BRPI0408554A - processo para a oxidação parcial de propeno a ácido acrìlico em fase gasosa - Google Patents
processo para a oxidação parcial de propeno a ácido acrìlico em fase gasosaInfo
- Publication number
- BRPI0408554A BRPI0408554A BRPI0408554-0A BRPI0408554A BRPI0408554A BR PI0408554 A BRPI0408554 A BR PI0408554A BR PI0408554 A BRPI0408554 A BR PI0408554A BR PI0408554 A BRPI0408554 A BR PI0408554A
- Authority
- BR
- Brazil
- Prior art keywords
- reaction
- propene
- highest temperature
- acrylic acid
- gas mixture
- Prior art date
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 9
- 239000000203 mixture Substances 0.000 abstract 5
- 239000012495 reaction gas Substances 0.000 abstract 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA A OXIDAçãO PARCIAL DE PROPENO A áCIDO ACRìLICO EM FASE GASOSA". A invenção refere-se a um método para a oxidação em fase gasosa parcial heterogeneamente catalisada de propeno para formar ácido acrílico. De acordo com o referido método, a mistura de partida da reação com uma carga de propeno < 169 NI/I. h é oxidada em um primeiro estágio de reação em um material de alimentação de catalisador de leito fixo (1), que está localizado em duas zonas de reação sucessivas A, B, e a mistura de gás do produto a partir do primeiro está io contendo acroleína é subseqüentemente oxidada em um segundo estágio de reação em um material de alimentação de catalisador de leito fixo (2), que está localizado em duas zonas de reação sucessivas C, D. De acordo com o referido método, a temperatura mais alta do gás de reação na zona A está acima da temperatura mais alta da mistura do gás de reação na zona B e a temperatura mais alta da mistura do gás de reação na zona de reação C está acima da temperatura mais alta da mistura do gás de reação na zona D.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10313208A DE10313208A1 (de) | 2003-03-25 | 2003-03-25 | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| US47578003P | 2003-06-05 | 2003-06-05 | |
| PCT/EP2004/002879 WO2004085367A1 (de) | 2003-03-25 | 2004-03-19 | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0408554A true BRPI0408554A (pt) | 2006-03-21 |
| BRPI0408554B1 BRPI0408554B1 (pt) | 2013-07-02 |
Family
ID=33099278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0408554-0B1A BRPI0408554B1 (pt) | 2003-03-25 | 2004-03-19 | processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1611076B1 (pt) |
| JP (1) | JP4532470B2 (pt) |
| KR (1) | KR101006649B1 (pt) |
| AT (1) | ATE389629T1 (pt) |
| BR (1) | BRPI0408554B1 (pt) |
| DE (1) | DE502004006576D1 (pt) |
| ES (1) | ES2300753T3 (pt) |
| WO (1) | WO2004085367A1 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7592483B2 (en) | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
| EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
| DE102007004960A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Acrylsäure |
| DE102007055086A1 (de) | 2007-11-16 | 2009-05-20 | Basf Se | Verfahren zur Herstellung von Acrylsäure |
| DE102010048405A1 (de) | 2010-10-15 | 2011-05-19 | Basf Se | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein |
| DE102012204436A1 (de) | 2012-03-20 | 2012-10-04 | Basf Se | Thermisches Trennverfahren |
| DE102013202048A1 (de) | 2013-02-07 | 2013-04-18 | Basf Se | Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist |
| EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
| JP7753249B2 (ja) | 2020-04-21 | 2025-10-14 | ベーアーエスエフ・エスエー | 元素Mo、W、V及びCuを含む触媒活性多元素酸化物を生成する方法 |
| US20240091756A1 (en) | 2020-10-29 | 2024-03-21 | Basf Se | Method for producing a core-shell catalyst |
| WO2023006503A1 (de) | 2021-07-28 | 2023-02-02 | Basf Se | Verfahren zur herstellung von acrylsäure |
| CN120322292A (zh) | 2022-12-07 | 2025-07-15 | 巴斯夫欧洲公司 | 用于制造含钼、钨、钒、铜和锑元素的催化活性多元素氧化物的方法 |
| WO2025125092A1 (de) | 2023-12-14 | 2025-06-19 | Basf Se | Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids |
| WO2025172146A1 (de) | 2024-02-15 | 2025-08-21 | Basf Se | Verfahren zur herstellung von acrylsäure |
| WO2025219136A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams |
| WO2025219137A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams by gasification and fermentation |
| WO2025219135A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing high calorific acrylic acid production waste streams |
| WO2026017456A1 (de) | 2024-07-15 | 2026-01-22 | Basf Se | Verfahren zur herstellung eines katalysators umfassend eine wasserbehandlung |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY121878A (en) * | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
| DE19955168A1 (de) * | 1999-11-16 | 2001-05-17 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
-
2004
- 2004-03-19 JP JP2006504743A patent/JP4532470B2/ja not_active Expired - Lifetime
- 2004-03-19 BR BRPI0408554-0B1A patent/BRPI0408554B1/pt not_active IP Right Cessation
- 2004-03-19 ES ES04721853T patent/ES2300753T3/es not_active Expired - Lifetime
- 2004-03-19 DE DE502004006576T patent/DE502004006576D1/de not_active Expired - Lifetime
- 2004-03-19 KR KR1020057017972A patent/KR101006649B1/ko not_active Expired - Lifetime
- 2004-03-19 WO PCT/EP2004/002879 patent/WO2004085367A1/de not_active Ceased
- 2004-03-19 AT AT04721853T patent/ATE389629T1/de not_active IP Right Cessation
- 2004-03-19 EP EP04721853A patent/EP1611076B1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050115310A (ko) | 2005-12-07 |
| EP1611076A1 (de) | 2006-01-04 |
| KR101006649B1 (ko) | 2011-01-10 |
| JP2006521313A (ja) | 2006-09-21 |
| EP1611076B1 (de) | 2008-03-19 |
| ES2300753T3 (es) | 2008-06-16 |
| BRPI0408554B1 (pt) | 2013-07-02 |
| JP4532470B2 (ja) | 2010-08-25 |
| ATE389629T1 (de) | 2008-04-15 |
| WO2004085367A1 (de) | 2004-10-07 |
| DE502004006576D1 (de) | 2008-04-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0408554B1 (pt) | processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa | |
| BRPI0408629B1 (pt) | processo para a oxidaÇço parcial de propeno a Ácido acrÍlico em fase gasosa | |
| TW200505847A (en) | Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid | |
| MY121141A (en) | Method for the catalytic gas-phase oxidation of propene into acrolein | |
| BRPI0408539B8 (pt) | processo para a oxidação parcial de acroleína para ácido acrílico em fase gasosa | |
| ATE463474T1 (de) | Verfahren zur herstellung von acrolein, oder acrylsäure oder deren gemisch aus propan | |
| TW200740745A (en) | Oxidation system with sidedraw secondary reactor | |
| MXPA05011302A (es) | Proceso de purificacion de acido tereftalico crudo en una zona post oxidacion por la adicion de corriente. | |
| BR0111607A (pt) | Processo para a preparação de acroleìna ou de ácido acrìlico ou de uma mistura dos mesmos a partir de propano | |
| WO2006028753A3 (en) | Optimized liquid-phase oxidation in a bubble column reactor | |
| WO2006028756A3 (en) | Optimized liquid-phase oxidation | |
| ZA200804663B (en) | Method for carrying out in a stable manner a process for continuously producing acrolein or acrylic acid or the mixture thereof from propane | |
| MY167589A (en) | Oxidation system with internal secondary reactor | |
| ATE270282T1 (de) | Verfahren zur kontinuierlichen herstellung eines epoxids | |
| MY149963A (en) | Oxidation system employing internal structure for enhanced hydrodynamics | |
| WO2006028771A3 (en) | Optimized liquid-phase oxidation | |
| MX344104B (es) | Composición de ácido tereftálico crudo y proceso de producción de la misma. | |
| WO2006028772A3 (en) | Optimized liquid-phase oxidation | |
| BRPI0408642B1 (pt) | processo para oxidar parcialmente acroleÍna a Ácido em fase gasosa. | |
| BRPI0416633A (pt) | processo para preparar acroleìna por oxidação parcial em fase gasosa heterogeneamente catalisada, e, catalisador anular não suportado | |
| MY136659A (en) | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein | |
| WO2006028754A3 (en) | Optimized liquid-phase oxidation | |
| WO2006028767A8 (en) | Optimized liquid-phase oxidation in a bubble column reactor | |
| BRPI0408636B1 (pt) | processo para a oxidaÇço parcial de propeno a acroleÍna em fase gasosa | |
| WO2006028752A3 (en) | Optimized liquid-phase oxidation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/03/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25D | Requested change of name of applicant approved | ||
| B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 19/03/2024 |