BRPI0408669A - processo e sistema contìnuos para produzir polióis poliéteres - Google Patents
processo e sistema contìnuos para produzir polióis poliéteresInfo
- Publication number
- BRPI0408669A BRPI0408669A BRPI0408669-4A BRPI0408669A BRPI0408669A BR PI0408669 A BRPI0408669 A BR PI0408669A BR PI0408669 A BRPI0408669 A BR PI0408669A BR PI0408669 A BRPI0408669 A BR PI0408669A
- Authority
- BR
- Brazil
- Prior art keywords
- loop reactor
- rate
- continuous process
- reactor
- polyether polyols
- Prior art date
Links
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 3
- 229920000570 polyether Polymers 0.000 title abstract 3
- 229920005862 polyol Polymers 0.000 title abstract 3
- 150000003077 polyols Chemical class 0.000 title abstract 3
- 238000010924 continuous production Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
- B01J19/1837—Loop-type reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Polyethers (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
"PROCESSO E SISTEMA CONTìNUOS PARA PRODUZIR POLIóIS POLIéTERES". Um processo e sistema continuos para produzir polióis poliéteres que permitem adicionar continuamente um óxido não reagido a um reator de loop enquanto adicionando pelo menos um catalisador desativável termicamente capaz de se desativar termicamente antes da decomposição do poliol poliéter que podem permitir maiores concentrações de óxidos não reagidos e/ou uma taxa de reação no reator de loop que seja pelo menos duas vezes mais rápida do que uma taxa de reação em um reator de loop contendo menos que 14 por cento em peso de óxido não reagido. Em uma configuração preferida, o catalisador é um catalisador de cianeto metálico duplo e um reator tubular de fluxo pistonado é formado em série com o reator de loop sendo que nenhum reator contém um espaço de vapor.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45307303P | 2003-03-07 | 2003-03-07 | |
| PCT/US2004/006643 WO2004081082A1 (en) | 2003-03-07 | 2004-03-05 | Continuous process and system of producing polyether polyols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0408669A true BRPI0408669A (pt) | 2006-03-28 |
Family
ID=32990720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0408669-4A BRPI0408669A (pt) | 2003-03-07 | 2004-03-05 | processo e sistema contìnuos para produzir polióis poliéteres |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7378559B2 (pt) |
| EP (1) | EP1603965B1 (pt) |
| JP (1) | JP2007524719A (pt) |
| KR (1) | KR20050107604A (pt) |
| CN (1) | CN1867609A (pt) |
| AT (1) | ATE353348T1 (pt) |
| AU (1) | AU2004220072A1 (pt) |
| BR (1) | BRPI0408669A (pt) |
| CA (1) | CA2518201A1 (pt) |
| DE (1) | DE602004004639T2 (pt) |
| MX (1) | MXPA05009512A (pt) |
| WO (1) | WO2004081082A1 (pt) |
| ZA (1) | ZA200506576B (pt) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005001076A1 (de) * | 2005-01-08 | 2006-07-20 | Goldschmidt Gmbh | Gleichgewichtsreaktion und Gas/Flüssigreaktion im Schlaufenreaktor |
| DE102005034001A1 (de) * | 2005-07-18 | 2007-01-25 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| US7495063B2 (en) | 2006-02-03 | 2009-02-24 | Dow Global Technologies Inc. | Reduced oligomer concentration in high purity polyalkylene glycols |
| EP2035479B1 (de) * | 2006-06-23 | 2010-07-07 | Basf Se | Verfahren zur kontinuierlichen herstellung von polyetheralkoholen |
| CN101003622B (zh) * | 2007-01-18 | 2010-05-26 | 浙江大学 | 一种负载型双金属氰化络合物催化剂及其制备方法和应用 |
| AR073933A1 (es) * | 2008-05-19 | 2010-12-15 | Dow Global Technologies Inc | Procedimiento de flujo de recirculacion continuo para la produccion de poliol de polieter |
| JP6022770B2 (ja) * | 2008-10-13 | 2016-11-09 | ブルー キューブ アイピー エルエルシー | 塩素化及び/又はフッ素化プロペンの製造方法 |
| JP5767231B2 (ja) | 2009-10-09 | 2015-08-19 | ダウ グローバル テクノロジーズ エルエルシー | 塩素化及び/又はフッ素化されたプロペン及びより高級なアルケンを製造するプロセス |
| JP5782038B2 (ja) * | 2009-10-09 | 2015-09-24 | ダウ グローバル テクノロジーズ エルエルシー | 等温多管式反応器及び該反応器を組み込んだプロセス |
| BR112012007916A2 (pt) * | 2009-10-09 | 2019-09-24 | Dow Global Technologies Llc | processo de etapa para a produção de propenos clorados ou fluorados e processo para preparar 1,1,3,3 - tetrafluorprop-1-eno |
| US9074044B2 (en) | 2009-12-14 | 2015-07-07 | Dow Global Technologies Llc | Method for continuously producing low equivalent weight polyols using double metal cyanide catalysts |
| WO2011089120A1 (de) | 2010-01-20 | 2011-07-28 | Bayer Materialscience Ag | Verfahren zur aktivierung von doppelmetallcyanidkatalysatoren zur herstellung von polyethercarbonatpolyolen |
| DE102010008410A1 (de) | 2010-02-18 | 2011-08-18 | Bayer MaterialScience AG, 51373 | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| JP2013522438A (ja) | 2010-03-24 | 2013-06-13 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | ポリエーテルカーボネートポリオールの製造方法 |
| SG185607A1 (en) | 2010-05-18 | 2012-12-28 | Bayer Ip Gmbh | Method for producing polyether carbonate polyols |
| DE102010040517A1 (de) | 2010-09-09 | 2012-03-15 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Polyetherpolyolen |
| DE102010043409A1 (de) | 2010-11-04 | 2012-05-10 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Polycarbonatpolyolen durch immortale Polymerisation von cyclischen Carbonaten |
| EP2465890A1 (de) | 2010-12-17 | 2012-06-20 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen mit primären Hydroxyl-Endgruppen und daraus hergestellte Polyurethanpolymere |
| KR20140007852A (ko) * | 2011-02-24 | 2014-01-20 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 폴리에테르 폴리올의 제조를 위한 방법 및 반응기 시스템 |
| WO2012166394A1 (en) | 2011-05-31 | 2012-12-06 | Dow Global Technologies, Llc | Process for the production of chlorinated propenes |
| JP6212035B2 (ja) | 2011-05-31 | 2017-10-11 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンの製造方法 |
| JP6267114B2 (ja) | 2011-06-08 | 2018-01-24 | ダウ アグロサイエンシィズ エルエルシー | 塩素化および/またはフッ素化プロペンを生成するためのプロセス |
| CN108929192A (zh) | 2011-08-07 | 2018-12-04 | 蓝立方知识产权有限责任公司 | 生产氯化的丙烯的方法 |
| CN103717557A (zh) | 2011-08-07 | 2014-04-09 | 陶氏环球技术有限责任公司 | 生产氯化的丙烯的方法 |
| IN2014CN03748A (pt) | 2011-11-21 | 2015-09-25 | Dow Global Technologies Llc | |
| JP6050375B2 (ja) | 2011-12-02 | 2016-12-21 | ブルー キューブ アイピー エルエルシー | クロロアルカンの製造方法 |
| CA2856545A1 (en) | 2011-12-02 | 2013-06-06 | Dow Global Technologies Llc | Process for the production of chlorinated alkanes |
| JP6170068B2 (ja) | 2011-12-13 | 2017-07-26 | ブルー キューブ アイピー エルエルシー | 塩素化プロパン及びプロペンの製造方法 |
| IN2014CN04418A (pt) | 2011-12-22 | 2015-09-04 | Dow Global Technologies Llc | |
| WO2013096706A1 (en) | 2011-12-23 | 2013-06-27 | Dow Global Technologies, Llc | Process for the production of alkenes and/or aromatic compounds |
| US9598334B2 (en) | 2012-09-20 | 2017-03-21 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| EP2897930A1 (en) | 2012-09-20 | 2015-07-29 | Dow Global Technologies LLC | Process for the production of chlorinated propenes |
| CA2885329A1 (en) | 2012-09-30 | 2014-03-04 | Dow Global Technologies Llc | Weir quench and processes incorporating the same |
| US10065157B2 (en) | 2012-10-26 | 2018-09-04 | Blue Cube Ip Llc | Mixer and processes incorporating the same |
| JP6247311B2 (ja) | 2012-12-18 | 2017-12-13 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンを生成するための方法 |
| CA2894168C (en) | 2012-12-19 | 2018-04-24 | Dow Global Technologies Llc | Process for the production of chlorinated propenes |
| CA2901450A1 (en) | 2013-02-27 | 2014-09-04 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| CA2903760C (en) | 2013-03-09 | 2018-02-20 | Blue Cube Ip Llc | Process for the production of chlorinated alkanes |
| JP2016521788A (ja) | 2013-06-13 | 2016-07-25 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ポリエーテルカーボネイト−ポリオキシメチレンブロック共重合体 |
| WO2021021845A1 (en) | 2019-08-01 | 2021-02-04 | Dow Global Technologies Llc | Process for purifying polyether polyols |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US618017A (en) * | 1899-01-17 | Striped knitted fabric | ||
| US3108060A (en) * | 1960-05-10 | 1963-10-22 | Phillips Petroleum Co | Loop reactor and process for sulfonating asphalt |
| US3427256A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| US3278457A (en) | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3278459A (en) | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3427335A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same |
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3427334A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity |
| US3278458A (en) | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US5159092A (en) * | 1989-09-22 | 1992-10-27 | Buss Ag | Process for the safe and environmentally sound production of highly pure alkylene oxide adducts |
| JP3283297B2 (ja) | 1992-06-30 | 2002-05-20 | 旭硝子株式会社 | ポリエーテル類の連続製造方法 |
| US5541346A (en) | 1992-10-21 | 1996-07-30 | E. I. Du Pont De Nemours And Company | Polymerization of, and depolymerization to, cyclic ethers using selected metal compound catalysts |
| US5364973A (en) * | 1993-05-06 | 1994-11-15 | Arco Chemical Technology | Productive process for making conventional and low-unsaturation polyether polyols |
| CH686117A5 (fr) * | 1993-07-08 | 1996-01-15 | Biazzi Sa | Appareillage de reaction gaz-liquide. |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5712216A (en) | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5563221A (en) | 1995-06-21 | 1996-10-08 | Arco Chemical Technology, L.P. | Process for making ethylene oxide-capped polyols from double metal cyanide-catalyzed polyols |
| US5688861A (en) | 1995-11-30 | 1997-11-18 | Arco Chemical Technology, L.P. | Process for the preparation of polyol polymer dispersions |
| US5767323A (en) * | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| US5777177A (en) * | 1996-02-07 | 1998-07-07 | Arco Chemical Technology, L.P. | Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter |
| US5789826A (en) * | 1996-04-12 | 1998-08-04 | Kumbatovic; Bogumil | Equipment to extract ocean wave power |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5689012A (en) * | 1996-07-18 | 1997-11-18 | Arco Chemical Technology, L.P. | Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter |
| DE19709031A1 (de) | 1997-03-06 | 1998-09-10 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| DE19735795A1 (de) * | 1997-08-18 | 1999-02-25 | Bayer Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| DE19834573A1 (de) * | 1998-07-31 | 2000-02-03 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| JP2001519468A (ja) * | 1997-10-13 | 2001-10-23 | バイエル・アクチエンゲゼルシヤフト | ポリエーテルポリオールを製造するための結晶質複金属シアン化物触媒 |
| US6323350B1 (en) * | 1997-12-22 | 2001-11-27 | The Dow Chemical Company | Process for the oxidation of olefins to olefin oxides |
| US6063897A (en) * | 1998-05-05 | 2000-05-16 | Arco Chemical Technology, L.P. | Acid-treated double metal cyanide complex catalysts |
| DE19906985A1 (de) | 1999-02-19 | 2000-08-31 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| PL358016A1 (en) * | 2000-03-30 | 2004-08-09 | Shell Internationale Research Maatschappij B.V. | Dmc complex catalyst and process for its preparation |
| CZ20023475A3 (cs) * | 2000-04-20 | 2003-02-12 | Bayer Aktiengesellschaft | Způsob výroby DMC-katalyzátorů |
| US6767407B2 (en) * | 2002-05-07 | 2004-07-27 | Taiwan Semiconductor Manufacturing Co., Ltd | Auto-centering device for mechanical clamp |
| US6710096B2 (en) * | 2002-07-22 | 2004-03-23 | Basf Corporation | Polyether polyol for foam applications |
-
2004
- 2004-03-05 EP EP04717948A patent/EP1603965B1/en not_active Expired - Lifetime
- 2004-03-05 CA CA002518201A patent/CA2518201A1/en not_active Abandoned
- 2004-03-05 US US10/545,661 patent/US7378559B2/en not_active Expired - Fee Related
- 2004-03-05 WO PCT/US2004/006643 patent/WO2004081082A1/en not_active Ceased
- 2004-03-05 KR KR1020057016606A patent/KR20050107604A/ko not_active Withdrawn
- 2004-03-05 BR BRPI0408669-4A patent/BRPI0408669A/pt not_active IP Right Cessation
- 2004-03-05 ZA ZA200506576A patent/ZA200506576B/en unknown
- 2004-03-05 AT AT04717948T patent/ATE353348T1/de not_active IP Right Cessation
- 2004-03-05 DE DE602004004639T patent/DE602004004639T2/de not_active Expired - Fee Related
- 2004-03-05 CN CNA2004800061423A patent/CN1867609A/zh active Pending
- 2004-03-05 MX MXPA05009512A patent/MXPA05009512A/es active IP Right Grant
- 2004-03-05 AU AU2004220072A patent/AU2004220072A1/en not_active Abandoned
- 2004-03-05 JP JP2006509135A patent/JP2007524719A/ja active Pending
-
2008
- 2008-03-25 US US12/054,782 patent/US20080221281A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA05009512A (es) | 2006-02-22 |
| CA2518201A1 (en) | 2004-09-23 |
| AU2004220072A1 (en) | 2004-09-23 |
| US20080221281A1 (en) | 2008-09-11 |
| US20060155151A1 (en) | 2006-07-13 |
| WO2004081082A1 (en) | 2004-09-23 |
| ATE353348T1 (de) | 2007-02-15 |
| JP2007524719A (ja) | 2007-08-30 |
| US7378559B2 (en) | 2008-05-27 |
| EP1603965B1 (en) | 2007-02-07 |
| CN1867609A (zh) | 2006-11-22 |
| ZA200506576B (en) | 2006-12-27 |
| EP1603965A1 (en) | 2005-12-14 |
| DE602004004639T2 (de) | 2007-11-08 |
| DE602004004639D1 (de) | 2007-03-22 |
| KR20050107604A (ko) | 2005-11-14 |
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