BRPI0410322A - sistema de catalisador para a produção de ácido carboxìlico aromático por oxidação em fase liquìda de hidrocarbonetos aromáticos e processos de oxidação de hidrocarbonetos aromáticos e de redução da formação de brometo de alquila - Google Patents
sistema de catalisador para a produção de ácido carboxìlico aromático por oxidação em fase liquìda de hidrocarbonetos aromáticos e processos de oxidação de hidrocarbonetos aromáticos e de redução da formação de brometo de alquilaInfo
- Publication number
- BRPI0410322A BRPI0410322A BRPI0410322-0A BRPI0410322A BRPI0410322A BR PI0410322 A BRPI0410322 A BR PI0410322A BR PI0410322 A BRPI0410322 A BR PI0410322A BR PI0410322 A BRPI0410322 A BR PI0410322A
- Authority
- BR
- Brazil
- Prior art keywords
- aromatic
- production
- oxidation
- catalyst system
- processes
- Prior art date
Links
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 150000001347 alkyl bromides Chemical class 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 title 1
- 239000007791 liquid phase Substances 0.000 title 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001454 anthracenes Chemical class 0.000 abstract 1
- -1 aromatic carboxylic acids Chemical class 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
- C07C57/34—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings containing more than one carboxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/32—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of manganese, technetium or rhenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
"SISTEMA DE CATALISADOR PARA A PRODUçãO DE áCIDO CARBOXìLICO AROMáTICO POR OXIDAçãO EM FASE LìQUIDA DE HIDROCARBONETOS AROMáTICOS E PROCESSOS DE OXIDAçãO DE HIDROCARBONETOS AROMáTICOS E DE REDUçãO DE FORMAçãO DE BROMETO DE ALQUILA". O antraceno bromado é usado de modo efetivo num sistema catalisador como promotor para a oxidação catalítica de hidrocarbonetos aromáticos na produção de ácidos carboxílicos aromáticos e resulta em corrosão reduzida do equipamento do processo e formação reduzida de brometos de alquila, ao mesmo tempo que proporciona rendimento e qualidade comparáveis às dos promotores de bromo convencionais.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47668703P | 2003-06-06 | 2003-06-06 | |
| PCT/US2004/016694 WO2005000779A2 (en) | 2003-06-06 | 2004-05-27 | Oxidation of aromatic hydrocarbons using brominated anthracene promoters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0410322A true BRPI0410322A (pt) | 2006-05-23 |
Family
ID=33551633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0410322-0A BRPI0410322A (pt) | 2003-06-06 | 2004-05-27 | sistema de catalisador para a produção de ácido carboxìlico aromático por oxidação em fase liquìda de hidrocarbonetos aromáticos e processos de oxidação de hidrocarbonetos aromáticos e de redução da formação de brometo de alquila |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20050192459A1 (pt) |
| EP (1) | EP1631383B1 (pt) |
| JP (1) | JP2006527071A (pt) |
| KR (1) | KR20060015321A (pt) |
| CN (1) | CN1802210A (pt) |
| AT (1) | ATE367200T1 (pt) |
| BR (1) | BRPI0410322A (pt) |
| CA (1) | CA2524738A1 (pt) |
| DE (1) | DE602004007654T2 (pt) |
| ES (1) | ES2287753T3 (pt) |
| MX (1) | MXPA05013037A (pt) |
| MY (1) | MY141601A (pt) |
| RU (1) | RU2005138793A (pt) |
| TW (1) | TW200502210A (pt) |
| WO (1) | WO2005000779A2 (pt) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7378544B2 (en) * | 2003-12-18 | 2008-05-27 | Bp Corporation North America Inc. | Anthracene and other polycyclic aromatics as activators in the oxidation of aromatic hydrocarbons |
| CA2591414A1 (en) * | 2004-12-20 | 2006-06-29 | Process Design Center B.V. | Process for preparing aromatic carboxylic acids |
| US7550627B2 (en) | 2005-03-08 | 2009-06-23 | Eastman Chemical Company | Processes for producing aromatic dicarboxylic acids |
| RU2348608C1 (ru) * | 2007-08-23 | 2009-03-10 | Институт химической физики им. Н.Н. Семенова РАН (ИХФ РАН) | Способ получения алкилароматических монокарбоновых кислот |
| CN104226368A (zh) * | 2012-05-27 | 2014-12-24 | 中国石油化工股份有限公司 | 甲基芳烃氧化含溴化萘催化剂体系 |
| CN107774315B (zh) * | 2016-08-29 | 2020-09-04 | 中国石油化工股份有限公司 | 液相氧化制备芳香多元羧酸的催化剂 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL169993C (nl) * | 1972-01-13 | 1982-09-16 | Maruzen Oil Co Ltd | Werkwijze ter bereiding van tereftaalzuur. |
| DE3207572A1 (de) * | 1981-04-22 | 1982-11-11 | Rütgerswerke AG, 6000 Frankfurt | Verfahren zur oxidation von reaktiven aromaten |
| JPH01121240A (ja) * | 1987-11-02 | 1989-05-12 | Teijin Yuka Kk | 2,6−ナフタレンジカルボン酸の製造法 |
| JPH06228050A (ja) * | 1992-06-05 | 1994-08-16 | Sumikin Chem Co Ltd | 1,4,5,8−ナフタレンテトラカルボン酸の製造方法 |
| US5919977A (en) * | 1997-02-20 | 1999-07-06 | Mitsui Chemicals, Inc. | Process for producing aromatic carboxylic acid and apparatus therefor |
-
2004
- 2004-05-27 AT AT04753512T patent/ATE367200T1/de not_active IP Right Cessation
- 2004-05-27 JP JP2006514991A patent/JP2006527071A/ja not_active Withdrawn
- 2004-05-27 WO PCT/US2004/016694 patent/WO2005000779A2/en not_active Ceased
- 2004-05-27 CA CA002524738A patent/CA2524738A1/en not_active Abandoned
- 2004-05-27 RU RU2005138793/04A patent/RU2005138793A/ru not_active Application Discontinuation
- 2004-05-27 US US10/854,815 patent/US20050192459A1/en not_active Abandoned
- 2004-05-27 ES ES04753512T patent/ES2287753T3/es not_active Expired - Lifetime
- 2004-05-27 MX MXPA05013037A patent/MXPA05013037A/es unknown
- 2004-05-27 BR BRPI0410322-0A patent/BRPI0410322A/pt not_active IP Right Cessation
- 2004-05-27 DE DE602004007654T patent/DE602004007654T2/de not_active Expired - Lifetime
- 2004-05-27 KR KR1020057022807A patent/KR20060015321A/ko not_active Withdrawn
- 2004-05-27 EP EP04753512A patent/EP1631383B1/en not_active Expired - Lifetime
- 2004-05-27 CN CNA2004800157981A patent/CN1802210A/zh active Pending
- 2004-06-03 MY MYPI20042153A patent/MY141601A/en unknown
- 2004-06-04 TW TW093116125A patent/TW200502210A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2524738A1 (en) | 2005-01-06 |
| MXPA05013037A (es) | 2006-03-02 |
| TW200502210A (en) | 2005-01-16 |
| KR20060015321A (ko) | 2006-02-16 |
| WO2005000779A3 (en) | 2005-03-03 |
| WO2005000779A2 (en) | 2005-01-06 |
| US20050192459A1 (en) | 2005-09-01 |
| ES2287753T3 (es) | 2007-12-16 |
| DE602004007654T2 (de) | 2008-04-10 |
| MY141601A (en) | 2010-05-31 |
| EP1631383A2 (en) | 2006-03-08 |
| EP1631383B1 (en) | 2007-07-18 |
| DE602004007654D1 (de) | 2007-08-30 |
| RU2005138793A (ru) | 2006-05-10 |
| JP2006527071A (ja) | 2006-11-30 |
| ATE367200T1 (de) | 2007-08-15 |
| CN1802210A (zh) | 2006-07-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 6A, 7A E 8A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2159 DE 22/05/2012. |