BRPI0410365A - processo para produzir produtos liquidos e, opcionalmente, produtos gasosos a partir de reagentes gasosos - Google Patents
processo para produzir produtos liquidos e, opcionalmente, produtos gasosos a partir de reagentes gasososInfo
- Publication number
- BRPI0410365A BRPI0410365A BRPI0410365-3A BRPI0410365A BRPI0410365A BR PI0410365 A BRPI0410365 A BR PI0410365A BR PI0410365 A BRPI0410365 A BR PI0410365A BR PI0410365 A BRPI0410365 A BR PI0410365A
- Authority
- BR
- Brazil
- Prior art keywords
- products
- gaseous
- optionally
- reagents
- producing liquid
- Prior art date
Links
- 239000003153 chemical reaction reagent Substances 0.000 title abstract 5
- 239000012263 liquid product Substances 0.000 title abstract 3
- 239000000047 product Substances 0.000 title abstract 3
- 239000000725 suspension Substances 0.000 abstract 5
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
- B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
- B01J8/28—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
- C10G2/343—Apparatus, reactors with moving solid catalysts according to the "moving-bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00141—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00539—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/0061—Controlling the level
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Treating Waste Gases (AREA)
Abstract
"PROCESSO PARA PRODUZIR PRODUTOS LIQUIDOS E, OPCIONALMENTE, PRODUTOS GASOSOS A PARTIR DE REAGENTES GASOSOS". A invenção descreve um processo (10) para produzir produtos líquidos e, opcionalmente, produtos gasosos, a partir de reagentes gasosos e inclui alimentar em um nível baixo reagentes gasosos (14) e, opcionalmente, uma porção de uma corrente de gás de reciclo em um leito de suspensão que se estende verticalmente (70) de partículas sólidas suspensas em um liquido de suspensão no interior do reator (12), e alimentar, como uma alimentação adicional de gas (58), ao menos uma porção da corrente de gás reciclado no interior do leito de suspensão (70) acima do nível no qual os reagentes gasosos (14) são alimentados no leito de suspensão (70) e acima dos 20% inferiores da altura vertical do leito de suspensão (70).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47132303P | 2003-05-16 | 2003-05-16 | |
| US60/471,323 | 2003-05-16 | ||
| PCT/IB2004/050656 WO2004101475A1 (en) | 2003-05-16 | 2004-05-12 | Process for producing liquid and, optionally, gaseous products from gaseous reactants |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0410365A true BRPI0410365A (pt) | 2006-05-30 |
| BRPI0410365B1 BRPI0410365B1 (pt) | 2014-09-09 |
Family
ID=33452435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0410365-3B1A BRPI0410365B1 (pt) | 2003-05-16 | 2004-05-12 | Processo para produzir produtos liquidos e, opcionalmente, produtos gasosos a partir de reagentes gasosos |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7439274B2 (pt) |
| EP (1) | EP1636151B1 (pt) |
| JP (1) | JP4966654B2 (pt) |
| CN (1) | CN100378043C (pt) |
| AT (1) | ATE405534T1 (pt) |
| AU (1) | AU2004238648B2 (pt) |
| BR (1) | BRPI0410365B1 (pt) |
| CA (1) | CA2525007C (pt) |
| DE (1) | DE602004015984D1 (pt) |
| NO (1) | NO20055938L (pt) |
| RU (1) | RU2342355C2 (pt) |
| WO (1) | WO2004101475A1 (pt) |
| ZA (1) | ZA200508993B (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4731553B2 (ja) * | 2004-05-10 | 2011-07-27 | サソール テクノロジー(プロプライエタリー)リミテッド | 膨張するスラリー床内への気体の反応物質からの液体のまた任意に気体の炭化水素の生成 |
| NL2000029C2 (nl) | 2005-03-17 | 2007-06-14 | Sasol Tech Pty Ltd | Werkwijze voor het bedienen van een driefase-slurryreactor en een driefase-slurryreactor. |
| BRPI0608541B1 (pt) * | 2005-03-17 | 2015-07-28 | Sasol Techology Proprietary | Métodos para operar um reator de leito fluidizado bifásico e para operar um reator de lama trifásico, e, reatores de leito fluidizado bifásico e de lama trifásico |
| FR2900065B1 (fr) * | 2006-04-21 | 2008-05-30 | Inst Francais Du Petrole | Nouvel echangeur interne pour reacteur gaz liquide solide destine a la synthese fischer tropsch. |
| FR2900066B1 (fr) | 2006-04-21 | 2008-05-30 | Inst Francais Du Petrole | Nouvel echangeur interne pour reacteur en lit fluidise gaz liquide solide, mettant en oeuvre une reaction fortement exothermique. |
| BRPI0816137B1 (pt) * | 2007-08-24 | 2017-05-02 | Sasol Tech (Proprietary) Ltd | processo de síntese de hidrocarbonetos para produzir produtos líquidos e gasosos a partir de reagentes gasosos |
| CN102165038B (zh) * | 2008-09-30 | 2013-10-16 | 日本石油天然气·金属矿物资源机构 | 烃合成反应装置、烃合成反应系统以及烃合成方法 |
| AU2011342806B2 (en) * | 2010-12-13 | 2016-05-26 | Sasol Technology (Proprietary) Limited | Slurry phase apparatus |
| BR112013031529B1 (pt) | 2011-06-07 | 2020-11-10 | Sasol Technology (Proprietary) Limited | processos de leito fluido |
| BR112014002629A2 (pt) | 2011-08-04 | 2017-05-02 | A Stuart Martin | forno de arco de plasma e aplicações |
| CN102703107B (zh) * | 2012-06-26 | 2015-04-01 | 武汉凯迪工程技术研究总院有限公司 | 一种由生物质生产的合成气制造液态烃产品的方法 |
| WO2015172132A1 (en) | 2014-05-09 | 2015-11-12 | Cunningham Stephen L | Arc furnace smeltering system & method |
| WO2023118974A1 (en) * | 2021-12-24 | 2023-06-29 | Vinati Organics Limited | An agitator reactor for synthesis of acrylamido tertiary butyl sulfonic acid and process implemented thereon |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2463912A (en) * | 1946-12-12 | 1949-03-08 | Standard Oil Dev Co | Synthesis of hydrocarbons |
| US2560171A (en) * | 1947-03-03 | 1951-07-10 | Kellogg M W Co | Synthesis of organic compounds |
| US2481089A (en) * | 1947-03-06 | 1949-09-06 | M K Kellogg Company | Process and apparatus for the synthesis of organic compounds |
| US4035152A (en) * | 1976-05-24 | 1977-07-12 | The United States Of America As Represented By The United States Energy Research And Development Administration | Distribution plate for recirculating fluidized bed |
| JPS6490030A (en) * | 1987-10-01 | 1989-04-05 | Mitsubishi Heavy Ind Ltd | Three-phase fluidized reactor |
| US5252613A (en) * | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
| IT1283774B1 (it) * | 1996-08-07 | 1998-04-30 | Agip Petroli | Processo di fischer-tropsch con reattore a colonna a bolle multistadio |
| US5817702A (en) * | 1997-05-02 | 1998-10-06 | Exxon Research And Engineering Company | Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement |
| ZA985992B (en) * | 1997-07-15 | 2000-01-10 | Sasol Tech Pty Ltd | A process for producing liquid and, optionally, gaseous products from gaseous reactants. |
| US6160026A (en) * | 1997-09-24 | 2000-12-12 | Texaco Inc. | Process for optimizing hydrocarbon synthesis |
| US6203031B1 (en) | 1998-12-07 | 2001-03-20 | Steelworks, Inc. | File cabinet dolly with open frame |
| FR2795001B1 (fr) * | 1999-06-17 | 2001-08-17 | Cogema | Procede et installation de mise en oeuvre d'une reaction chimique triphasique sous pression |
| IT1312356B1 (it) * | 1999-06-17 | 2002-04-15 | Eni Spa | Procedimento migliorato di fischer-tropsch |
| US6455644B1 (en) * | 2000-02-28 | 2002-09-24 | Union Carbide Chemicals & Plastics Technology Corporation | Polyolefin production using condensing mode in fluidized beds, with liquid phase enrichment and bed injection |
| CN2562866Y (zh) * | 2002-02-01 | 2003-07-30 | 中国石油天然气股份有限公司 | 多级环流反应器 |
| US6800664B1 (en) * | 2003-05-23 | 2004-10-05 | Conocophillips Company | Conjoined reactor system |
-
2004
- 2004-05-12 JP JP2006526468A patent/JP4966654B2/ja not_active Expired - Lifetime
- 2004-05-12 RU RU2005138918/04A patent/RU2342355C2/ru not_active Application Discontinuation
- 2004-05-12 DE DE602004015984T patent/DE602004015984D1/de not_active Expired - Fee Related
- 2004-05-12 EP EP04732393A patent/EP1636151B1/en not_active Expired - Lifetime
- 2004-05-12 AT AT04732393T patent/ATE405534T1/de not_active IP Right Cessation
- 2004-05-12 BR BRPI0410365-3B1A patent/BRPI0410365B1/pt not_active IP Right Cessation
- 2004-05-12 WO PCT/IB2004/050656 patent/WO2004101475A1/en not_active Ceased
- 2004-05-12 AU AU2004238648A patent/AU2004238648B2/en not_active Ceased
- 2004-05-12 US US10/555,957 patent/US7439274B2/en not_active Expired - Lifetime
- 2004-05-12 CN CNB2004800129695A patent/CN100378043C/zh not_active Expired - Fee Related
- 2004-05-12 CA CA2525007A patent/CA2525007C/en not_active Expired - Fee Related
-
2005
- 2005-11-07 ZA ZA200508993A patent/ZA200508993B/en unknown
- 2005-12-14 NO NO20055938A patent/NO20055938L/no not_active Application Discontinuation
-
2008
- 2008-08-15 US US12/192,337 patent/US20080299022A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| RU2342355C2 (ru) | 2008-12-27 |
| DE602004015984D1 (de) | 2008-10-02 |
| NO20055938L (no) | 2005-12-14 |
| JP4966654B2 (ja) | 2012-07-04 |
| AU2004238648A1 (en) | 2004-11-25 |
| CA2525007C (en) | 2012-02-14 |
| EP1636151A1 (en) | 2006-03-22 |
| EP1636151B1 (en) | 2008-08-20 |
| US7439274B2 (en) | 2008-10-21 |
| RU2005138918A (ru) | 2006-05-10 |
| US20070043125A1 (en) | 2007-02-22 |
| BRPI0410365B1 (pt) | 2014-09-09 |
| JP2007501121A (ja) | 2007-01-25 |
| ZA200508993B (en) | 2006-12-27 |
| AU2004238648B2 (en) | 2009-05-14 |
| US20080299022A1 (en) | 2008-12-04 |
| CA2525007A1 (en) | 2004-11-25 |
| WO2004101475A1 (en) | 2004-11-25 |
| ATE405534T1 (de) | 2008-09-15 |
| CN100378043C (zh) | 2008-04-02 |
| CN1787982A (zh) | 2006-06-14 |
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