BRPI0410604A - processo para a preparação de caprolactama - Google Patents

processo para a preparação de caprolactama

Info

Publication number
BRPI0410604A
BRPI0410604A BRPI0410604-0A BRPI0410604A BRPI0410604A BR PI0410604 A BRPI0410604 A BR PI0410604A BR PI0410604 A BRPI0410604 A BR PI0410604A BR PI0410604 A BRPI0410604 A BR PI0410604A
Authority
BR
Brazil
Prior art keywords
tube
reaction mixture
sup
channels
fed
Prior art date
Application number
BRPI0410604-0A
Other languages
English (en)
Inventor
Petrus Jozef Hubertu Thomissen
Joannes Albertus Wilhe Lemmens
Theodorus Maria Smeets
Original Assignee
Dsm Ip Assets Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets Bv filed Critical Dsm Ip Assets Bv
Publication of BRPI0410604A publication Critical patent/BRPI0410604A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B01F25/3121—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof with additional mixing means other than injector mixers, e.g. screens, baffles or rotating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B01F25/3124—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow
    • B01F25/31242—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow the main flow being injected in the central area of the venturi, creating an aspiration in the circumferential part of the conduit
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Spinning Or Twisting Of Yarns (AREA)

Abstract

"PROCESSO PARA A PREPARAçãO DE CAPROLACTAMA". A invenção se relaciona a um processo para a preparação de caprolactama por rearranjo de Beckmann da ciclohexanona oxima através do suprimento de ciclohexanona oxima à mistura de reação que compreende (i) ácido sulfúrico (ii) SO~ 3~ e (iii) caprolactama, onde o conteúdo de SO~ 3~ da mistura de reação está entre 9 e 20% em peso e a proporção molar M da mistura de reação definida como (n~ SO3~ + n~ H2SO4~)/ncap está entre 1 e 1,4, em que: n~ S03~ = quantidade de SO~ 3~ na mistura de reação, em mol; n~ H2SO4~ = quantidade de H~ 2~S0~ 4~ na mistura de reaçao, em mol; n~ cap~ = quantidade de caprolactama na mistura de reação, em mol.
BRPI0410604-0A 2003-05-23 2004-05-17 processo para a preparação de caprolactama BRPI0410604A (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP03076591 2003-05-23
EP03076590 2003-05-23
EP03076592 2003-05-23
EP03076589 2003-05-23
PCT/EP2004/005340 WO2004103963A1 (en) 2003-05-23 2004-05-17 Process for preparing caprolactam by beckmann rearrangement

Publications (1)

Publication Number Publication Date
BRPI0410604A true BRPI0410604A (pt) 2006-06-20

Family

ID=33479744

Family Applications (3)

Application Number Title Priority Date Filing Date
BRPI0410604-0A BRPI0410604A (pt) 2003-05-23 2004-05-17 processo para a preparação de caprolactama
BRPI0410577-0A BRPI0410577A (pt) 2003-05-23 2004-05-17 processo contìnuo para a preparação de caprolactama
BRPI0410587-7A BRPI0410587A (pt) 2003-05-23 2004-05-17 processo para preparação de caprolactama por mistura de oxima de ciclohexanona a uma mistura reacional

Family Applications After (2)

Application Number Title Priority Date Filing Date
BRPI0410577-0A BRPI0410577A (pt) 2003-05-23 2004-05-17 processo contìnuo para a preparação de caprolactama
BRPI0410587-7A BRPI0410587A (pt) 2003-05-23 2004-05-17 processo para preparação de caprolactama por mistura de oxima de ciclohexanona a uma mistura reacional

Country Status (15)

Country Link
US (3) US7339056B2 (pt)
EP (3) EP1633706B1 (pt)
JP (3) JP5014791B2 (pt)
KR (3) KR101199719B1 (pt)
CN (2) CN104262223A (pt)
AT (3) ATE504564T1 (pt)
BR (3) BRPI0410604A (pt)
DE (3) DE602004026866D1 (pt)
EA (3) EA009914B1 (pt)
MX (3) MXPA05012688A (pt)
MY (2) MY139965A (pt)
PL (1) PL1628955T3 (pt)
TW (3) TWI335317B (pt)
UA (1) UA83663C2 (pt)
WO (3) WO2004103963A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399188B (zh) * 2010-09-10 2014-02-19 北京化工大学 一种贝克曼重排反应方法
WO2012141997A1 (en) 2011-04-09 2012-10-18 Amyris, Inc. Process for preparing caprolactam and polyamides therefrom
CN102229553B (zh) * 2011-05-06 2012-10-10 清华大学 一种多段重排由环己酮肟制备己内酰胺的系统及方法
CN103007869B (zh) * 2011-09-20 2015-02-25 中国石油化工股份有限公司 一种己内酰胺重排反应的三液相进料喷嘴
CN105085354B (zh) * 2014-05-07 2018-09-28 中国石油化工股份有限公司 一种己内酰胺制备方法
TWI882026B (zh) 2019-11-11 2025-05-01 荷蘭商卡普三世責任有限公司 工業規模上用於生產ε-己內醯胺及硫酸銨之方法及設備
CN115073343B (zh) * 2022-06-29 2023-09-29 中国天辰工程有限公司 一种不副产硫酸铵的己内酰胺合成方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2237365A (en) * 1938-11-28 1941-04-08 Ig Farbenindustrie Ag Production of oximes
CH519448A (de) * 1968-04-11 1972-02-29 Inventa Ag Mischvorrichtung
CH454876A (de) * 1966-01-14 1968-04-30 Inventa Ag Verfahren zur kontinuierlichen Herstellung von Lactamen
US3914217A (en) * 1974-11-13 1975-10-21 Allied Chem Process for the preparation of lactams
DE2547025A1 (de) * 1974-11-13 1976-05-26 Allied Chem Verfahren zur herstellung von epsilon-caprolactam
US3953438A (en) * 1975-02-07 1976-04-27 Eli Lilly And Company Preparation of cephalosporin ethers
JPS52135308A (en) * 1976-05-07 1977-11-12 Toa Nekken Kk Mixer for emulsifying water and oil
NL7609749A (nl) * 1976-09-02 1978-03-06 Stamicarbon Werkwijze voor de bereiding van lactamen uit cyclische oximen.
DE2845019A1 (de) * 1978-10-16 1980-04-30 Basf Ag Verfahren zur kontinuierlichen herstellung von epsilon -caprolactam durch beckmann'sche umlagerung
JPS61138529A (ja) * 1984-12-10 1986-06-26 Idemitsu Petrochem Co Ltd サイズ用乳化液の製造方法
DE3642314A1 (de) * 1986-12-11 1988-06-23 Basf Ag Verfahren zur herstellung von caprolactam durch beckmannsche umlagerung von cyclohexanonoxim
IT1204503B (it) * 1987-03-11 1989-03-03 Montedipe Spa Processo per la sintesi dell'epsiloncaprolattame
JPH0737435B2 (ja) * 1988-07-12 1995-04-26 三菱化学株式会社 オキシム類の製法
JP2576279Y2 (ja) * 1993-02-19 1998-07-09 敏克 清水 ボルドー液の調製装置
KR970706249A (ko) 1995-07-20 1997-11-03 미우라 아끼라 엡실론-카프로락탐의 제조방법(process for the preparation of epsilon-caprolactam)
JPH1036332A (ja) * 1996-07-22 1998-02-10 Toray Ind Inc シクロヘキサノンオキシム塩酸塩の精製方法
JPH10180066A (ja) * 1996-12-26 1998-07-07 Jiinasu:Kk 微粒化方法及びその装置
US6333411B1 (en) * 1998-12-24 2001-12-25 Praxair Technology, Inc. Method for production of hydroxylammonium phosphate in the synthesis of caprolactam
EP1299353B1 (en) * 2000-06-05 2006-04-12 DSM IP Assets B.V. Process for the preparation of cyclohexanone oxime
ATE425958T1 (de) * 2000-06-05 2009-04-15 Dsm Ip Assets Bv Verfahren zur herstellung von cyclohexanonoxim
EP1301468B1 (en) * 2000-06-05 2004-08-04 DSM IP Assets B.V. Process for the production of cyclohexanone oxime
JP4223694B2 (ja) * 2001-03-28 2009-02-12 住友化学株式会社 シクロヘキサノンオキシムの蒸発方法
JP2005510562A (ja) 2001-11-26 2005-04-21 ディーエスエム アイピー アセッツ ビー．ブイ． カプロラクタムの回収方法

Also Published As

Publication number Publication date
KR20060015616A (ko) 2006-02-17
CN104262223A (zh) 2015-01-07
DE602004009173D1 (de) 2007-11-08
DE602004026866D1 (de) 2010-06-10
US20070055061A1 (en) 2007-03-08
TW200502217A (en) 2005-01-16
US7351820B2 (en) 2008-04-01
EA200501857A1 (ru) 2006-06-30
TWI335317B (en) 2011-01-01
JP2007520445A (ja) 2007-07-26
EP1626953B1 (en) 2007-09-26
JP2007513061A (ja) 2007-05-24
JP5014791B2 (ja) 2012-08-29
ATE374179T1 (de) 2007-10-15
TW200505851A (en) 2005-02-16
MXPA05012688A (es) 2006-02-22
TWI335318B (en) 2011-01-01
US7358357B2 (en) 2008-04-15
US20070083043A1 (en) 2007-04-12
WO2004103964A1 (en) 2004-12-02
EA009914B1 (ru) 2008-04-28
MXPA05012689A (es) 2006-02-22
KR20060006088A (ko) 2006-01-18
JP5014792B2 (ja) 2012-08-29
KR20060015615A (ko) 2006-02-17
MXPA05012621A (es) 2006-02-08
MY139965A (en) 2009-11-30
DE602004009173T2 (de) 2008-06-26
BRPI0410587A (pt) 2006-06-20
US7339056B2 (en) 2008-03-04
KR101199719B1 (ko) 2012-11-08
ATE504564T1 (de) 2011-04-15
KR101177137B1 (ko) 2012-08-24
BRPI0410577A (pt) 2006-06-20
UA83663C2 (ru) 2008-08-11
JP2007500198A (ja) 2007-01-11
EP1633706B1 (en) 2010-04-28
MY140436A (en) 2009-12-31
EP1628955B1 (en) 2011-04-06
EP1633706A1 (en) 2006-03-15
EA010840B1 (ru) 2008-12-30
TW200427658A (en) 2004-12-16
EA009600B1 (ru) 2008-02-28
EP1628955B9 (en) 2012-01-04
CN1842519A (zh) 2006-10-04
US20070060749A1 (en) 2007-03-15
EP1626953A1 (en) 2006-02-22
EP1628955A1 (en) 2006-03-01
EA200501850A1 (ru) 2006-08-25
CN1842519B (zh) 2011-06-15
WO2004113287A1 (en) 2004-12-29
TWI337991B (en) 2011-03-01
ATE465991T1 (de) 2010-05-15
WO2004103963A1 (en) 2004-12-02
EA200501858A1 (ru) 2006-06-30
PL1628955T3 (pl) 2011-09-30
DE602004032128D1 (de) 2011-05-19

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 10A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2259 DE 22/04/2014.