BRPI0416091A - processo homogêneo para a hidrogenação de ácidos dicarboxìlicos e/ou de anidridos dos mesmos - Google Patents

processo homogêneo para a hidrogenação de ácidos dicarboxìlicos e/ou de anidridos dos mesmos

Info

Publication number
BRPI0416091A
BRPI0416091A BRPI0416091-6A BRPI0416091A BRPI0416091A BR PI0416091 A BRPI0416091 A BR PI0416091A BR PI0416091 A BRPI0416091 A BR PI0416091A BR PI0416091 A BRPI0416091 A BR PI0416091A
Authority
BR
Brazil
Prior art keywords
hydrogenation
anhydrides
dicarboxylic acids
homogeneous process
approximately
Prior art date
Application number
BRPI0416091-6A
Other languages
English (en)
Inventor
Michael Anthony Wood
Simon Peter Crabtree
Derek Vincent Tyers
Original Assignee
Davy Process Techn Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Davy Process Techn Ltd filed Critical Davy Process Techn Ltd
Publication of BRPI0416091A publication Critical patent/BRPI0416091A/pt
Publication of BRPI0416091B1 publication Critical patent/BRPI0416091B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D307/08—Preparation of tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

"PROCESSO HOMOGêNEO PARA A HIDROGENAçãO DE áCIDOS DICARBOXìLICOS E/OU DE ANIDRIDOS DOS MESMOS". Um processo homogêneo para a hidrogenação de ácidos dicarboxílicos e/ou de anidridos na presença de um catalisador compreendendo: (a) rutênio, ródio, ferro, ósmio ou paládio; e (b) uma fosfina orgânica; em que a hidrogenação é realizada na presença ao menos de aproximadamente 1% por peso de água e em que a reação é realizada em uma pressão de aproximadamente 500 psig a aproximadamente 2000 psig e a uma temperatura de aproximadamente 200<198>C a aproximadamente a 300<198>C tais que de aproximadamente 1 mol a aproximadamente 10 mol do hidrogênio são usados tirar 1 mol de produto do reator.
BRPI0416091-6A 2003-10-31 2004-10-15 Processo homogêneo para a hidrogenação de ácidos dicarboxílicos e/ou de anidridos dos mesmos BRPI0416091B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0325526.2 2003-10-31
GBGB0325526.2A GB0325526D0 (en) 2003-10-31 2003-10-31 Process
PCT/GB2004/004397 WO2005051875A1 (en) 2003-10-31 2004-10-15 Homogeneous process for the hydrogenation of dicarboxylic acids and/or anhydrides thereof

Publications (2)

Publication Number Publication Date
BRPI0416091A true BRPI0416091A (pt) 2007-01-02
BRPI0416091B1 BRPI0416091B1 (pt) 2014-08-19

Family

ID=29725777

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0416091-6A BRPI0416091B1 (pt) 2003-10-31 2004-10-15 Processo homogêneo para a hidrogenação de ácidos dicarboxílicos e/ou de anidridos dos mesmos

Country Status (19)

Country Link
US (1) US7498450B2 (pt)
EP (1) EP1678108B1 (pt)
JP (1) JP4648327B2 (pt)
KR (1) KR101127083B1 (pt)
CN (1) CN100467433C (pt)
AR (1) AR046822A1 (pt)
AU (1) AU2004293238B2 (pt)
BR (1) BRPI0416091B1 (pt)
CA (1) CA2543854C (pt)
EA (1) EA010436B1 (pt)
ES (1) ES2429063T3 (pt)
GB (1) GB0325526D0 (pt)
MY (1) MY140106A (pt)
NO (1) NO20062499L (pt)
PL (1) PL1678108T3 (pt)
SG (1) SG147484A1 (pt)
TW (1) TWI351314B (pt)
WO (1) WO2005051875A1 (pt)
ZA (1) ZA200604399B (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0421928D0 (en) 2004-10-01 2004-11-03 Davy Process Techn Ltd Process
TW200837045A (en) * 2006-09-22 2008-09-16 Lucite Int Uk Ltd Production of amines
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
TWI421240B (zh) * 2011-12-12 2014-01-01 Ind Tech Res Inst 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法
DE102012006946A1 (de) 2012-04-10 2013-10-10 Stratley Ag Verfahren zur Herstellung von Caprolactam
US9512054B2 (en) 2015-02-10 2016-12-06 Eastman Chemical Company Method for making a high purity alcohol
CN107282044B (zh) * 2016-04-12 2020-02-04 中国石油化工股份有限公司 1,4-环己烷二甲酸合成用催化剂
CN117658792A (zh) * 2022-08-30 2024-03-08 中国石油化工股份有限公司 一种间歇式顺酐水相加氢制备丁二酸的工艺方法
CN117658791A (zh) * 2022-08-30 2024-03-08 中国石油化工股份有限公司 一种连续式顺酐水相加氢制备丁二酸的工艺方法

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1939882A1 (de) 1968-08-10 1970-02-19 Mitsubishi Chem Ind Verfahren zur Herstellung von Ta?rahydrofuran
US3957827A (en) 1974-10-17 1976-05-18 Sun Ventures, Inc. Hydrogenation of carboxylic acid anhydrides to lactones or esters by homogeneous catalysis
JPS5511555A (en) * 1978-07-13 1980-01-26 Mitsubishi Chem Ind Ltd Isomerization of diacetoxybutene
US4377715A (en) 1979-12-26 1983-03-22 Allied Corporation Production of perfluoropropane
US4301077A (en) * 1980-12-22 1981-11-17 Standard Oil Company Process for the manufacture of 1-4-butanediol and tetrahydrofuran
US4485245A (en) 1982-10-29 1984-11-27 Sun Tech, Inc. Hydrogenation of carboxylic acid anhydrides to lactones or esters using a ruthenium trichlorostannate catalyst
US4480115A (en) 1983-03-17 1984-10-30 Celanese Corporation Direct hydrogenation of carboxylic acids to alcohol and esters
US4892955A (en) 1986-08-19 1990-01-09 Mitsubishi Chemical Industries Limited Method for producing a lactone
JPH07121925B2 (ja) 1987-04-18 1995-12-25 三菱化学株式会社 ラクトン類の製造法
EP0304696B1 (de) 1987-08-08 1992-04-29 BASF Aktiengesellschaft Verfahren zur Herstellung von 1,4-Butandiol und/oder Tetrahydrofuran
US4810807A (en) 1987-10-13 1989-03-07 The Standard Oil Company Hydrogenation of maleic anhydride to tetrahydrofuran
US4827001A (en) 1987-11-02 1989-05-02 The Standard Oil Company Preparation of γ-butyrolactone and 1,4-butanediol by catalytic hydrogenation of maleic acid
US5072009A (en) 1987-12-23 1991-12-10 The Standard Oil Company Vapor-phase hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone
US4965378A (en) 1987-12-23 1990-10-23 The Standard Oil Company Vapor-phase hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone
JPH075489B2 (ja) * 1988-05-17 1995-01-25 三菱化学株式会社 ジオール及び/又は環状エーテルの製造法
EP0358607A3 (de) 1988-09-09 1990-10-31 Gesellschaft für Biotechnologische Forschung mbH (GBF) Mikrobizide makrozyklische Laktonderivate
JPH089607B2 (ja) 1988-10-31 1996-01-31 三菱化学株式会社 フタライド類の製造法
JP2666151B2 (ja) 1988-12-14 1997-10-22 東燃株式会社 1,4−ブタンジオールの製造法
JP2611831B2 (ja) * 1989-01-31 1997-05-21 三菱化学株式会社 1,4―ブタンジオール及び/又はテトラヒドロフランの製造法
JPH02200680A (ja) 1989-01-31 1990-08-08 Mitsubishi Kasei Corp γ―ブチロラクトンの製造法
JP2516805B2 (ja) 1989-02-06 1996-07-24 三菱化学株式会社 ラクトン類の製造方法
JPH02233674A (ja) 1989-03-07 1990-09-17 Mitsubishi Kasei Corp ラクトン類の製造法
JP2516809B2 (ja) 1989-03-09 1996-07-24 三菱化学株式会社 ラクトン類の製法
US5055599A (en) 1989-06-23 1991-10-08 The Standard Oil Company Process for the hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone
JP2516815B2 (ja) 1989-08-11 1996-07-24 三菱化学株式会社 ラクトン類の製造法
JP2785967B2 (ja) 1989-08-25 1998-08-13 三菱化学株式会社 ラクトン類の製造方法
JP2825286B2 (ja) 1989-09-27 1998-11-18 三菱化学株式会社 ラクトン類の製造法
US5047561A (en) 1989-09-27 1991-09-10 Mitsubishi Kasei Corporation Process for producing a lactone
JP2516836B2 (ja) * 1989-10-04 1996-07-24 三菱化学株式会社 ラクトン類の製造法
US4973713A (en) 1989-11-28 1990-11-27 E. I. Du Pont De Nemours And Company Catalytic hydrogenation of carboxylic anhydrides to esters or lactones
JP2595358B2 (ja) 1989-12-07 1997-04-02 東燃株式会社 1,4―ブタンジオールおよびテトラヒドロフランの製造方法
US5077442A (en) 1990-04-26 1991-12-31 Mitsubishi Kasei Corporation Method for producing 1,4-butanediol
IE912635A1 (en) 1990-07-27 1992-01-29 Du Pont Hydrogenation catalyst and method for preparing¹tetrahydrofuran
JP2906706B2 (ja) 1990-10-08 1999-06-21 三菱化学株式会社 1,4−ブタンジオールの製造法
EP0543340B1 (en) 1991-11-18 1998-05-20 Tosoh Corporation Process for preparing lactones
US5196602A (en) 1991-12-30 1993-03-23 The Standard Oil Company Two-stage maleic anhydride hydrogenation process for 1,4-butanediol synthesis
JPH06107654A (ja) 1992-09-29 1994-04-19 Tosoh Corp ラクトン類の製造法
JP3194803B2 (ja) 1992-12-03 2001-08-06 東ソー株式会社 ラクトン類の製造方法
JPH0733756A (ja) 1993-06-28 1995-02-03 Tosoh Corp ラクトン類を製造する方法
JP3381804B2 (ja) 1993-07-27 2003-03-04 荒川化学工業株式会社 カルボン酸直接還元用触媒および該触媒の製造方法ならびにアルコール化合物の製造方法
JPH0782260A (ja) 1993-09-14 1995-03-28 Tosoh Corp ラクトン類の製法
TW319771B (pt) 1994-04-05 1997-11-11 Mitsubishi Chem Corp
JP3560377B2 (ja) 1995-01-06 2004-09-02 昭和電工株式会社 水素化触媒及びそれを用いた反応
US5473086A (en) 1995-01-17 1995-12-05 The Standard Oil Co. Process for the hydrogenation of maleic acid to 1,4-butanediol
US5478952A (en) * 1995-03-03 1995-12-26 E. I. Du Pont De Nemours And Company Ru,Re/carbon catalyst for hydrogenation in aqueous solution
US5698749A (en) 1995-09-06 1997-12-16 The Standard Oil Company Catalysts for the hydrogenation of aqueous maleic acid to 1,4-butanediol
DE59706719D1 (de) 1996-04-26 2002-05-02 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines in situ gebildeten Ruthenium-katalysators
ZA973972B (en) 1996-05-14 1998-03-23 Kvaerner Process Tech Ltd A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran.
ZA973971B (en) 1996-05-15 1998-03-23 Kvaerner Process Tech Ltd A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran.
DE19622497A1 (de) * 1996-06-05 1997-12-11 Basf Ag Verfahren zur Herstellung von Tetrahydrofuran aus Dialkoxybutenen
EP0813906A3 (de) 1996-06-19 1998-11-18 Basf Aktiengesellschaft Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
US5969164A (en) 1996-12-20 1999-10-19 The Standard Oil Company Catalysts for the hydrogenation of maleic acid to 1,4-butanediol
TW500716B (en) 1997-03-04 2002-09-01 Mitsubishi Chem Corp A method for producing 1,6-hexanediol
US5985789A (en) 1997-03-27 1999-11-16 E. I. Du Pont De Nemours And Company Ru, Sn/oxide catalyst and process for hydrogenation in acidic aqueous solution
GB9724004D0 (en) 1997-11-13 1998-10-21 Kvaerner Process Tech Ltd Process
GB9724195D0 (en) 1997-11-14 1998-01-14 Kvaerner Process Tech Ltd Process
BE1011699A6 (fr) 1998-01-08 1999-12-07 Pantochim Sa Procede de production de tetrahydrofuranne et de gamma-butyrolactone.
US6008384A (en) 1998-03-03 1999-12-28 E. I. Du Pont De Nemours And Company Method and Ru,Re,Sn/carbon catalyst for hydrogenation in aqueous solution
EP0962438B1 (en) 1998-03-23 2001-06-06 Basf Aktiengesellschaft Process for the preparation of 1,4-butanediol, butyrolactone and tetrahydrofuran.
DE19818248A1 (de) 1998-04-23 1999-10-28 Basf Ag Verfahren zur Herstellung von 1,4-Butandiol
DE19818340A1 (de) 1998-04-23 1999-10-28 Basf Ag Verfahren zur Herstellung von Gemischen aus 1,4-Butandiol, Tetrahydrofuran und gamma-Butyrolacton
JP2000034244A (ja) * 1998-07-16 2000-02-02 Mitsubishi Chemicals Corp 1,4−ブタンジオール及び/又はテトラヒドロフランの製造方法
BE1012274A7 (fr) 1998-11-10 2000-08-01 Pantochim Sa Procede a haute productivite pour la preparation de gamma butyrolactone et de tetrahydrofurane.
ATE345867T1 (de) 1999-08-18 2006-12-15 Ineos Usa Llc Verbesserte katalysatoren zur hydrierung von maleinsäure zu 1,4-butandiol
CN1114488C (zh) 1999-08-30 2003-07-16 标准石油公司 用于马来酸加氢制1,4-丁二醇的改进的催化剂
MY139259A (en) 1999-10-12 2009-09-30 Kvaerner Process Tech Ltd Process
AU1055701A (en) 1999-11-05 2001-06-06 Asahi Kasei Kabushiki Kaisha Process for the preparation of diol mixtures
DE10061553A1 (de) 2000-12-11 2002-06-13 Basf Ag Poröser Katalysator für die Hydrierung von Maleinsäureanhydrid zu Tetrahydrofuran
DE10061555A1 (de) 2000-12-11 2002-06-20 Basf Ag Schalenkatalysator für die Hydrierung von Maleinsäureanhydrid und verwandten Verbindungen zu gamma-Butyrolacton und Tetrahydrofuran und Derivaten davon
DE10061557A1 (de) 2000-12-11 2002-06-13 Basf Ag Verfahren zur Hydrierung von Maleinsäureanhydrid und verwandten Verbindungen in zwei hintereinandergeschalteten Reaktionszonen
GB0210143D0 (en) 2002-05-02 2002-06-12 Davy Process Techn Ltd Process

Also Published As

Publication number Publication date
US7498450B2 (en) 2009-03-03
GB0325526D0 (en) 2003-12-03
AR046822A1 (es) 2005-12-28
ES2429063T3 (es) 2013-11-12
CA2543854A1 (en) 2005-06-09
ZA200604399B (en) 2007-10-31
MY140106A (en) 2009-11-30
SG147484A1 (en) 2008-11-28
KR101127083B1 (ko) 2012-03-23
TW200529924A (en) 2005-09-16
WO2005051875A1 (en) 2005-06-09
US20070142679A1 (en) 2007-06-21
CN1871194A (zh) 2006-11-29
EA010436B1 (ru) 2008-08-29
EP1678108A1 (en) 2006-07-12
EP1678108B1 (en) 2013-08-14
JP2007510638A (ja) 2007-04-26
BRPI0416091B1 (pt) 2014-08-19
TWI351314B (en) 2011-11-01
AU2004293238A1 (en) 2005-06-09
AU2004293238B2 (en) 2010-03-11
CN100467433C (zh) 2009-03-11
JP4648327B2 (ja) 2011-03-09
NO20062499L (no) 2006-06-16
CA2543854C (en) 2012-07-24
KR20060103502A (ko) 2006-10-02
PL1678108T3 (pl) 2014-01-31
EA200600881A1 (ru) 2006-08-25

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Legal Events

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B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/10/2004, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)