BRPI0413252A - partìculas de sìlica amorfa tendo capacidades de absorção elevadas e caracterìsticas estruturais superiores - Google Patents
partìculas de sìlica amorfa tendo capacidades de absorção elevadas e caracterìsticas estruturais superioresInfo
- Publication number
- BRPI0413252A BRPI0413252A BRPI0413252-1A BRPI0413252A BRPI0413252A BR PI0413252 A BRPI0413252 A BR PI0413252A BR PI0413252 A BRPI0413252 A BR PI0413252A BR PI0413252 A BRPI0413252 A BR PI0413252A
- Authority
- BR
- Brazil
- Prior art keywords
- structural characteristics
- high absorption
- pore
- silica particles
- amorphous particles
- Prior art date
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 5
- 239000002245 particle Substances 0.000 title abstract 4
- 238000010521 absorption reaction Methods 0.000 title 1
- 239000000377 silicon dioxide Substances 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/126—Preparation of silica of undetermined type
- C01B33/128—Preparation of silica of undetermined type by acidic treatment of aqueous silicate solutions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/02—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/141—Intimate drug-carrier mixtures characterised by the carrier, e.g. ordered mixtures, adsorbates, solid solutions, eutectica, co-dried, co-solubilised, co-kneaded, co-milled, co-ground products, co-precipitates, co-evaporates, co-extrudates, co-melts; Drug nanoparticles with adsorbed surface modifiers
- A61K9/143—Intimate drug-carrier mixtures characterised by the carrier, e.g. ordered mixtures, adsorbates, solid solutions, eutectica, co-dried, co-solubilised, co-kneaded, co-milled, co-ground products, co-precipitates, co-evaporates, co-extrudates, co-melts; Drug nanoparticles with adsorbed surface modifiers with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
- C01P2006/17—Pore diameter distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Silicon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
Abstract
"PARTìCULAS DE SìLICA AMORFA TENDO CAPACIDADES DE ABSORçãO ELEVADAS E CARACTERìSTICAS ESTRUTURAIS SUPERIORES". A presente invenção proporciona partículas de sílica amorfa tendo elevadas capacidades de absorção e elevadas características estruturais, em que a capacidade de absorção de óleo é duramente diminuída, mesmo quando uma elevada carga é aplicada às partículas de sílica amorfa. Em particular, partículas de sílica amorfa são proporcionadas, em que o valor máximo de <30>Vp/<30>Rp (onde Vp é o volume de poro ¢mm¬ 3¬/g! e Rp é o radio de poro ¢nm!) é de 20 mm¬ 3¬/nm.g¬ -1¬ ou mais na curva de distribuição de poro obtida por um método de isoterma de adsorção de benzeno e o raio de pico de poro quando o <30>Vp/<30>Rp é no máximo de 20 nm ou mais a 100 nm ou menos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003285163A JP2005053728A (ja) | 2003-08-01 | 2003-08-01 | 高吸油性および高い構造性を有する非晶質シリカ粒子 |
| PCT/IB2004/002431 WO2005012175A1 (en) | 2003-08-01 | 2004-07-29 | Amorphous silica particles having high absorbing capabilities and high structural characteristics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0413252A true BRPI0413252A (pt) | 2006-10-03 |
Family
ID=34113867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0413252-1A BRPI0413252A (pt) | 2003-08-01 | 2004-07-29 | partìculas de sìlica amorfa tendo capacidades de absorção elevadas e caracterìsticas estruturais superiores |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20080153694A1 (pt) |
| EP (1) | EP1648824B1 (pt) |
| JP (2) | JP2005053728A (pt) |
| KR (1) | KR20060121809A (pt) |
| CN (2) | CN101863481A (pt) |
| AT (1) | ATE380779T1 (pt) |
| BR (1) | BRPI0413252A (pt) |
| DE (1) | DE602004010671T2 (pt) |
| ES (1) | ES2298776T3 (pt) |
| RU (1) | RU2006106052A (pt) |
| WO (1) | WO2005012175A1 (pt) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005053744A (ja) * | 2003-08-05 | 2005-03-03 | Dsl Japan Co Ltd | 高吸油性非晶質シリカ粒子 |
| JP4752442B2 (ja) * | 2005-10-17 | 2011-08-17 | 王子製紙株式会社 | 製紙用水和珪酸およびその製造方法 |
| KR100828575B1 (ko) * | 2007-01-22 | 2008-05-13 | 인하대학교 산학협력단 | 짧은 수직 채널의 메조 세공을 갖는 소평판형 실리카 |
| JP5288433B2 (ja) * | 2007-03-26 | 2013-09-11 | ソマール株式会社 | 遮光フィルム |
| EP2156487A4 (en) * | 2007-06-01 | 2016-11-16 | Daramic Llc | BLEIBATTERIETRENGLIED MEMBER WITH IMPROVED STIFFNESS |
| WO2009003142A1 (en) | 2007-06-27 | 2008-12-31 | The Board Of Trustees Of The Leland, Stanford Junior University | Beta2-microglobulin and c reactive protein (crp) as biomarkers for peripheral artery disease |
| DE102008000290A1 (de) | 2008-02-13 | 2009-08-20 | Evonik Degussa Gmbh | Lagerstabile Produktsyteme für Prämixformulierungen |
| DE102008035867A1 (de) | 2008-08-01 | 2010-02-04 | Evonik Degussa Gmbh | Neuartige Fällungskieselsäuren für Trägeranwendungen |
| AT507280B1 (de) * | 2008-08-27 | 2011-04-15 | Blum Gmbh Julius | Möbelbeschlag mit einem dämpfer |
| EP2411329B1 (en) * | 2009-03-11 | 2021-05-19 | Imerys Filtration Minerals, Inc. | Natural amorphous silica filler products |
| DE102009028255A1 (de) | 2009-08-05 | 2011-02-10 | Evonik Degussa Gmbh | Mikrostrukturierte multifunktionale anorganische Coating-Additive zur Vermeidung von Fouling (Biofilmbewuchs) bei aquatischen Anwendungen |
| DE102009036767A1 (de) | 2009-08-08 | 2011-02-10 | Evonik Degussa Gmbh | Kompositpartikel für den Einsatz in der Mundhygiene |
| CN102666868A (zh) * | 2009-10-21 | 2012-09-12 | 诺维信公司 | 油处理方法 |
| MX346364B (es) * | 2010-05-21 | 2017-03-16 | Grace Gmbh & Co Kg * | Particulas porosas de oxido inorganico y metodos para preparar y utilizar los mismos. |
| US20130277916A1 (en) * | 2010-11-26 | 2013-10-24 | Uchiyama Manufacturing Corp. | Seal Member Having Excellent Wear Resistance, and Seal Structure Using Same |
| US9480913B2 (en) | 2011-01-26 | 2016-11-01 | WhitewaterWest Industries Ltd. | Interactive entertainment using a mobile device with object tagging and/or hyperlinking |
| US20130064757A1 (en) * | 2011-09-09 | 2013-03-14 | Uop Llc | Methods for forming zeolites from homogeneous amorphous silica alumina |
| FR2984134B1 (fr) * | 2011-12-16 | 2014-05-16 | Oreal | Composition cosmetique comprenant un polymere superabsorbant et une charge minerale, lamellaire ou plaquettaire, matifiante |
| DE102012210294A1 (de) | 2012-06-19 | 2013-12-19 | Evonik Industries Ag | Bewuchsmindernde-Additive, Verfahren zu deren Herstellung und deren Verwendung in Beschichtungen |
| CN102766358B (zh) * | 2012-07-02 | 2014-02-26 | 广东新会美达锦纶股份有限公司 | 一种锦纶化纤用消光剂的表面处理方法 |
| CN102980850B (zh) * | 2012-11-02 | 2015-01-28 | 成都新柯力化工科技有限公司 | 一种复合钛白粉基本指标的快速测定方法 |
| JP6026866B2 (ja) * | 2012-11-26 | 2016-11-16 | 興亜硝子株式会社 | 漆模様ガラス容器および漆模様ガラス容器の製造方法 |
| PL2950923T3 (pl) * | 2013-02-01 | 2022-04-04 | W.R. Grace & Co. - Conn. | Porowaty żel krzemionkowy jako nośnik płynnych technologii |
| JP2015078141A (ja) * | 2013-10-15 | 2015-04-23 | 株式会社ニックス | 徐放性樹脂組成物 |
| CN103911022B (zh) * | 2014-04-10 | 2016-01-20 | 福建省馨和纳米硅业有限公司 | 一种粒径可控的纳米二氧化硅及其制备方法 |
| CN105440770B (zh) * | 2014-06-30 | 2021-05-04 | 四川茵地乐材料科技集团有限公司 | 用于改性锂离子电池用隔膜的水性组合物及改性隔膜和电池 |
| DE102014113411A1 (de) * | 2014-09-17 | 2016-03-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Anorganische, Silica-basierte Feststoff-Schaumpartikel mit geschlossenen Innenporen, ihre Herstellung und ihre Verwendung als Füll- oder Speicherstoff |
| JP6487785B2 (ja) * | 2015-06-12 | 2019-03-20 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸 |
| WO2017159161A1 (ja) * | 2016-03-14 | 2017-09-21 | 株式会社Adeka | 難燃性熱可塑性ポリウレタン樹脂組成物 |
| JP7248425B2 (ja) * | 2016-03-31 | 2023-03-29 | エンテックアジア株式会社 | 液式鉛蓄電池用セパレータ |
| EP3528957B1 (en) * | 2016-10-20 | 2025-12-03 | Mycelx Technologies Corporation | Removing oil and/or particulate contaminants from contaminated water |
| CN110678206B (zh) * | 2017-05-19 | 2023-03-21 | 株式会社德山 | 医药原料药载体及其制造方法 |
| WO2019042887A1 (en) * | 2017-08-28 | 2019-03-07 | Evonik Degussa Gmbh | SPHERICAL SILICA FOR OCCLUSION OF TUBULES |
| CN108393062B (zh) * | 2018-03-20 | 2019-12-27 | 中国矿业大学 | 一种脱除水中亚甲基蓝的吸附剂及其制备方法和应用 |
| CN110104655B (zh) * | 2019-05-15 | 2021-03-16 | 福建省馨和纳米硅业有限公司 | 一种高性能二氧化硅的制备工艺 |
| CN116419795A (zh) * | 2020-11-16 | 2023-07-11 | Agc株式会社 | 吸附材料 |
| CN113274987A (zh) * | 2021-05-18 | 2021-08-20 | 贵州金之键高科技材料有限公司 | 功能性配位材料及其在天然提取物中的应用 |
| CN113353941B (zh) * | 2021-07-26 | 2022-02-22 | 广州市飞雪材料科技有限公司 | 一种医用二氧化硅吸附剂及其制备方法 |
| CN114132938B (zh) * | 2021-12-08 | 2022-05-24 | 金三江(肇庆)硅材料股份有限公司 | 一种高吸油值低比表面积二氧化硅及其制备方法 |
| US20230356181A1 (en) * | 2022-05-04 | 2023-11-09 | Basf Corporation | Adsorbent for hydrocarbon recovery with improved mechanical properties |
| CN119015956A (zh) * | 2024-10-29 | 2024-11-26 | 任丘市鸿运石油化工有限公司 | 一种钻井液润滑剂生产设备 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE420596B (sv) * | 1975-03-25 | 1981-10-19 | Osaka Packing | Formad kropp av amorf kiseldioxid, eventuellt innehallande kalciumkarbonat, sett att framstella en formad kropp av amorf kiseldioxid samt partikel av amorf kiseldioxid for framstellning av en formad kropp |
| FR2567505B1 (fr) * | 1984-07-11 | 1986-11-21 | Rhone Poulenc Chim Base | Silice a prise d'huile elevee et a structure primaire controlee et procede pour son obtention |
| ES2158318T3 (es) * | 1995-06-30 | 2001-09-01 | Ineos Silicas Ltd | Silices amorfas y composiciones orales. |
| JP3107735B2 (ja) * | 1995-09-29 | 2000-11-13 | 株式会社トクヤマ | インクジェット記録用紙 |
| US5605569A (en) * | 1995-11-08 | 1997-02-25 | Ppg Industries, Inc. | Precipitated silica having high sodium sulfate content |
| EP0902758B1 (en) * | 1996-05-31 | 2001-06-06 | PPG Industries Ohio, Inc. | Amorphous precipitated silica |
| DE69714727T2 (de) * | 1996-05-31 | 2003-04-03 | Ppg Industries Ohio, Inc. | Amorphe fällungskieselsäure |
| CA2265234A1 (en) * | 1998-03-12 | 1999-09-12 | Oji Paper Co., Ltd. | Process for producing silica particles suitable for use as filler for paper |
| DE19943103A1 (de) * | 1999-09-09 | 2001-03-15 | Wacker Chemie Gmbh | Hochgefüllte SiO2-Dispersion, Verfahren zu ihrer Herstellung und Verwendung |
| WO2001038223A1 (en) * | 1999-11-23 | 2001-05-31 | Universite Laval | Mesoporous zeolitic material with microporous crystalline mesopore walls |
| US6838068B2 (en) * | 2000-06-30 | 2005-01-04 | Mitsubishi Chemical Corporation | Silica gel |
| DE10058616A1 (de) * | 2000-11-25 | 2002-05-29 | Degussa | Fällungskieselsäuren mit hoher Struktur |
| JP2002226302A (ja) * | 2000-11-29 | 2002-08-14 | Shionogi & Co Ltd | 農薬製剤用シリカ担体及び農薬製剤 |
| JP4764558B2 (ja) * | 2001-03-21 | 2011-09-07 | 水澤化学工業株式会社 | 吸油量の増大した非晶質シリカ粒子、その製法及び用途 |
| GB0130907D0 (en) * | 2001-12-22 | 2002-02-13 | Ineos Silicas Ltd | Amorphous silica |
| JP2003192992A (ja) * | 2001-12-26 | 2003-07-09 | Kotobuki Kako Kk | 塗料用艶消し剤、およびエネルギー線硬化型塗料用組成物 |
-
2003
- 2003-08-01 JP JP2003285163A patent/JP2005053728A/ja active Pending
-
2004
- 2004-07-29 KR KR1020067002260A patent/KR20060121809A/ko not_active Ceased
- 2004-07-29 RU RU2006106052/15A patent/RU2006106052A/ru unknown
- 2004-07-29 DE DE602004010671T patent/DE602004010671T2/de not_active Expired - Lifetime
- 2004-07-29 WO PCT/IB2004/002431 patent/WO2005012175A1/en not_active Ceased
- 2004-07-29 JP JP2006522425A patent/JP4588705B2/ja not_active Expired - Fee Related
- 2004-07-29 ES ES04744085T patent/ES2298776T3/es not_active Expired - Lifetime
- 2004-07-29 EP EP04744085A patent/EP1648824B1/en not_active Expired - Lifetime
- 2004-07-29 CN CN201010136275A patent/CN101863481A/zh active Pending
- 2004-07-29 CN CNA2004800219600A patent/CN1829659A/zh active Pending
- 2004-07-29 BR BRPI0413252-1A patent/BRPI0413252A/pt not_active IP Right Cessation
- 2004-07-29 AT AT04744085T patent/ATE380779T1/de not_active IP Right Cessation
- 2004-07-29 US US10/566,373 patent/US20080153694A1/en not_active Abandoned
-
2010
- 2010-03-22 US US12/728,307 patent/US20100331177A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN1829659A (zh) | 2006-09-06 |
| ES2298776T3 (es) | 2008-05-16 |
| KR20060121809A (ko) | 2006-11-29 |
| CN101863481A (zh) | 2010-10-20 |
| WO2005012175A1 (en) | 2005-02-10 |
| DE602004010671T2 (de) | 2009-07-09 |
| JP4588705B2 (ja) | 2010-12-01 |
| DE602004010671D1 (de) | 2008-01-24 |
| JP2007501179A (ja) | 2007-01-25 |
| ATE380779T1 (de) | 2007-12-15 |
| RU2006106052A (ru) | 2007-09-10 |
| EP1648824B1 (en) | 2007-12-12 |
| EP1648824A1 (en) | 2006-04-26 |
| US20100331177A1 (en) | 2010-12-30 |
| JP2005053728A (ja) | 2005-03-03 |
| US20080153694A1 (en) | 2008-06-26 |
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