BRPI0405642A - Processo para a oxidação extrativa e contaminantes de correntes brutas de hidrocarbonetos - Google Patents

Processo para a oxidação extrativa e contaminantes de correntes brutas de hidrocarbonetos

Info

Publication number
BRPI0405642A
BRPI0405642A BR0405642-6A BRPI0405642A BRPI0405642A BR PI0405642 A BRPI0405642 A BR PI0405642A BR PI0405642 A BRPI0405642 A BR PI0405642A BR PI0405642 A BRPI0405642 A BR PI0405642A
Authority
BR
Brazil
Prior art keywords
compounds
contaminants
peroxide
organic acid
extractive oxidation
Prior art date
Application number
BR0405642-6A
Other languages
English (en)
Inventor
Wladmir Ferraz De Souza
Original Assignee
Petroleo Brasileiro Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa filed Critical Petroleo Brasileiro Sa
Publication of BRPI0405642A publication Critical patent/BRPI0405642A/pt
Publication of BRPI0405642B1 publication Critical patent/BRPI0405642B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/08—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including acid treatment as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including oxidation as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

"PROCESSO PARA A OXIDAçãO EXTRATIVA DE CONTAMINANTES DE CORRENTES BRUTAS DE HIDROCARBONETOS". é descrito um processo para a oxidação extrativa de contaminantes de correntes brutas (24) de hidrocarbonetos ricas em compostos polares heteroatómicos, o processo envolvendo a oxidação extrativa de compostos sulfurados e nitrogenados dessas correntes, dito processo compreendendo tratar ditas correntes com um par peróxido em solução (23) /ácido orgânico (22), o porcentual em peso da solução de peróxido e de ácido orgânico sendo de pelo menos 3 tanto para o peróxido como para o ácido orgânico, sob pH ácido, pressão atmosférica ou mais alta e pressão ambiente ou mais elevada. Como resultado da reação, os compostos heteroatómicos oxidados, tendo forte afinidade pela fase aquosa, são extraídos para a dita fase aquosa, enquanto o hidrocarboneto oxidado é neutralizado em (5), lavado com água em (6) e seco em (7), o produto final resultante sendo uma corrente tratada (29) da qual foram removidos 88,1 % em peso ou mais de compostos de nitrogênio total, nitrogênio básico até 99,1 % em peso, ambos calculados como teores mássicos; compostos de enxofre total foram removidos em até 23% em peso, enquanto a remoção de olefinas totais é limitada a 6,5% em peso. O produto tratado (29) é posteriormente dirigido para qualquer processo de refino.
BRPI0405642-6B1A 2003-05-06 2004-05-06 Processo para a oxidação extrativa e contaminantes de correntes brutas de hidrocarbonetos BRPI0405642B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/429,843 US7175755B2 (en) 2003-05-06 2003-05-06 Process for the extractive oxidation of contaminants from raw hydrocarbon streams
PCT/GB2004/001966 WO2004099346A1 (en) 2003-05-06 2004-05-06 Process for the extractive oxidation of contaminants from raw hydrocarbon streams

Publications (2)

Publication Number Publication Date
BRPI0405642A true BRPI0405642A (pt) 2005-04-19
BRPI0405642B1 BRPI0405642B1 (pt) 2013-10-22

Family

ID=33416128

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0405642-6B1A BRPI0405642B1 (pt) 2003-05-06 2004-05-06 Processo para a oxidação extrativa e contaminantes de correntes brutas de hidrocarbonetos

Country Status (5)

Country Link
US (1) US7175755B2 (pt)
EP (1) EP1620528B1 (pt)
JP (1) JP2006525401A (pt)
BR (1) BRPI0405642B1 (pt)
WO (1) WO2004099346A1 (pt)

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JP2003330963A (ja) * 2002-03-01 2003-11-21 Inventio Ag エレベータ設備におけるマルチメディアコンテンツ提示の手順、システムおよびコンピュータプログラム製品
BRPI0405847B1 (pt) * 2004-12-21 2015-04-22 Petroleo Brasileiro Sa Processo para a oxidação extrativa de contaminantes presentes em correntes brutas de combustíveis catalisada por óxidos de ferro
US20070151901A1 (en) * 2005-07-20 2007-07-05 Council Of Scientific And Industrial Research Process for desulphurisation of liquid hydrocarbon fuels
US8936719B2 (en) * 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
US8658028B2 (en) * 2007-01-19 2014-02-25 Exxonmobil Research And Engineering Company Removal of elemental sulfur in pipelines using static mixers
FR2923837B1 (fr) * 2007-11-19 2009-11-20 Inst Francais Du Petrole Procede de desulfuration en deux etapes d'essences olefiniques comprenant de l'arsenic.
US8241490B2 (en) * 2008-03-26 2012-08-14 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8197671B2 (en) * 2008-03-26 2012-06-12 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
RU2472841C2 (ru) * 2008-03-26 2013-01-20 Отерра, Инк. Катализаторы сульфоокисления и способы и системы их применения
US8298404B2 (en) 2010-09-22 2012-10-30 Auterra, Inc. Reaction system and products therefrom
US8764973B2 (en) 2008-03-26 2014-07-01 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9206359B2 (en) 2008-03-26 2015-12-08 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9061273B2 (en) 2008-03-26 2015-06-23 Auterra, Inc. Sulfoxidation catalysts and methods and systems of using same
US8894843B2 (en) 2008-03-26 2014-11-25 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
BRPI0805341B1 (pt) * 2008-12-05 2017-02-07 Petroleo Brasileiro S A - Petrobras reator multifásico multifuncional
US8419948B2 (en) * 2009-11-22 2013-04-16 United Laboratories International, Llc Wastewater treatment
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US20110220550A1 (en) * 2010-03-15 2011-09-15 Abdennour Bourane Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
WO2011116059A1 (en) * 2010-03-16 2011-09-22 Saudi Arabian Oil Company System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks
US8658027B2 (en) * 2010-03-29 2014-02-25 Saudi Arabian Oil Company Integrated hydrotreating and oxidative desulfurization process
US9828557B2 (en) 2010-09-22 2017-11-28 Auterra, Inc. Reaction system, methods and products therefrom
US8741128B2 (en) * 2010-12-15 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
WO2014138810A1 (en) 2013-03-15 2014-09-18 Ultraclean Pty Ltd Process for removing sulphur compounds from hydrocarbons
US9453167B2 (en) 2013-08-30 2016-09-27 Uop Llc Methods and apparatuses for processing hydrocarbon streams containing organic nitrogen species
WO2016154529A1 (en) 2015-03-26 2016-09-29 Auterra, Inc. Adsorbents and methods of use
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation
BR102017012313B1 (pt) 2017-06-09 2022-06-28 Petróleo Brasileiro S.A. - Petrobrás Sistema catalítico para remoção de compostos heteroatômicos de enxofre e/ou nitrogênio dissolvidos em hidrocarbonetos

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Also Published As

Publication number Publication date
BRPI0405642B1 (pt) 2013-10-22
US20040222134A1 (en) 2004-11-11
EP1620528A1 (en) 2006-02-01
WO2004099346A1 (en) 2004-11-18
JP2006525401A (ja) 2006-11-09
EP1620528B1 (en) 2019-09-25
US7175755B2 (en) 2007-02-13

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Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/05/2004, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 06/05/2024