BRPI0407782A - processo e dispositivo para pirólise de biomassa - Google Patents
processo e dispositivo para pirólise de biomassaInfo
- Publication number
- BRPI0407782A BRPI0407782A BRPI0407782-2A BRPI0407782A BRPI0407782A BR PI0407782 A BRPI0407782 A BR PI0407782A BR PI0407782 A BRPI0407782 A BR PI0407782A BR PI0407782 A BRPI0407782 A BR PI0407782A
- Authority
- BR
- Brazil
- Prior art keywords
- pyrolysing
- bars
- biomass
- heating element
- station
- Prior art date
Links
- 239000002028 Biomass Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 238000000197 pyrolysis Methods 0.000 title abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/02—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge
- C10B47/12—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge in which the charge is subjected to mechanical pressures during coking
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1018—Biomass of animal origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
"PROCESSO E DISPOSITIVO PARA PIRóLISE DE BIOMASSA". A invenção refere-se a um processo para a pirólise de biomassa, com ajuda de um elemento de aquecimento e dispositivos para guia da biomassa. Durante a pirólise, o elemento de aquecimento e a biomassa são comprimidos um contra o outro a uma pressão de 5 bar - 80 bar. A invenção também refere-se a um dispositivo para pirolisar biomassas, que compreende uma alimentação de material (4) e uma estação de pirolisação (6). A alimentação de material (4) compreende dispositivos para gerar uma pressão dentre 5 bar e 200 bar, comprimindo a matéria-prima a ser pirolisada contra a estação de pirolisação (6). A estação de pirolisação (6) compreende um elemento de aquecimento (22), que é aquecido para uma temperatura dentre 300<198>C e 1000<198>C em um estado operacional.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10308260.3 | 2003-02-25 | ||
| DE10308260A DE10308260A1 (de) | 2003-02-25 | 2003-02-25 | Verfahren zum Pyrolysieren von Biomasse mit einem Heizelement und mit Mitteln zum Führen von Biomasse |
| DE10345842A DE10345842A1 (de) | 2003-09-30 | 2003-09-30 | Verfahren und Vorrichtung zur Pyrolyse von Biomasse |
| DE10345842.5 | 2003-09-30 | ||
| PCT/EP2004/001858 WO2004076591A1 (de) | 2003-02-25 | 2004-02-25 | Verfahren und vorrichtung zur pyrolyse von biomasse |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0407782A true BRPI0407782A (pt) | 2006-02-14 |
| BRPI0407782B1 BRPI0407782B1 (pt) | 2014-09-02 |
Family
ID=32928843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0407782-2B1A BRPI0407782B1 (pt) | 2003-02-25 | 2004-02-25 | Processo e dispositivo para pirólise de biomassa, oligômeros sintéticos, polímeros sintéticos, borracha e/ou plásticos |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7438785B2 (pt) |
| EP (1) | EP1608721B1 (pt) |
| JP (1) | JP5270090B2 (pt) |
| KR (1) | KR101161550B1 (pt) |
| CN (1) | CN1753972A (pt) |
| AT (1) | ATE506425T1 (pt) |
| AU (1) | AU2004215629B9 (pt) |
| BR (1) | BRPI0407782B1 (pt) |
| CA (1) | CA2516012C (pt) |
| DE (1) | DE502004012415D1 (pt) |
| EA (1) | EA008391B1 (pt) |
| PL (1) | PL210303B1 (pt) |
| PT (1) | PT1608721E (pt) |
| WO (1) | WO2004076591A1 (pt) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7108767B2 (en) * | 2004-08-18 | 2006-09-19 | Noto Vincent H | Pyrolysis machine |
| WO2006117006A1 (en) * | 2005-05-03 | 2006-11-09 | Danmarks Tekniske Universitet | A method and a mobile unit for collecting and pyrolysing biomass |
| US7897798B2 (en) | 2006-08-04 | 2011-03-01 | Mcneff Research Consultants, Inc. | Methods and apparatus for producing alkyl esters from lipid feed stocks and systems including same |
| US20090007484A1 (en) * | 2007-02-23 | 2009-01-08 | Smith David G | Apparatus and process for converting biomass feed materials into reusable carbonaceous and hydrocarbon products |
| US7893307B2 (en) * | 2007-02-23 | 2011-02-22 | Smith David G | Apparatus and process for converting feed material into reusable hydrocarbons |
| US7943791B2 (en) * | 2007-09-28 | 2011-05-17 | Mcneff Research Consultants, Inc. | Methods and compositions for refining lipid feed stocks |
| DE102008049350A1 (de) * | 2008-09-29 | 2010-04-01 | Claas Selbstfahrende Erntemaschinen Gmbh | Thermochemischer Reaktor für ein selbstfahrendes Erntefahrzeug |
| US8361174B2 (en) * | 2008-10-07 | 2013-01-29 | Sartec Corporation | Catalysts, systems, and methods for producing fuels and fuel additives from polyols |
| US9102877B2 (en) | 2008-11-12 | 2015-08-11 | Sartec Corporation | Systems and methods for producing fuels from biomass |
| US9909067B2 (en) | 2009-01-21 | 2018-03-06 | Cool Planet Energy Systems, Inc. | Staged biomass fractionator |
| CN102292414A (zh) * | 2009-01-21 | 2011-12-21 | 酷星生物燃料有限公司 | 用于生物质分馏的系统和方法 |
| US8217212B2 (en) * | 2009-04-01 | 2012-07-10 | Paoluccio John A | Sequencing retort liquid phase torrefication processing apparatus and method |
| KR100967906B1 (ko) * | 2009-12-24 | 2010-07-06 | 더블유비엠과학기술 주식회사 | 바이오매스 열분해 가스 발생 시스템 및 그 발생 방법 |
| US8951476B2 (en) | 2011-03-24 | 2015-02-10 | Cool Planet Energy Systems, Inc. | System for making renewable fuels |
| US8143464B2 (en) | 2011-03-24 | 2012-03-27 | Cool Planet Biofuels, Inc. | Method for making renewable fuels |
| US8431757B2 (en) | 2011-03-24 | 2013-04-30 | Cool Planet Biofuels, Inc. | Method for making renewable fuels |
| JP2014524824A (ja) | 2011-04-15 | 2014-09-25 | バイオジェニック リージェンツ エルエルシー | 高炭素生体試薬の生成のためのシステムおよび装置 |
| US8367881B2 (en) | 2011-05-09 | 2013-02-05 | Cool Planet Biofuels, Inc. | Method for biomass fractioning by enhancing biomass thermal conductivity |
| WO2013169803A1 (en) | 2012-05-07 | 2013-11-14 | Biogenic Reagents LLC | Biogenic activated carbon and methods of making and using same |
| US20140073823A1 (en) * | 2012-09-10 | 2014-03-13 | Phillips 66 Company | Generating deoxygenated pyrolysis vapors |
| DE202013101154U1 (de) | 2013-03-18 | 2013-04-22 | Matthias Überdiek | Pyrolyseaggregat für feuchte Biomasse |
| US12350648B2 (en) | 2013-10-24 | 2025-07-08 | Carbon Technology Holdings, LLC | Methods and apparatus for producing activated carbon from biomass through carbonized ash intermediates |
| LT3094593T (lt) | 2014-01-16 | 2022-04-11 | Carbon Technology Holdings, LLC | Anglies mikrogamykla |
| EP3110754A4 (en) | 2014-02-24 | 2017-11-22 | Biogenic Reagents Ventures, LLC | Highly mesoporous activated carbon |
| WO2016065357A1 (en) | 2014-10-24 | 2016-04-28 | Biogenic Reagent Ventures, Llc | Halogenated activated carbon compositions and methods of making and using same |
| BR112017023252B1 (pt) | 2015-04-27 | 2020-12-15 | Shell Internationale Research Maatschappij B.V. | Processo para produzir produtos de hidrocarboneto líquido a partir de uma matériaprima sólida |
| KR101699610B1 (ko) * | 2015-05-06 | 2017-01-25 | 서울대학교산학협력단 | 바이오매스 처리 방법 |
| KR20160141347A (ko) | 2015-05-31 | 2016-12-08 | 연세대학교 원주산학협력단 | 바이오매스 급속열분해를 위한 순환유동층 열분해 장치 및 바이오 오일 제조방법 |
| DE212016000279U1 (de) * | 2016-05-30 | 2019-02-06 | Obshchestvo S Ogranichennoj Otvetstvennostyu "Energolesprom" | Anlage der thermochemischen Umwandlung von organhaltigen Rohstoffen |
| US10239812B2 (en) | 2017-04-27 | 2019-03-26 | Sartec Corporation | Systems and methods for synthesis of phenolics and ketones |
| CN108164113B (zh) * | 2018-01-15 | 2020-10-13 | 东南大学 | 翅翼式污泥管式热解反应器 |
| US10696923B2 (en) | 2018-02-07 | 2020-06-30 | Sartec Corporation | Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids |
| US10544381B2 (en) | 2018-02-07 | 2020-01-28 | Sartec Corporation | Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid |
| US10604704B2 (en) * | 2018-05-07 | 2020-03-31 | Vorsana Inc | Shear retort for ablative pyrolysis |
| BR112020025445A2 (pt) | 2018-06-14 | 2021-03-16 | Carbon Technology Holdings, LLC | Composições de dióxido de silício de carbono poroso biogênico e métodos de produção e uso das mesmas |
| US11834611B2 (en) | 2019-01-17 | 2023-12-05 | His Majesty The King In Right Of Canada, Represented By The Minister Of Natural Resources | Reactor and method for ablative centrifuge pyrolysis |
| CN111676036B (zh) * | 2020-05-29 | 2024-07-30 | 华电电力科学研究院有限公司 | 一种生物质热解反应器及其工作方法 |
| CN116529400A (zh) | 2020-09-25 | 2023-08-01 | 卡本科技控股有限责任公司 | 与生物质热解集成的金属矿石的生物还原 |
| US11851723B2 (en) | 2021-02-18 | 2023-12-26 | Carbon Technology Holdings, LLC | Carbon-negative metallurgical products |
| JP2024515776A (ja) | 2021-04-27 | 2024-04-10 | カーボン テクノロジー ホールディングス, エルエルシー | 最適化された固定炭素を有するバイオカーボン組成物及びこれを生成するためのプロセス |
| AU2022308660A1 (en) | 2021-07-09 | 2024-02-22 | Carbon Technology Holdings, LLC | Processes for producing biocarbon pellets with high fixed-carbon content and optimized reactivity, and biocarbon pellets obtained therefrom |
| KR20240043777A (ko) | 2021-08-02 | 2024-04-03 | 카본 테크놀로지 홀딩스, 엘엘씨 | 바이오매스 열분해 액체로부터 탄소를 재포집하기 위한 프로세스 및 시스템 |
| WO2023086323A1 (en) | 2021-11-12 | 2023-05-19 | Carbon Technology Holdings, LLC | Biocarbon compositions with optimized compositional parameters, and processes for producing the same |
| KR102399530B1 (ko) * | 2021-11-26 | 2022-05-18 | 주식회사 상수 | 리볼버식 연속 열분해장치 |
| EP4253504A1 (en) * | 2022-04-01 | 2023-10-04 | Lauridsen Holding, Skjern ApS | Friction heated pyrolysis unit and method for friction heating a biomass pyrolysis unit |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2436290A1 (de) * | 1974-07-27 | 1976-02-05 | Woldemar Oelkers | Vorrichtung fuer die kontinuierliche schnellentgasung durch schwelung von organischen natur- und kunststoffen |
| EP0561849B1 (en) * | 1990-12-03 | 1995-03-22 | Ireton International Inc. | Method for ablative heat transfer |
| NL1001006C2 (nl) * | 1995-08-18 | 1997-02-20 | Biomass Technology Group B V | Werkwijze en inrichting voor het thermisch behandelen van niet-gasvormig materiaal. |
| GB0200476D0 (en) * | 2002-01-10 | 2002-02-27 | Univ Aston | Reactor |
| US7144558B2 (en) * | 2004-07-01 | 2006-12-05 | Biogas Technologies, Inc. | Wood gasification apparatus |
-
2004
- 2004-02-25 EP EP04714297A patent/EP1608721B1/de not_active Expired - Lifetime
- 2004-02-25 KR KR1020057015173A patent/KR101161550B1/ko not_active Expired - Fee Related
- 2004-02-25 JP JP2006501952A patent/JP5270090B2/ja not_active Expired - Fee Related
- 2004-02-25 PT PT04714297T patent/PT1608721E/pt unknown
- 2004-02-25 PL PL377899A patent/PL210303B1/pl unknown
- 2004-02-25 AU AU2004215629A patent/AU2004215629B9/en not_active Ceased
- 2004-02-25 WO PCT/EP2004/001858 patent/WO2004076591A1/de not_active Ceased
- 2004-02-25 EA EA200501342A patent/EA008391B1/ru not_active IP Right Cessation
- 2004-02-25 DE DE502004012415T patent/DE502004012415D1/de not_active Expired - Lifetime
- 2004-02-25 CN CNA2004800051703A patent/CN1753972A/zh active Pending
- 2004-02-25 CA CA2516012A patent/CA2516012C/en not_active Expired - Fee Related
- 2004-02-25 AT AT04714297T patent/ATE506425T1/de active
- 2004-02-25 US US10/545,879 patent/US7438785B2/en not_active Expired - Fee Related
- 2004-02-25 BR BRPI0407782-2B1A patent/BRPI0407782B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EA008391B1 (ru) | 2007-04-27 |
| US7438785B2 (en) | 2008-10-21 |
| KR20050107431A (ko) | 2005-11-11 |
| PL377899A1 (pl) | 2006-02-20 |
| EP1608721B1 (de) | 2011-04-20 |
| KR101161550B1 (ko) | 2012-07-03 |
| AU2004215629A1 (en) | 2004-09-10 |
| EP1608721A1 (de) | 2005-12-28 |
| JP2006518787A (ja) | 2006-08-17 |
| JP5270090B2 (ja) | 2013-08-21 |
| CN1753972A (zh) | 2006-03-29 |
| BRPI0407782B1 (pt) | 2014-09-02 |
| WO2004076591A1 (de) | 2004-09-10 |
| ATE506425T1 (de) | 2011-05-15 |
| US20060169572A1 (en) | 2006-08-03 |
| CA2516012C (en) | 2015-02-10 |
| AU2004215629B2 (en) | 2009-02-26 |
| PL210303B1 (pl) | 2011-12-30 |
| CA2516012A1 (en) | 2004-09-10 |
| PT1608721E (pt) | 2011-07-25 |
| EA200501342A1 (ru) | 2006-02-24 |
| AU2004215629B9 (en) | 2009-07-30 |
| DE502004012415D1 (de) | 2011-06-01 |
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