BRPI0416406A - método para produzir um catalisador ou pré-catalisador adequado para auxiliar na produção de alcanoatos de alquenila, composição para catalisar a produção de um alcanoato de alquenila e método de produção de alcanoatos de alquenila - Google Patents

método para produzir um catalisador ou pré-catalisador adequado para auxiliar na produção de alcanoatos de alquenila, composição para catalisar a produção de um alcanoato de alquenila e método de produção de alcanoatos de alquenila

Info

Publication number
BRPI0416406A
BRPI0416406A BRPI0416406-7A BRPI0416406A BRPI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A
Authority
BR
Brazil
Prior art keywords
catalyst
alkenyl
production
producing
alkanoates
Prior art date
Application number
BRPI0416406-7A
Other languages
English (en)
Inventor
Tao Wang
Leslie E Wade
Victor Wong
Valery Sokolovskii
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BRPI0416406A publication Critical patent/BRPI0416406A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B01J35/53—Spheres with a core-shell structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"MéTODO PARA PRODUZIR UM CATALISADOR OU PRé-CATALISADOR ADEQUADO PARA AUXILIAR NA PRODUçãO DE ALCANOATOS DE ALQUENILA, COMPOSIçãO PAPA CATALISAR A PRODUçãO DE UM ALCANOATO DE ALQUENILA E MéTODO DE PRODUçãO DE ALCANOATOS DE ALQUENILA". A presente invenção refere-se a pelo menos quatro diferentes aspectos relacionados com estrutura de catalisadores, métodos de fabricação destes catalisadores e métodos de utilização daqueles catalisadores para fabricar alcanoatos de alquenila. Separadamente ou juntos, os diversos aspectos da invenção referem-se a aperfeiçoar a produção de alcanoatos de alquenila e VA em especial, incluindo a redução de subprodutos e eficiência de produção melhorada. Um primeiro aspecto da presente invenção refere-se a um catalisador único de paládio/ouro ou pré-catalisador (opcionalmente calcinado) que inclui ródio ou outro metal. Um segundo aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é baseado em um material de suporte em camadas onde uma camada do material de suporte é substancialmente isenta de componentes catalíticos. Um terceiro aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador sobre um material de suporte que contém zircónia. Um quarto aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é produzido a partir de componentes catalíticos substancialmente isentos de cloro.
BRPI0416406-7A 2003-12-19 2004-11-19 método para produzir um catalisador ou pré-catalisador adequado para auxiliar na produção de alcanoatos de alquenila, composição para catalisar a produção de um alcanoato de alquenila e método de produção de alcanoatos de alquenila BRPI0416406A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53093603P 2003-12-19 2003-12-19
PCT/US2004/038814 WO2005065821A1 (en) 2003-12-19 2004-11-19 Layered support material for catalysts

Publications (1)

Publication Number Publication Date
BRPI0416406A true BRPI0416406A (pt) 2007-01-09

Family

ID=34748748

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0416406-7A BRPI0416406A (pt) 2003-12-19 2004-11-19 método para produzir um catalisador ou pré-catalisador adequado para auxiliar na produção de alcanoatos de alquenila, composição para catalisar a produção de um alcanoato de alquenila e método de produção de alcanoatos de alquenila

Country Status (15)

Country Link
EP (1) EP1694437A1 (pt)
JP (1) JP4772694B2 (pt)
KR (1) KR100890655B1 (pt)
CN (1) CN100569364C (pt)
AR (1) AR056250A1 (pt)
AU (1) AU2004311900B2 (pt)
BR (1) BRPI0416406A (pt)
CA (1) CA2547318C (pt)
NO (1) NO20062528L (pt)
NZ (1) NZ547073A (pt)
PL (1) PL380018A1 (pt)
RU (1) RU2380154C2 (pt)
UA (1) UA94208C2 (pt)
WO (1) WO2005065821A1 (pt)
ZA (1) ZA200604363B (pt)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA200704864B (en) * 2004-12-20 2008-08-27 Celanese Int Corp Modified support materials for catalysts
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
CN101428238B (zh) * 2007-11-07 2011-02-09 中国石油化工股份有限公司上海石油化工研究院 热稳定性的层状复合载体
DE102008059341A1 (de) * 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung
JP2011121048A (ja) * 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法
DE102011101459A1 (de) * 2011-05-13 2012-11-15 Süd-Chemie AG Verfahren zur Herstellung eines metallhaltigen Schalenkatalysators ohne Zwischenkalzinierung
DE102012008714A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
DE102013015436A1 (de) * 2012-09-19 2014-03-20 Clariant International Ltd. Kupfer-promotierter Schalenkatalysator zur Herstellung von Alkenylcarbonsäureestern
JP6866344B2 (ja) 2015-07-22 2021-04-28 ビーエーエスエフ コーポレーション 酢酸ビニルモノマー生成のための高い幾何学的表面積の触媒
CN105478154B (zh) * 2015-12-14 2019-09-03 中石化南京催化剂有限公司 一种用于高活性流体床催化剂
KR102309341B1 (ko) * 2017-11-30 2021-10-05 롯데케미칼 주식회사 열적 안정성이 향상된 코어-쉘 구조의 촉매담체 및 이의 제조방법
EP4201523A1 (de) 2021-12-21 2023-06-28 Clariant International Ltd Schalenkatalysator zur herstellung von alkenylcarbonsäureestern mit verbesserter pd-verteilung
EP4201519A1 (de) 2021-12-21 2023-06-28 Clariant International Ltd Schalenkatalysator zur herstellung von alkenylcarbonsäureestern mit verbesserter pd- und au-verteilung
KR20250084075A (ko) * 2023-12-01 2025-06-10 한국화학연구원 성형촉매 및 이의 제조방법

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FR2469204A1 (fr) * 1979-11-12 1981-05-22 Inst Francais Du Petrole Nouveaux catalyseurs de dealkylation, a la vapeur d'eau, d'hydrocarbures aromatiques
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
IN188013B (pt) * 1995-05-23 2002-08-10 Hoechst Celanese Corp
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Also Published As

Publication number Publication date
NO20062528L (no) 2006-07-03
UA94208C2 (ru) 2011-04-26
WO2005065821A1 (en) 2005-07-21
CA2547318C (en) 2010-11-02
NZ547073A (en) 2010-05-28
CA2547318A1 (en) 2005-07-21
KR100890655B1 (ko) 2009-03-26
AU2004311900A1 (en) 2005-07-21
CN100569364C (zh) 2009-12-16
RU2006119178A (ru) 2007-12-20
CN1929916A (zh) 2007-03-14
AR056250A1 (es) 2007-10-03
KR20060100454A (ko) 2006-09-20
EP1694437A1 (en) 2006-08-30
JP4772694B2 (ja) 2011-09-14
ZA200604363B (en) 2007-10-31
RU2380154C2 (ru) 2010-01-27
PL380018A1 (pl) 2006-12-11
AU2004311900B2 (en) 2008-10-02
JP2007514540A (ja) 2007-06-07

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