BRPI0407689A - processo para a obtenção de ésteres de alquila dos ácidos graxos, ácidos de rosina e esteróis a partir de óleo de "tall" em bruto - Google Patents

processo para a obtenção de ésteres de alquila dos ácidos graxos, ácidos de rosina e esteróis a partir de óleo de "tall" em bruto

Info

Publication number
BRPI0407689A
BRPI0407689A BRPI0407689A BRPI0407689A BR PI0407689 A BRPI0407689 A BR PI0407689A BR PI0407689 A BRPI0407689 A BR PI0407689A BR PI0407689 A BRPI0407689 A BR PI0407689A
Authority
BR
Brazil
Prior art keywords
acids
sterols
esters
fatty acid
rosin
Prior art date
Application number
Other languages
English (en)
Inventor
Setsuo Sato
Henrique Jorge Sousa Sales
Hercules Peloggia
Peter Kempers
Sabine Both
Ulrich Schoerken
Thomas Wolf
Original Assignee
Cognis Brasil Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Brasil Ltda filed Critical Cognis Brasil Ltda
Priority to BRPI0407689 priority Critical patent/BRPI0407689B1/pt
Publication of BRPI0407689A publication Critical patent/BRPI0407689A/pt
Publication of BRPI0407689B1 publication Critical patent/BRPI0407689B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J51/00—Normal steroids with unmodified cyclopenta(a)hydrophenanthrene skeleton not provided for in groups C07J1/00 - C07J43/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J75/00—Processes for the preparation of steroids in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07J—STEROIDS
    • C07J9/00—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B13/00—Recovery of fats, fatty oils or fatty acids from waste materials
    • C11B13/005—Recovery of fats, fatty oils or fatty acids from waste materials of residues of the fabrication of wood-cellulose (in particular tall-oil)
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
    • C11C1/08—Refining
    • C11C1/10—Refining by distillation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/6445—Glycerides
    • C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/649—Biodiesel, i.e. fatty acid alkyl esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Zoology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • Genetics & Genomics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Steroid Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA A OBTENçãO DE éSTERES DE ALQUILA DOS áCIDOS GRAXOS, áCIDOS DE ROSINA E ESTERóIS A PARTIR DE óLEO DE 'TALL' EM BRUTO". A presente invenção refere-se a um processo para a obtenção de ésteres de alquila do ácido graxo, ácidos de rosina e de esteróis a partir de óleo de 'tall' em bruto (CTO), o qual é caracterizado pelas etapas que se seguem: (a) pondo em reação os ácidos graxos livres presentes no CTO com álcoois inferiores; (b) esterificando os esteróis no CTO com ácido bórico ou transesterificando com catalisador; (c) separando os ésteres de alquila inferiores do ácido graxo e os ácidos de rosina a partir dos esterol borato ésteres restantes ou os esterol ésteres dos ácidos graxos para a produção de uma corrente de esterol ésteres; (d) separando os ésteres de alquila dos ácidos graxos a partir dos ácidos de rosina para a produção de uma primeira corrente de ésteres de alquila do ácido graxo e uma corrente secundária de ácidos de rosina; e (e) convertendo os referidos esterol ésteres em esteróis livres para a produção de uma terceira corrente de esteróis livres.
BRPI0407689 2003-02-21 2004-02-20 processo para a obtenÇço de Ésteres de alquila dos Ácidos graxos, Ácidos de rosina e esteràis a partir de àleo de "tall" em bruto BRPI0407689B1 (pt)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BRPI0407689 BRPI0407689B1 (pt) 2003-02-21 2004-02-20 processo para a obtenÇço de Ésteres de alquila dos Ácidos graxos, Ácidos de rosina e esteràis a partir de àleo de "tall" em bruto

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/BR2003/000024 WO2004074233A1 (en) 2003-02-21 2003-02-21 Process for obtaining fatty acid alkyl esters, rosin acids and sterols from crude tall oil
BRPI0407689 BRPI0407689B1 (pt) 2003-02-21 2004-02-20 processo para a obtenÇço de Ésteres de alquila dos Ácidos graxos, Ácidos de rosina e esteràis a partir de àleo de "tall" em bruto
PCT/BR2004/000016 WO2004080942A1 (en) 2003-02-21 2004-02-20 Process for obtaining fatty acid alkyl esters, rosin acids and sterols from crude tall oil

Publications (2)

Publication Number Publication Date
BRPI0407689A true BRPI0407689A (pt) 2006-03-01
BRPI0407689B1 BRPI0407689B1 (pt) 2013-07-02

Family

ID=32873322

Family Applications (2)

Application Number Title Priority Date Filing Date
BRPI0318115A BRPI0318115B8 (pt) 2003-02-21 2003-02-21 processo para obtenção de ésteres alquílicos de ácidos graxos, ácidos de colofônia e esteróis de óleo de tall bruto
BRPI0407689 BRPI0407689B1 (pt) 2003-02-21 2004-02-20 processo para a obtenÇço de Ésteres de alquila dos Ácidos graxos, Ácidos de rosina e esteràis a partir de àleo de "tall" em bruto

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BRPI0318115A BRPI0318115B8 (pt) 2003-02-21 2003-02-21 processo para obtenção de ésteres alquílicos de ácidos graxos, ácidos de colofônia e esteróis de óleo de tall bruto

Country Status (11)

Country Link
US (2) US20070015904A1 (pt)
EP (2) EP1594834B1 (pt)
JP (2) JP2006518335A (pt)
AT (2) ATE463477T1 (pt)
AU (1) AU2003303929A1 (pt)
BR (2) BRPI0318115B8 (pt)
CA (2) CA2514700A1 (pt)
DE (2) DE60332053D1 (pt)
ES (2) ES2342936T3 (pt)
NO (2) NO20053894L (pt)
WO (2) WO2004074233A1 (pt)

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BRPI0318115B8 (pt) * 2003-02-21 2016-05-17 Cognis Brasil Ltda processo para obtenção de ésteres alquílicos de ácidos graxos, ácidos de colofônia e esteróis de óleo de tall bruto
JP2009513771A (ja) * 2005-10-26 2009-04-02 サンパイン・アクチボラゲット 粗トールオイルから得られる自動車燃料およびファインケミカル
US7695532B2 (en) * 2005-11-16 2010-04-13 The Research Foundation Of State University Of New York Process for making biodiesel from crude tall oil
JP4914113B2 (ja) * 2006-05-11 2012-04-11 ハリマ化成株式会社 ステロール類の製造方法
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JP5238147B2 (ja) * 2006-07-31 2013-07-17 ハリマ化成株式会社 トール脂肪酸エステル、その製造方法およびその用途
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US20080228011A1 (en) 2007-03-14 2008-09-18 Endicott Biofuels Ii, Llc Methods for Producing Triol Ethers by Reactive Distillation
WO2008112881A1 (en) 2007-03-14 2008-09-18 Endicott Biofuels Ii, Llc Production of biodiesel fuels which are low in glycerin and sulfur
US8105399B2 (en) 2007-07-31 2012-01-31 Endicott Biofuels Ii, Llc Production of renewable diesel by pyrolysis and esterification
WO2009029344A1 (en) * 2007-08-27 2009-03-05 Endicott Biofuels Ii, Llc Production of ester-based fuels such as biodiesel from renewable starting materials
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CN109825359B (zh) * 2019-04-04 2021-05-25 南京林业大学 一种利用造纸黑液制备生物基润滑油的方法及专用生产装置

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BRPI0318115B8 (pt) * 2003-02-21 2016-05-17 Cognis Brasil Ltda processo para obtenção de ésteres alquílicos de ácidos graxos, ácidos de colofônia e esteróis de óleo de tall bruto

Also Published As

Publication number Publication date
EP1613581B1 (en) 2008-10-29
DE602004017442D1 (de) 2008-12-11
JP2006518768A (ja) 2006-08-17
CA2516598C (en) 2012-08-07
JP4484865B2 (ja) 2010-06-16
WO2004080942B1 (en) 2004-10-28
BR0318115A (pt) 2006-02-07
ES2342936T3 (es) 2010-07-19
WO2004074233A1 (en) 2004-09-02
US9079845B2 (en) 2015-07-14
US20070015904A1 (en) 2007-01-18
EP1613581A1 (en) 2006-01-11
BRPI0318115B8 (pt) 2016-05-17
US20060235198A1 (en) 2006-10-19
ES2315639T3 (es) 2009-04-01
EP1594834A1 (en) 2005-11-16
NO20053894L (no) 2005-08-19
BR0318115B1 (pt) 2013-11-12
ATE463477T1 (de) 2010-04-15
ATE412626T1 (de) 2008-11-15
EP1594834B1 (en) 2010-04-07
JP2006518335A (ja) 2006-08-10
CA2514700A1 (en) 2004-09-02
AU2003303929A1 (en) 2004-09-09
BRPI0407689B1 (pt) 2013-07-02
NO20053893L (no) 2005-08-19
WO2004080942A1 (en) 2004-09-23
CA2516598A1 (en) 2004-09-23
DE60332053D1 (de) 2010-05-20

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