ES2116539T3 - Proceso y catalizador para la produccion de acido acetico. - Google Patents
Proceso y catalizador para la produccion de acido acetico.Info
- Publication number
- ES2116539T3 ES2116539T3 ES94306506T ES94306506T ES2116539T3 ES 2116539 T3 ES2116539 T3 ES 2116539T3 ES 94306506 T ES94306506 T ES 94306506T ES 94306506 T ES94306506 T ES 94306506T ES 2116539 T3 ES2116539 T3 ES 2116539T3
- Authority
- ES
- Spain
- Prior art keywords
- acetic acid
- production
- catalyst
- derivative
- osmio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/20—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
- C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
UN PROCESO PARA LA PRODUCCION DE ACIDO ACETICO MEDIANTE LA CARBONILACION DE UN DERIVADO REACTIVO DEL MISMO A TRAVES DEL CONTACTO DE METANOL O DERIVADO CON MONOXIDO DE CARBONO EN UNA COMPOSICION DE REACCION LIQUIDA QUE CONSTA DE (A) ACIDO ACETICO, (B) UN CATALIZADOR DE IRIDIO, (C) IODURO DE METILO, (D) AL MENOS UNA CANTIDAD FINITA DE AGUA Y (E) EL ACETATO DE METILO SE MEJORA A TRAVES DEL USO DE AL MENOS RUTENIO U OSMIO COMO PROMOTOR.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB939318809A GB9318809D0 (en) | 1993-09-10 | 1993-09-10 | Process |
| GB9408966A GB9408966D0 (en) | 1994-05-05 | 1994-05-05 | Process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2116539T3 true ES2116539T3 (es) | 1998-07-16 |
Family
ID=26303500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94306506T Expired - Lifetime ES2116539T3 (es) | 1993-09-10 | 1994-09-01 | Proceso y catalizador para la produccion de acido acetico. |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US5672743A (es) |
| EP (1) | EP0643034B1 (es) |
| JP (2) | JP4195103B2 (es) |
| KR (1) | KR100337066B1 (es) |
| CN (2) | CN1041915C (es) |
| BR (1) | BR9403499A (es) |
| CA (1) | CA2117569C (es) |
| DE (1) | DE69410557T2 (es) |
| ES (1) | ES2116539T3 (es) |
| FI (1) | FI944164A7 (es) |
| IN (1) | IN187227B (es) |
| MY (1) | MY121194A (es) |
| NO (1) | NO301708B1 (es) |
| NZ (1) | NZ264419A (es) |
| RU (1) | RU2132840C1 (es) |
| SG (1) | SG43676A1 (es) |
| TW (1) | TW252105B (es) |
| UA (1) | UA26345C2 (es) |
| YU (1) | YU49260B (es) |
Families Citing this family (116)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5672743A (en) * | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
| US5510524A (en) * | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
| GB9503385D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
| GB9503382D0 (en) * | 1995-02-21 | 1995-04-12 | Bp Chem Int Ltd | Process |
| GB9504708D0 (en) * | 1995-03-08 | 1995-04-26 | Bp Chem Int Ltd | Process |
| GB9512427D0 (en) * | 1995-06-19 | 1995-08-23 | Bp Chem Int Ltd | Process |
| US5696284A (en) * | 1995-06-21 | 1997-12-09 | Bp Chemicals Limited | Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof |
| RU2173314C2 (ru) * | 1995-08-22 | 2001-09-10 | Бп Кемикэлз Лимитед | Способ карбонилирования спирта и/или его реакционноспособного производного |
| GB9521501D0 (en) * | 1995-10-20 | 1995-12-20 | Bp Chem Int Ltd | Process |
| US6156692A (en) * | 1996-04-30 | 2000-12-05 | Bp Amoco Corporation | Ruthenium-containing catalyst composition for olefin metathesis |
| US5831120A (en) * | 1996-11-19 | 1998-11-03 | Watson; Derrick John | Process for the production of acetic acid |
| GB9625335D0 (en) * | 1996-12-05 | 1997-01-22 | Bp Chem Int Ltd | Process |
| GB9626324D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9626429D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9626317D0 (en) * | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| GB9825424D0 (en) * | 1998-11-19 | 1999-01-13 | Bp Chem Int Ltd | Process |
| US6274096B1 (en) | 1999-11-01 | 2001-08-14 | Acetex (Cyprus) Limited | Methanol plant retrofit |
| US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
| GB9926855D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
| GB9926854D0 (en) * | 1999-11-12 | 2000-01-12 | Bp Chem Int Ltd | Process |
| US6458995B1 (en) | 2000-03-31 | 2002-10-01 | Celanese International Corporation | Catalytic composition for carbonylation including iridium and pyridine polymers |
| US6235673B1 (en) * | 2000-04-05 | 2001-05-22 | Eastman Chemical Company | Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer |
| US6627770B1 (en) | 2000-08-24 | 2003-09-30 | Celanese International Corporation | Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process |
| US6531630B2 (en) | 2000-12-29 | 2003-03-11 | Kenneth Ebenes Vidalin | Bimodal acetic acid manufacture |
| US6599348B2 (en) | 2001-06-01 | 2003-07-29 | Celanese International Corporation | Methods for reducing entrainment of solids and liquids |
| GB0211560D0 (en) * | 2002-05-20 | 2002-06-26 | Bp Chem Int Ltd | Process |
| GB0212974D0 (en) * | 2002-06-06 | 2002-07-17 | Bp Chem Int Ltd | Process |
| GB0221800D0 (en) | 2002-09-19 | 2002-10-30 | Bp Chem Int Ltd | Process |
| GB0316756D0 (en) | 2003-07-17 | 2003-08-20 | Bp Chem Int Ltd | Process |
| US6846951B1 (en) | 2003-10-09 | 2005-01-25 | Acetex (Cyprus) Limited | Integrated process for acetic acid and methanol |
| US7208624B2 (en) * | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
| US7223886B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
| MY146697A (en) | 2004-07-09 | 2012-09-14 | Acetex Cyprus Ltd | Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock |
| US7053241B1 (en) | 2005-02-24 | 2006-05-30 | Celanese International Corporation | Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer |
| CN1978055B (zh) * | 2005-12-08 | 2010-05-05 | 中国科学院化学研究所 | 一种羰基合成催化体系及应用 |
| GB0601861D0 (en) | 2006-01-30 | 2006-03-08 | Bp Chem Int Ltd | Process |
| TWI465424B (zh) | 2006-03-21 | 2014-12-21 | Bp Chem Int Ltd | 製造醋酸的方法 |
| US7902398B2 (en) | 2007-04-25 | 2011-03-08 | Celanese International Corporation | Method and apparatus for carbonylation with reduced catalyst loss |
| US7989659B2 (en) | 2007-05-17 | 2011-08-02 | Celanese International Corporation | Method and apparatus for making acetic acid with improved light ends column productivity |
| US7902397B2 (en) * | 2007-10-11 | 2011-03-08 | Celanese International Corporation | Method and apparatus for making acetic acid with improved productivity |
| US8062482B2 (en) * | 2007-10-30 | 2011-11-22 | Celanese International Corporation | Acetaldehyde removal from methyl acetate by distillation at elevated pressure |
| EP2093209A1 (en) | 2008-02-19 | 2009-08-26 | BP Chemicals Limited | Process for the production of acetic acid |
| BRPI0910840B1 (pt) | 2008-04-29 | 2018-05-08 | Celanese International Corporation | aparelho para produção de ácido acético, método de operação de uma torre absorvedora em uma unidade de carbonilação e método aperfeiçoado para operação de um aparelho para fabricação de ácido acético |
| US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| US7790920B2 (en) * | 2008-09-11 | 2010-09-07 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| US7884237B2 (en) * | 2008-11-07 | 2011-02-08 | Celanese International Corp. | Methanol carbonylation with improved aldehyde removal |
| EP2186787A1 (en) | 2008-11-13 | 2010-05-19 | BP p.l.c. | Hydrogenation of ethanoic acid to produce ethanol |
| US8076508B2 (en) * | 2008-12-08 | 2011-12-13 | Lyondell Chemical Technology | Preparation of acetic acid |
| US8168822B2 (en) | 2009-07-07 | 2012-05-01 | Celanese International Corporation | Acetic acid production by way of carbonylation with enhanced reaction and flashing |
| US8455685B2 (en) * | 2009-07-07 | 2013-06-04 | Celanese International Corporation | Acetic anhydride production by way of carbonylation with enhanced reaction and flashing |
| CN101722047B (zh) * | 2009-11-27 | 2013-07-10 | 中国科学院化学研究所 | 甲醇羰基合成醋酸的均相铱配合物催化剂及其制备方法和应用 |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
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| US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
| US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| US8859827B2 (en) | 2011-11-18 | 2014-10-14 | Celanese International Corporation | Esterifying acetic acid to produce ester feed for hydrogenolysis |
| US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
| US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| WO2012148509A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
| US8378141B2 (en) | 2010-08-16 | 2013-02-19 | Celanese International Corporation | Process and system for supplying vapor from drying column to light ends column |
| US8530696B2 (en) | 2010-09-24 | 2013-09-10 | Celanese International Corporation | Pump around reactor for production of acetic acid |
| US8394988B2 (en) | 2010-09-28 | 2013-03-12 | Celanese International Corporation | Production of acetic acid with high conversion rate |
| US8877963B2 (en) | 2010-09-28 | 2014-11-04 | Celanese International Corporation | Production of acetic acid with high conversion rate |
| US8461379B2 (en) | 2010-10-12 | 2013-06-11 | Celanese International Corporation | Production of acetic acid comprising feeding at least one reactant to a recycle stream |
| EP2627624B1 (en) | 2010-10-13 | 2019-02-13 | Celanese International Corporation | Process for recovering halogen promoters and removing permanganate reducing compounds |
| US8637698B2 (en) | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
| US8563773B2 (en) | 2010-12-16 | 2013-10-22 | Celanese International Corporation | Eductor-based reactor and pump around loops for production of acetic acid |
| RU2013135468A (ru) | 2010-12-30 | 2015-02-10 | Селаниз Интернэшнл Корпорейшн | Очистка потоков продукта уксусной кислоты |
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| TW201302684A (zh) | 2011-04-26 | 2013-01-16 | Celanese Int Corp | 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程 |
| US8884081B2 (en) | 2011-04-26 | 2014-11-11 | Celanese International Corporation | Integrated process for producing acetic acid and alcohol |
| US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
| US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
| US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
| SG194198A1 (en) | 2011-05-05 | 2013-12-30 | Celanese Int Corp | Removal of aromatics from carbonylation process |
| US8697908B2 (en) | 2011-05-05 | 2014-04-15 | Celanese International Corporation | Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants |
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| CN103086868B (zh) * | 2011-11-02 | 2015-06-17 | 中国石油化工股份有限公司 | 一种羰基化反应制备乙酸的方法 |
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| WO2013070210A1 (en) | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Integrated carbonylation and hydrogenation process to obtain ethanol having flashing to recover acid production catalyst |
| US8686201B2 (en) | 2011-11-09 | 2014-04-01 | Celanese International Corporation | Integrated acid and alcohol production process having flashing to recover acid production catalyst |
| US8614359B2 (en) | 2011-11-09 | 2013-12-24 | Celanese International Corporation | Integrated acid and alcohol production process |
| US8748673B2 (en) | 2011-11-18 | 2014-06-10 | Celanese International Corporation | Process of recovery of ethanol from hydrogenolysis process |
| CN104024192A (zh) | 2011-11-22 | 2014-09-03 | 国际人造丝公司 | 将乙酸加氢生产乙酸乙酯和将乙酸乙酯还原为乙醇 |
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| US9029614B2 (en) | 2011-12-14 | 2015-05-12 | Celanese International Corporation | Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol |
| US9421522B2 (en) | 2011-12-28 | 2016-08-23 | Eastman Chemical Company | Iridium catalysts for carbonylation |
| US20130172633A1 (en) | 2011-12-29 | 2013-07-04 | Celanese International Corporation | Process For Producing Ethanol From Impure Methanol |
| WO2013119275A1 (en) | 2012-02-08 | 2013-08-15 | Celanese International Corporation | Production of acetic acid from methanol |
| US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
| US8729311B2 (en) | 2012-02-10 | 2014-05-20 | Celanese International Corporaton | Catalysts for converting acetic acid to acetone |
| US8729317B2 (en) | 2012-02-15 | 2014-05-20 | Celanese International Corporation | Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof |
| US8802903B2 (en) | 2012-03-13 | 2014-08-12 | Celanese International Corporation | Stacked bed reactor with diluents for producing ethanol |
| US8859810B2 (en) | 2012-08-21 | 2014-10-14 | Celanese International Corporation | Process for recovering permanganate reducing compounds from an acetic acid production process |
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| KR101667222B1 (ko) | 2014-12-29 | 2016-10-18 | 한국화학연구원 | 카보닐화 반응에 의한 초산 제조용 Rh-C3N4 불균일 촉매 |
| KR101667223B1 (ko) | 2014-12-29 | 2016-10-18 | 한국화학연구원 | 카보닐화 반응에 의한 초산 제조용 Rh/WxC 불균일 촉매 |
| US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
| US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
| US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| MY181882A (en) | 2015-10-02 | 2021-01-12 | Celanese Int Corp | Process to produce acetic acid with recycle of water |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| JP2023528451A (ja) | 2020-06-03 | 2023-07-04 | セラニーズ・インターナショナル・コーポレーション | 酢酸の製造及び精製 |
| CN116803525B (zh) * | 2022-03-16 | 2025-07-04 | 中国石油化工股份有限公司 | 一种用于制备醋酸的复合催化剂及其制备醋酸的方法 |
| FI20246015A1 (en) * | 2024-08-14 | 2025-05-20 | Neste Oyj | Process for manufacturing a jet fuel component |
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-
1994
- 1994-08-01 US US08/284,078 patent/US5672743A/en not_active Expired - Lifetime
- 1994-08-03 IN IN987DE1994 patent/IN187227B/en unknown
- 1994-08-20 TW TW083107641A patent/TW252105B/zh not_active IP Right Cessation
- 1994-08-24 CA CA002117569A patent/CA2117569C/en not_active Expired - Lifetime
- 1994-09-01 DE DE69410557T patent/DE69410557T2/de not_active Expired - Lifetime
- 1994-09-01 SG SG1995001784A patent/SG43676A1/en unknown
- 1994-09-01 ES ES94306506T patent/ES2116539T3/es not_active Expired - Lifetime
- 1994-09-01 EP EP94306506A patent/EP0643034B1/en not_active Expired - Lifetime
- 1994-09-07 YU YU53394A patent/YU49260B/sh unknown
- 1994-09-08 NO NO943318A patent/NO301708B1/no not_active IP Right Cessation
- 1994-09-08 NZ NZ264419A patent/NZ264419A/en unknown
- 1994-09-09 BR BR9403499A patent/BR9403499A/pt not_active IP Right Cessation
- 1994-09-09 FI FI944164A patent/FI944164A7/fi unknown
- 1994-09-09 MY MYPI94002387A patent/MY121194A/en unknown
- 1994-09-09 UA UA94095799A patent/UA26345C2/uk unknown
- 1994-09-09 JP JP21622994A patent/JP4195103B2/ja not_active Expired - Lifetime
- 1994-09-09 RU RU94033107A patent/RU2132840C1/ru active
- 1994-09-10 CN CN94115261A patent/CN1041915C/zh not_active Expired - Lifetime
- 1994-09-10 KR KR1019940022862A patent/KR100337066B1/ko not_active Expired - Lifetime
-
1997
- 1997-06-12 US US08/873,761 patent/US5942460A/en not_active Expired - Lifetime
-
1998
- 1998-06-25 CN CN98115522A patent/CN1092541C/zh not_active Expired - Lifetime
-
2008
- 2008-01-25 JP JP2008015687A patent/JP2008110990A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MY121194A (en) | 2006-01-28 |
| CN1107460A (zh) | 1995-08-30 |
| TW252105B (es) | 1995-07-21 |
| NO943318D0 (no) | 1994-09-08 |
| SG43676A1 (en) | 1997-11-14 |
| YU49260B (sh) | 2004-12-31 |
| US5942460A (en) | 1999-08-24 |
| RU94033107A (ru) | 1996-07-20 |
| FI944164L (fi) | 1995-03-11 |
| KR100337066B1 (ko) | 2002-11-30 |
| BR9403499A (pt) | 1995-05-16 |
| YU53394A (sh) | 1996-10-18 |
| JP2008110990A (ja) | 2008-05-15 |
| CA2117569C (en) | 2003-12-30 |
| DE69410557D1 (de) | 1998-07-02 |
| NO943318L (no) | 1995-03-13 |
| CN1092541C (zh) | 2002-10-16 |
| CN1041915C (zh) | 1999-02-03 |
| CN1210760A (zh) | 1999-03-17 |
| FI944164A7 (fi) | 1995-03-11 |
| KR950008463A (ko) | 1995-04-17 |
| NZ264419A (en) | 1995-03-28 |
| NO301708B1 (no) | 1997-12-01 |
| FI944164A0 (fi) | 1994-09-09 |
| JPH07165664A (ja) | 1995-06-27 |
| CA2117569A1 (en) | 1995-03-11 |
| JP4195103B2 (ja) | 2008-12-10 |
| IN187227B (es) | 2002-03-02 |
| RU2132840C1 (ru) | 1999-07-10 |
| DE69410557T2 (de) | 1998-09-17 |
| EP0643034B1 (en) | 1998-05-27 |
| EP0643034A1 (en) | 1995-03-15 |
| US5672743A (en) | 1997-09-30 |
| UA26345C2 (uk) | 1999-08-30 |
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