BRPI0416633A - processo para preparar acroleìna por oxidação parcial em fase gasosa heterogeneamente catalisada, e, catalisador anular não suportado - Google Patents

processo para preparar acroleìna por oxidação parcial em fase gasosa heterogeneamente catalisada, e, catalisador anular não suportado

Info

Publication number
BRPI0416633A
BRPI0416633A BRPI0416633-7A BRPI0416633A BRPI0416633A BR PI0416633 A BRPI0416633 A BR PI0416633A BR PI0416633 A BRPI0416633 A BR PI0416633A BR PI0416633 A BRPI0416633 A BR PI0416633A
Authority
BR
Brazil
Prior art keywords
gas phase
catalyst
phase oxidation
heterogeneously catalyzed
partial gas
Prior art date
Application number
BRPI0416633-7A
Other languages
English (en)
Inventor
Jochen Petzoldt
Klaus Joachim Mueller-Engel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10353954A external-priority patent/DE10353954A1/de
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0416633A publication Critical patent/BRPI0416633A/pt
Publication of BRPI0416633B1 publication Critical patent/BRPI0416633B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"PROCESSO PARA PREPARAR ACROLEìNA POR OXIDAçãO PARCIAL EM FASE GASOSA HETEROGENEAMENTE CATALISADA, E, CATALISADOR ANULAR NãO SUPORTADO". A invenção refere-se a um método para a oxidação parcial em fase gasosa heterogeneamente catalisada de propeno para produzir acroleína com uma carga de propeno do leito catalítico <242> 120 N1/1<sym>h e um conteúdo total de CO~ 2~ e de hidrocarbonetos saturados no produto de reação menor do que 15% em mol, por meio do qual o catalisador no leito catalítico é um catalisador pleno anular, cuja massa ativa é um óxido de multimetais no qual as razões molares são Co/Fe = 2 a 4 e Co/Mo = 0,3 a 0,7.
BRPI0416633-7A 2003-11-18 2004-11-16 Processo para preparar acroleína por oxidação parcial em fase gasosa heterogeneamente catalisada, e, catalisador anular não suportado BRPI0416633B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US52066003P 2003-11-18 2003-11-18
US60/520660 2003-11-18
DE10353954A DE10353954A1 (de) 2003-11-18 2003-11-18 Verfahren zur Herstellung von Acrolein durch heterogen katalysierte partielle Gasphasenoxidation von Propen
DE10353954.9 2003-11-18
PCT/EP2004/012966 WO2005049200A1 (de) 2003-11-18 2004-11-16 Verfahren zur herstellung von acrolein durch heterogen katalysierte partielle gasphasenoxidation von propen

Publications (2)

Publication Number Publication Date
BRPI0416633A true BRPI0416633A (pt) 2007-01-16
BRPI0416633B1 BRPI0416633B1 (pt) 2014-04-08

Family

ID=34621298

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0416633-7A BRPI0416633B1 (pt) 2003-11-18 2004-11-16 Processo para preparar acroleína por oxidação parcial em fase gasosa heterogeneamente catalisada, e, catalisador anular não suportado

Country Status (10)

Country Link
EP (1) EP1689524B1 (pt)
JP (1) JP4751335B2 (pt)
KR (1) KR101135780B1 (pt)
AT (1) ATE500890T1 (pt)
BR (1) BRPI0416633B1 (pt)
DE (1) DE502004012292D1 (pt)
MY (1) MY139735A (pt)
RU (1) RU2373993C2 (pt)
TW (1) TWI351313B (pt)
WO (1) WO2005049200A1 (pt)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007028332A1 (de) * 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
DE102008042064A1 (de) 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042061A1 (de) * 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042060A1 (de) 2008-09-12 2009-06-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008054586A1 (de) 2008-12-12 2010-06-17 Basf Se Verfahren zur kontinuierlichen Herstellung von geometrischen Katalysatorformkörpern K
JP5295815B2 (ja) * 2009-02-18 2013-09-18 住友化学株式会社 メタクロレインおよびメタクリル酸の製造触媒
JP5908595B2 (ja) 2012-09-28 2016-04-26 旭化成ケミカルズ株式会社 酸化物触媒及びその製造方法、並びに、不飽和アルデヒド、ジオレフィン及び不飽和ニトリルの製造方法
US9656248B2 (en) 2013-05-09 2017-05-23 Nippon Kayaku Kabushiki Kaisha Catalyst for producing unsaturated aldehyde and/or unsaturated carboxylic acid, method for producing same, and method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
KR20160032037A (ko) 2013-07-18 2016-03-23 닛뽄 가야쿠 가부시키가이샤 불포화 알데히드 및/또는 불포화 카본산의 제조 방법
US10300463B2 (en) 2015-02-27 2019-05-28 Nippon Kayaku Kabushiki Kaisha Catalyst for manufacturing unsaturated aldehyde and/or unsaturated carboxylic acid and manufacturing method of same, and manufacturing method of unsaturated aldehyde and/or unsaturated carboxylic acid
JP6447327B2 (ja) * 2015-04-02 2019-01-09 三菱ケミカル株式会社 複合酸化物触媒、それを用いたアクロレイン及びアクリル酸の製造方法
WO2017010159A1 (ja) 2015-07-10 2017-01-19 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
EP3120926A1 (de) 2015-07-20 2017-01-25 Evonik Degussa GmbH Verfahren zur herstellung von mischoxidkatalysatoren
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
EP4442362A4 (en) * 2021-11-30 2025-11-19 Nippon Kayaku Kk CATALYST AND PROCESS FOR PRODUCING COMPOUNDS USING IT
US20240351008A1 (en) * 2021-11-30 2024-10-24 Nippon Kayaku Kabushiki Kaisha Catalyst, and method for producing compound using same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1112618A1 (ru) * 1982-07-30 1994-09-30 Институт катализа СО АН СССР Способ приготовления катализатора для окисления пропилена
DE4220859A1 (de) * 1992-06-25 1994-01-05 Basf Ag Multimetalloxidmassen
FR2718061B1 (fr) * 1994-04-01 1996-04-26 Rhone Poulenc Chimie Compositions catalytiques du type enrobées, comprenant du nickel, cobalt, molybdène et leur utilisation pour la préparation d'aldéhydes insaturés.
MY121141A (en) * 1999-03-10 2005-12-30 Basf Ag Method for the catalytic gas-phase oxidation of propene into acrolein
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung

Also Published As

Publication number Publication date
KR101135780B1 (ko) 2012-04-16
RU2373993C2 (ru) 2009-11-27
KR20060132585A (ko) 2006-12-21
TW200529923A (en) 2005-09-16
ATE500890T1 (de) 2011-03-15
RU2006121336A (ru) 2008-01-10
JP2007511565A (ja) 2007-05-10
EP1689524A1 (de) 2006-08-16
EP1689524B1 (de) 2011-03-09
MY139735A (en) 2009-10-30
DE502004012292D1 (de) 2011-04-21
JP4751335B2 (ja) 2011-08-17
BRPI0416633B1 (pt) 2014-04-08
WO2005049200A1 (de) 2005-06-02
TWI351313B (en) 2011-11-01

Similar Documents

Publication Publication Date Title
BR0111702A (pt) Processo para a preparação de acroleìna e/ou ácido acrìlico a partir de propano e/ou propeno
AU2001281823A1 (en) Method for the production of acrolein or acrylic acid or the mixture thereof from propane
DE50113787D1 (de) Verfahren zur herstellung von acrylsäure durch heterogen katalysierte gasphasenoxidation von propan
DE60104129D1 (de) Verfahren zur kontinuierlichen herstellung eines epoxids
TW200718680A (en) Process for preparing acrolein or acrylic acid or a mixture thereof from propane
DE50007278D1 (de) Verfahren zur Herstellung von Aminen
MY137100A (en) Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of propene to acrolein
MY132763A (en) Preparation of at least one partial oxidation and/or ammoxidation product of propylene
BRPI0408539B8 (pt) processo para a oxidação parcial de acroleína para ácido acrílico em fase gasosa
MY139360A (en) Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid
BR0209297A (pt) Processo para a preparação de ácido acrìlico pela oxidação parcial heterogeneamente catalisada de propano na fase gasosa
MY140688A (en) Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid
ZA200700832B (en) Method for the production of acrylic acid by means of heterogeneously catalyzed partial gas phase oxidation of propylene
WO2008012249A3 (de) Verfahren zum langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen dehydrierung eines zu dehydrierenden kohlenwasserstoffs
ATE500890T1 (de) Verfahren zur herstellung von acrolein durch heterogen katalysierte partielle gasphasenoxidation von propen
BR9914287A (pt) Processo para a preparação de acroleìna e/ou de ácido acrìlico a partir de propano
BRPI0408554A (pt) processo para a oxidação parcial de propeno a ácido acrìlico em fase gasosa
EP1350566A3 (en) Process for the preparation of unsaturated aldehydes and/or carboxylic acids by gas phase oxidation using a Mo-V based catalyst
MY136659A (en) Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein
Liu et al. Selective oxidation of propylene to acetone by molecular oxygen over Mx/2H5− x [PMo10V2O40]/HMS (M= Cu2+, Co2+, Ni2+)
MY135595A (en) Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid
BR0212483A (pt) Processo para a produção de ácido acrìlico a partir de propeno através de oxidação em fase gasosa, e, uso de um ácido acrìlico
EP1484302A4 (en) PROCESS FOR PRODUCING (METH) ACRYLIC ACID
MY141769A (en) Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation or propylene
BRPI0418791A (pt) método para produzir ácido (met) acrìlico ou (met) acroleìna

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/11/2004, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 18A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2696 DE 06-09-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.