BRPI0412708A - catalisador e processo para a produção de ácido acético - Google Patents
catalisador e processo para a produção de ácido acéticoInfo
- Publication number
- BRPI0412708A BRPI0412708A BRPI0412708-0A BRPI0412708A BRPI0412708A BR PI0412708 A BRPI0412708 A BR PI0412708A BR PI0412708 A BRPI0412708 A BR PI0412708A BR PI0412708 A BRPI0412708 A BR PI0412708A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- production
- acetic acid
- acid
- carbonylation
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 230000006315 carbonylation Effects 0.000 abstract 2
- 238000005810 carbonylation reaction Methods 0.000 abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 239000011964 heteropoly acid Substances 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 150000004715 keto acids Chemical class 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 239000003930 superacid Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"CATALISADOR E PROCESSO PARA A PRODUçãO DE áCIDO ACéTICO". Um catalisador e processo para a produção de ácido acético pela a carbonilação de metanol e/ou um derivado reativo do mesmo. O sistema de catalisador compreende um catalisador de carbonilação de irídio, co-catalisador de iodeto de metila, opcionalmente pelo menos um de rutênio, ósmio, rênio, zinco, gálio, tungstênio, cádmio, mercúrio e índio e pelo menos um promotor de ácido não-hidrohalogenóico. O ácido não-hidrohalogenóico pode ser um oxoácido, um superácido e/ou um heteropoliácido.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0316756.6A GB0316756D0 (en) | 2003-07-17 | 2003-07-17 | Process |
| PCT/GB2004/002686 WO2005009939A1 (en) | 2003-07-17 | 2004-06-23 | Catalyst and process for the production of acetic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0412708A true BRPI0412708A (pt) | 2006-09-26 |
| BRPI0412708B1 BRPI0412708B1 (pt) | 2013-10-15 |
Family
ID=27764007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0412708-0B1A BRPI0412708B1 (pt) | 2003-07-17 | 2004-06-23 | Catalisador e processo para a produção de ácido acético |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7915446B2 (pt) |
| EP (1) | EP1646602A1 (pt) |
| JP (1) | JP5336701B2 (pt) |
| KR (1) | KR101286321B1 (pt) |
| CN (1) | CN1823031B (pt) |
| BR (1) | BRPI0412708B1 (pt) |
| CA (1) | CA2532234C (pt) |
| GB (1) | GB0316756D0 (pt) |
| MY (1) | MY146559A (pt) |
| NO (1) | NO20060759L (pt) |
| RS (1) | RS20060025A (pt) |
| RU (1) | RU2336262C2 (pt) |
| TW (1) | TWI343371B (pt) |
| UA (1) | UA89475C2 (pt) |
| WO (1) | WO2005009939A1 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0427821D0 (en) * | 2004-12-17 | 2005-01-19 | Bp Chem Int Ltd | Catalyst and process |
| GB0601863D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
| GB0601861D0 (en) | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
| GB0601865D0 (en) * | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
| EP2075070A1 (en) * | 2007-12-13 | 2009-07-01 | BP Chemicals Limited | Catalyst recovery process |
| EP2327474B1 (en) * | 2008-04-29 | 2018-01-10 | Celanese International Corporation | Methanol carbonylation system having absorber with multiple solvent options |
| US9421522B2 (en) * | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
| PL2970890T3 (pl) | 2013-03-14 | 2020-11-16 | The Brigham And Women's Hospital, Inc. | Kompozycje i sposoby ekspansji i hodowli nabłonkowych komórek macierzystych |
| US11021687B2 (en) | 2016-01-08 | 2021-06-01 | The Brigham And Women's Hospital, Inc. | Production of differentiated enteroendocrine cells and insulin producing cells |
| US11260130B2 (en) | 2016-03-02 | 2022-03-01 | Frequency Therapeutics, Inc. | Solubilized compositions for controlled proliferation of stem cells / generating inner ear hair cells using a GSK3 inhibitor: IV |
| US10213511B2 (en) | 2016-03-02 | 2019-02-26 | Frequency Therapeutics, Inc. | Thermoreversible compositions for administration of therapeutic agents |
| US10201540B2 (en) | 2016-03-02 | 2019-02-12 | Frequency Therapeutics, Inc. | Solubilized compositions for controlled proliferation of stem cells / generating inner ear hair cells using GSK3 inhibitors: I |
| CN108067222B (zh) * | 2016-11-15 | 2020-09-22 | 中国科学院大连化学物理研究所 | 活性炭载体负载的硫促进的铱基催化剂及其制备和应用 |
| EP3562827A1 (en) | 2016-12-30 | 2019-11-06 | Frequency Therapeutics, Inc. | 1h-pyrrole-2,5-dione compounds and methods of using them to induce self-renewal of stem/progenitor supporting cells |
| CN109759055B (zh) * | 2017-11-09 | 2022-04-15 | 中国科学院大连化学物理研究所 | 一种活性炭负载的含硫铱基催化剂及其制备与应用 |
| CN108097319A (zh) * | 2017-12-19 | 2018-06-01 | 宁夏大学 | 羰基化制备醋酸的铑钌联用双金属催化剂及其制备方法 |
| US11617745B2 (en) | 2018-08-17 | 2023-04-04 | Frequency Therapeutics, Inc. | Compositions and methods for generating hair cells by downregulating FOXO |
| JP2021533788A (ja) | 2018-08-17 | 2021-12-09 | フリークエンシー セラピューティクス インコーポレイテッド | Jag−1を上方制御することにより有毛細胞を生成するための組成物及び方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1941449C3 (de) * | 1968-08-15 | 1979-07-26 | Monsanto Co., St. Louis, Mo. (V.St.A.) | Verfahren zur Herstellung von Monocarbonsäuren |
| JPS4924459B1 (pt) * | 1969-08-27 | 1974-06-22 | ||
| CA1195340A (en) * | 1980-11-14 | 1985-10-15 | The Standard Oil Company | Selective hydrocarboxylation of propylene to isobutyric acid |
| US4629809A (en) * | 1983-07-21 | 1986-12-16 | Texaco Inc. | Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system |
| US5281751A (en) * | 1983-12-02 | 1994-01-25 | Union Carbide Chemicals And Plastics Company Inc. | Synergistic production of carboxylic acids from alcohols |
| JP2782363B2 (ja) * | 1989-08-25 | 1998-07-30 | 日本石油化学株式会社 | α−(4−イソブチルフェニル)プロピオン酸またはそのエステルの製造方法 |
| US5672743A (en) * | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
| FR2703351A1 (fr) * | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium. |
| US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| US5710325A (en) * | 1996-11-01 | 1998-01-20 | E. I. Du Pont De Nemours And Company | Manufacture of adipic acid |
| US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
| GB9626324D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| US6521783B1 (en) * | 1998-01-29 | 2003-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates |
| GB9819079D0 (en) * | 1998-09-03 | 1998-10-28 | Bp Chem Int Ltd | Carbonylation process |
| GB9926855D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
| GB9926854D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
| GB0212974D0 (en) | 2002-06-06 | 2002-07-17 | Bp Chem Int Ltd | Process |
-
2003
- 2003-07-17 GB GBGB0316756.6A patent/GB0316756D0/en not_active Ceased
-
2004
- 2004-06-23 CN CN200480020623XA patent/CN1823031B/zh not_active Expired - Fee Related
- 2004-06-23 KR KR1020057025331A patent/KR101286321B1/ko not_active Expired - Fee Related
- 2004-06-23 RS YUP-2006/0025A patent/RS20060025A/sr unknown
- 2004-06-23 EP EP04743037A patent/EP1646602A1/en not_active Withdrawn
- 2004-06-23 UA UAA200601526A patent/UA89475C2/uk unknown
- 2004-06-23 JP JP2006519986A patent/JP5336701B2/ja not_active Expired - Fee Related
- 2004-06-23 BR BRPI0412708-0B1A patent/BRPI0412708B1/pt not_active IP Right Cessation
- 2004-06-23 US US10/563,920 patent/US7915446B2/en not_active Expired - Fee Related
- 2004-06-23 CA CA2532234A patent/CA2532234C/en not_active Expired - Fee Related
- 2004-06-23 RU RU2006104673/04A patent/RU2336262C2/ru not_active IP Right Cessation
- 2004-06-23 WO PCT/GB2004/002686 patent/WO2005009939A1/en not_active Ceased
- 2004-06-25 TW TW093118521A patent/TWI343371B/zh not_active IP Right Cessation
- 2004-07-14 MY MYPI20042811A patent/MY146559A/en unknown
-
2006
- 2006-02-17 NO NO20060759A patent/NO20060759L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP5336701B2 (ja) | 2013-11-06 |
| CA2532234C (en) | 2012-05-01 |
| UA89475C2 (uk) | 2010-02-10 |
| TWI343371B (en) | 2011-06-11 |
| GB0316756D0 (en) | 2003-08-20 |
| WO2005009939A1 (en) | 2005-02-03 |
| BRPI0412708B1 (pt) | 2013-10-15 |
| RS20060025A (sr) | 2008-06-05 |
| KR101286321B1 (ko) | 2013-07-15 |
| RU2006104673A (ru) | 2007-09-20 |
| KR20060030067A (ko) | 2006-04-07 |
| MY146559A (en) | 2012-08-30 |
| US7915446B2 (en) | 2011-03-29 |
| US20060155144A1 (en) | 2006-07-13 |
| RU2336262C2 (ru) | 2008-10-20 |
| EP1646602A1 (en) | 2006-04-19 |
| JP2007516064A (ja) | 2007-06-21 |
| NO20060759L (no) | 2006-04-12 |
| TW200505844A (en) | 2005-02-16 |
| CN1823031B (zh) | 2010-06-23 |
| CA2532234A1 (en) | 2005-02-03 |
| CN1823031A (zh) | 2006-08-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0412708A (pt) | catalisador e processo para a produção de ácido acético | |
| AR002559A1 (es) | Proceso para la carbonilacion de alcoholes alquilicos y/o derivados reactivos de los mismos | |
| ES2116539T3 (es) | Proceso y catalizador para la produccion de acido acetico. | |
| Wang et al. | Synthesis of Active Hexafluoroisopropyl Benzoates through a Hydrogen‐Bond‐Enabled Palladium (II)‐Catalyzed C− H Alkoxycarbonylation Reaction | |
| AR010832A1 (es) | Proceso de carbonilacion catalizado con iridio para la produccion de acido acetico. | |
| JP2007516064A5 (pt) | ||
| AR040799A1 (es) | Procedimiento y dispositivo para la obtencion de formiato de acido formico y su uso | |
| CY1113461T1 (el) | Μη συνεζευγμενο χολικο οξυ μαζι με propyl gallate και/ή βηα για την αυξηση της απορροφησης μακρο-μοριων | |
| ATE438937T1 (de) | Antenne für windschutzscheibe oder heckscheibe eines fahrzeuges | |
| WO2001034545A3 (de) | Verfahren zur herstellung von ameisensäure | |
| BR9809715B1 (pt) | catalisador para produÇço de acetato vinÍlico por reaÇço de etileno, oxigÊnio e Ácido acÉtico e processo para produÇço do mesmo. | |
| BR0010149A (pt) | Método e sistema de catalisador para produzir carbonatos aromáticos | |
| BRPI0410209A (pt) | sistema de célula de combustìvel, e, método de operação de um sistema de célula de combustìvel | |
| AU2003263311A1 (en) | Process for the production of acetic acid | |
| AU2002213847A1 (en) | Antioxidant agent based on phenolic salts | |
| Ballard et al. | Kinamycin-mediated DNA cleavage under biomimetic conditions | |
| BR0013681A (pt) | Processo contìnuo para produzir ácido acético mediante reação de metanol com monóxido de carbono em um meio lìquido de reação | |
| EP1619239A3 (de) | Biogasanlage zur Fermentation von organischen Stoffen | |
| BRPI0417575A (pt) | complexo de monociclopentadienila, sistema catalisador, uso do mesmo, processos para preparar poliolefinas, e sistemas de ciclopentadieno, sistema de ciclopentadieno, e, ciclopentenona | |
| ID28477A (id) | Metoda pembuatan asam asetat dan/atau metil asetat dengan adanya iridium dan platinum | |
| YU17701A (sh) | Postupak za proizvodnju acetata alfa tokoferola | |
| Chang et al. | Study of ion-pair return in 2-norbornyl brosylate by means of oxygen-17 NMR | |
| AU6602301A (en) | Perfluorosulfonic acid membranes, method for the production and use thereof for fuel cells | |
| Stellwagen et al. | The alkaline isomerization of lysine-modified ferricytochrome c | |
| EP0924187A3 (en) | Organic ester plasticizers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/06/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |