-05-23 | 1998-04-23 | Procedimiento de obtencion de oxido de propileno que usa catalizadores de plata soportados sobre compuestos de metal alcalino-terreo y que contienen promotores de wolframio y de potasio. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5861519A (es) |
| EP (1) | EP0983253B1 (es) |
| JP (1) | JP2001527563A (es) |
| KR (1) | KR20010012888A (es) |
| CN (1) | CN1102929C (es) |
| AU (1) | AU7431798A (es) |
| BR (1) | BR9809129A (es) |
| CA (1) | CA2287078A1 (es) |
| DE (1) | DE69806927T2 (es) |
| ES (1) | ES2181218T3 (es) |
| WO (1) | WO1998052931A1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001229525A1 (en) * | 2000-02-22 | 2001-09-03 | Arco Chemical Technology, L.P. | Direct epoxidation process using improved catalyst composition |
| DE10064301A1 (de) * | 2000-12-22 | 2002-07-04 | Basf Ag | Silberkatalysator für die Epoxidation von Alkenen |
| US6392066B1 (en) | 2001-02-22 | 2002-05-21 | Sri International | Epoxidation of olefins using lanthanide-promoted silver catalysts |
| US6509485B2 (en) | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
| AU2003278999A1 (en) | 2002-09-30 | 2004-04-23 | Shell Oil Company | Calcium carbonate carrier for making silver based epoxidation catalysts |
| EP2255876A3 (en) * | 2002-10-28 | 2011-06-29 | Shell Internationale Research Maatschappij B.V. | A process for preparing an olefin oxide, a method of using the olefin oxide and a catalyst composition |
| US20050027133A1 (en) * | 2003-07-29 | 2005-02-03 | Saudi Basic Industries Corporation | Method of making a catalyst for direct oxidation of an alkene to an alkene oxide |
| CN101160298B (zh) * | 2005-02-25 | 2011-06-22 | 住友化学株式会社 | 环氧烷烃的制备方法 |
| WO2013098855A1 (en) * | 2011-12-27 | 2013-07-04 | Council Of Scientific & Industrial Research | A process for preparation of ag-w oxide catalyst for the selective conversion of propylene to propylene oxide with molecular oxygen |
| CN113603658A (zh) | 2015-08-28 | 2021-11-05 | 利安德化学技术有限公司 | 环氧化工艺及其使用的催化剂 |
| KR101810328B1 (ko) | 2016-08-22 | 2017-12-19 | 롯데케미칼 주식회사 | 프로필렌 직접산화 반응용 촉매, 이의 제조방법 및 이를 이용한 프로필렌 직접산화 반응에 의한 프로필렌 옥사이드 제조방법 |
| EP3573962A1 (en) | 2017-01-24 | 2019-12-04 | Lyondell Chemical Technology, L.P. | Liquid phase selective oxidation to epoxides with molecular oxygen |
| CN112206798B (zh) * | 2020-10-29 | 2022-03-22 | 润和催化材料(浙江)有限公司 | 一种乙烯氧化制环氧乙烷的银催化剂及其制备方法和应用 |
| CN119701989B (zh) * | 2023-09-27 | 2025-10-14 | 中国石油化工股份有限公司 | 一种改性α-氧化铝载体及其制备方法与银催化剂及其应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1491447A (en) * | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
| US4808738A (en) * | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| US4820675A (en) * | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| EP0357293B1 (en) * | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5112795A (en) * | 1990-10-12 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Supported silver catalyst, and processes for making and using same |
| DK0480538T3 (da) * | 1990-10-12 | 1998-11-02 | Union Carbide Chem Plastic | Alkylenoxidkatalysatorer med forøget aktivitet og/eller stabilitet |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5407888A (en) * | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| DE4314304A1 (de) * | 1992-05-12 | 1993-11-18 | Basf Ag | Silberkatalysator |
| US5502020A (en) * | 1993-04-14 | 1996-03-26 | Mitsubishi Petrochemical Co., Ltd. | Catalyst for production of ethylene oxide and process for producing the catalyst |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| PH11994048580B1 (en) * | 1993-07-07 | 2001-01-12 | Shell Int Research | Epoxidation catalyst |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| DE69507160T2 (de) * | 1994-11-01 | 1999-06-24 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Verfahren zur herstellung von ethylenoxulkatalysatoren |
| US5739075A (en) * | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
| AU2507497A (en) * | 1996-03-29 | 1997-10-22 | Shell Internationale Research Maatschappij B.V. | Epoxidation oxide catalysts |
-
1997
- 1997-05-23 US US08/862,457 patent/US5861519A/en not_active Expired - Fee Related
-
1998
- 1998-04-23 DE DE69806927T patent/DE69806927T2/de not_active Expired - Fee Related
- 1998-04-23 AU AU74317/98A patent/AU7431798A/en not_active Abandoned
- 1998-04-23 KR KR1019997010854A patent/KR20010012888A/ko not_active Abandoned
- 1998-04-23 ES ES98921485T patent/ES2181218T3/es not_active Expired - Lifetime
- 1998-04-23 JP JP54985698A patent/JP2001527563A/ja not_active Ceased
- 1998-04-23 CN CN98805334A patent/CN1102929C/zh not_active Expired - Fee Related
- 1998-04-23 WO PCT/EP1998/002422 patent/WO1998052931A1/en not_active Ceased
- 1998-04-23 CA CA002287078A patent/CA2287078A1/en not_active Abandoned
- 1998-04-23 BR BR9809129-8A patent/BR9809129A/pt not_active IP Right Cessation
- 1998-04-23 EP EP98921485A patent/EP0983253B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001527563A (ja) | 2001-12-25 |
| DE69806927D1 (de) | 2002-09-05 |
| BR9809129A (pt) | 2000-08-01 |
| EP0983253A1 (en) | 2000-03-08 |
| KR20010012888A (ko) | 2001-02-26 |
| CN1257487A (zh) | 2000-06-21 |
| CA2287078A1 (en) | 1998-11-26 |
| US5861519A (en) | 1999-01-19 |
| AU7431798A (en) | 1998-12-11 |
| DE69806927T2 (de) | 2003-03-13 |
| CN1102929C (zh) | 2003-03-12 |
| WO1998052931A1 (en) | 1998-11-26 |
| EP0983253B1 (en) | 2002-07-31 |
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