BRPI0501601A - Processo de transesterificação de óleo vegetais ou animais em um meio de catalisadores heterogêneos a base de zinco ou bismuto, titânio e alumìnio - Google Patents

Processo de transesterificação de óleo vegetais ou animais em um meio de catalisadores heterogêneos a base de zinco ou bismuto, titânio e alumìnio

Info

Publication number
BRPI0501601A
BRPI0501601A BR0501601-0A BRPI0501601A BRPI0501601A BR PI0501601 A BRPI0501601 A BR PI0501601A BR PI0501601 A BRPI0501601 A BR PI0501601A BR PI0501601 A BRPI0501601 A BR PI0501601A
Authority
BR
Brazil
Prior art keywords
titanium
bismuth
vegetable
zinc
medium
Prior art date
Application number
BR0501601-0A
Other languages
English (en)
Inventor
Bruno Delfort
Gerard Hillion
Dominique Le Pennec
Christophe Lendresse
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0404731A external-priority patent/FR2869613B1/fr
Priority claimed from FR0404730A external-priority patent/FR2869612B1/fr
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of BRPI0501601A publication Critical patent/BRPI0501601A/pt
Publication of BRPI0501601B1 publication Critical patent/BRPI0501601B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO DE TRANSESTERIFICAçãO DE óLEOS VEGETAIS OU ANIMAIS EM UM MEIO DE CATALISADORES HETEROGêNEOS A BASE DE ZINCO OU BISMUTO, TITâNIO E ALUMìNIO". A presente invenção refere-se a um processo de produção de ésteres e de ácidos monocarboxílicos, lineares, de 6 a 26 átomos de carbono, por reação de óleos vegetais ou animais, neutros ou não, como monoálcoois de 1 a 18 átomos de carbono, utiliza um catalisador escolhido dentre: - as combinações de óxidos de zinco e de titânio; e - as combinações de óxidos de zinco, de óxido de titânio e de alumina; -as combinações de óxidos de bismuto e de titânio; e - as combinações de óxidos de bismuto, de óxido de titânio e de alumina. O processo permite produzir diretamente, em uma ou várias etapas, um éster utilizável como carburante ou combustível e uma glicerina pura.
BRPI0501601-0A 2004-05-03 2005-05-03 Processo de transesterificação de óleos vegetais ou animais em um meio de catalisadores heterogêneos a base de zinco ou bismuto, titânio e alumínio BRPI0501601B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0404731A FR2869613B1 (fr) 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de bismuth, de titane et d'aluminium
FR0404730A FR2869612B1 (fr) 2004-05-03 2004-05-03 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de zinc, de titane et d'aluminium

Publications (2)

Publication Number Publication Date
BRPI0501601A true BRPI0501601A (pt) 2006-01-10
BRPI0501601B1 BRPI0501601B1 (pt) 2014-04-22

Family

ID=34942106

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0501601-0A BRPI0501601B1 (pt) 2004-05-03 2005-05-03 Processo de transesterificação de óleos vegetais ou animais em um meio de catalisadores heterogêneos a base de zinco ou bismuto, titânio e alumínio

Country Status (3)

Country Link
US (1) US7151187B2 (pt)
EP (1) EP1593732A1 (pt)
BR (1) BRPI0501601B1 (pt)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021697A1 (en) 2003-08-29 2005-03-10 Nippon Shokubai Co., Ltd. Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
EP2253609A1 (en) * 2003-11-20 2010-11-24 SOLVAY (Société Anonyme) Process for producing organic compounds from glycerol, the glycerol coming from renewable raw material
US7906690B2 (en) * 2004-07-21 2011-03-15 Dow Global Technologies Inc. Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloracetone levels
US7910781B2 (en) * 2004-07-21 2011-03-22 Dow Global Technologies Llc Process for the conversion of a crude glycerol, crude mixtures of naturally derived multihydroxylated aliphatic hydrocarbons or esters thereof to a chlorohydrin
CA2596105A1 (en) * 2005-02-21 2006-08-24 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin
EP1885676A2 (fr) * 2005-05-20 2008-02-13 Solvay SA Procede de conversion d'hydrocarbures aliphatiques poly hydroxyles en chlorhydrines
KR20080037613A (ko) 2005-05-20 2008-04-30 솔베이(소시에떼아노님) 폴리히드록실화 지방족 탄화수소의 클로로히드린으로의전환 방법
CN102219644B (zh) * 2005-11-08 2013-11-06 索尔维公司 通过甘油的氯化制备二氯丙醇的方法
KR101330183B1 (ko) * 2006-04-21 2013-11-15 이수화학 주식회사 바이오디젤 제조용 고체상 촉매 및 이를 이용한바이오디젤의 제조방법
EP2043984A1 (en) * 2006-06-14 2009-04-08 Solvay S.A. Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol
EP1878716A1 (en) * 2006-07-14 2008-01-16 Rohm and Haas Company Method for transesterification of triglycerides
US8445709B2 (en) * 2006-08-04 2013-05-21 Mcneff Research Consultants, Inc. Systems and methods for refining alkyl ester compositions
US7897798B2 (en) 2006-08-04 2011-03-01 Mcneff Research Consultants, Inc. Methods and apparatus for producing alkyl esters from lipid feed stocks and systems including same
US8017796B2 (en) * 2007-02-13 2011-09-13 Mcneff Research Consultants, Inc. Systems for selective removal of contaminants from a composition and methods of regenerating the same
US8585976B2 (en) * 2007-02-13 2013-11-19 Mcneff Research Consultants, Inc. Devices for selective removal of contaminants from a composition
FR2913421B1 (fr) 2007-03-07 2009-05-15 Solvay Procede de fabrication de dichloropropanol.
FR2913684B1 (fr) 2007-03-14 2012-09-14 Solvay Procede de fabrication de dichloropropanol
TW200911740A (en) * 2007-06-01 2009-03-16 Solvay Process for manufacturing a chlorohydrin
TW200911693A (en) 2007-06-12 2009-03-16 Solvay Aqueous composition containing a salt, manufacturing process and use
TW200911773A (en) 2007-06-12 2009-03-16 Solvay Epichlorohydrin, manufacturing process and use
DE112008002440T5 (de) 2007-09-28 2010-08-19 Ifp Verfahren zur Herstellung von Alkoholestern aus Triglyceriden und Alkoholen mittels heterogener Katalysatoren auf der Basis eines hybriden Feststoffs mit organisch-anorganischer Mischmatrix
US7943791B2 (en) * 2007-09-28 2011-05-17 Mcneff Research Consultants, Inc. Methods and compositions for refining lipid feed stocks
CN101896262A (zh) 2007-10-02 2010-11-24 索尔维公司 含硅的组合物用于改进容器的抗腐蚀性的用途
FR2925045B1 (fr) 2007-12-17 2012-02-24 Solvay Produit a base de glycerol, procede pour son obtention et son utilisation dans la fabrication de dichloropropanol
TWI478875B (zh) 2008-01-31 2015-04-01 Solvay 使水性組成物中之有機物質降解之方法
TWI448449B (zh) 2008-04-03 2014-08-11 Solvay 含甘油的組成物、彼之製法及彼於製造二氯丙醇上的用途
EP3572395A1 (en) * 2008-06-25 2019-11-27 Benefuel Inc. Process of manufacturing of fatty acid alkyl esters
WO2010020053A1 (en) * 2008-08-21 2010-02-25 Sbi Fine Chemicals Inc. Solid, heterogeneous catalysts and methods of use
FR2935968B1 (fr) * 2008-09-12 2010-09-10 Solvay Procede pour la purification de chlorure d'hydrogene
FR2935983B1 (fr) * 2008-09-15 2010-09-17 Inst Francais Du Petrole Procede de preparation d'esters alcooliques a partir de triglycerides et d'alcools au moyen de catalyseur heterogene a base d'un solide silicique mesostructure contenant du zinc
US8361174B2 (en) * 2008-10-07 2013-01-29 Sartec Corporation Catalysts, systems, and methods for producing fuels and fuel additives from polyols
US9102877B2 (en) 2008-11-12 2015-08-11 Sartec Corporation Systems and methods for producing fuels from biomass
BRPI0805625A2 (pt) * 2008-12-29 2010-09-14 Petroleo Brasileiro Sa catalisadores heterogêneos para a transesterificação de triglicerìdeos e métodos preparatórios dos mesmos
WO2011149754A1 (en) 2010-05-26 2011-12-01 Dow Global Technologies Llc Process for hydrochlorination of multihydroxylated aliphatic hydrocarbons
JP6049087B2 (ja) 2010-09-30 2016-12-21 ソルヴェイ（ソシエテ アノニム） 天然起源のエピクロロヒドリンの誘導体
EP2457648A1 (en) 2010-11-29 2012-05-30 Yellow Diesel B.V. Production of fatty acid alkyl esters
CN103370405B (zh) 2011-02-14 2016-05-11 科学与工业研究委员会 使用生态友好固体碱催化剂由甘油三酯油制备脂肪酸烷基酯(生物柴油)的改进方法
CA2826817C (en) 2011-03-09 2019-01-15 Benefuel Inc. Systems and methods for making bioproducts
US9328054B1 (en) 2013-09-27 2016-05-03 Travis Danner Method of alcoholisis of fatty acids and fatty acid gyicerides
CN103752297B (zh) * 2014-01-03 2016-02-24 南昌大学 一种用于生产生物柴油的氧化锆催化剂及制备方法和应用
CN103877958B (zh) * 2014-03-12 2017-06-13 南京大学昆山创新研究院 用于制备生物柴油的催化剂及制备方法和生物柴油的制备工艺
CN105032386B (zh) * 2015-07-24 2017-11-21 南昌大学 一种用于废弃油脂与废弃塑料共裂解的泡沫陶瓷催化剂及制备方法
CN105566407A (zh) * 2016-02-17 2016-05-11 常州市庆发工业气体有限公司 一种利用大豆油和蔗糖超声合成蔗糖脂肪酸酯的方法
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US11964263B2 (en) 2018-08-17 2024-04-23 Sbi Fine Chemicals Inc. Catalyst for the production of carboxylic acid ester

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752242B1 (fr) * 1996-08-08 1998-10-16 Inst Francais Du Petrole Procede de fabrication d'esters a partir d'huiles vegetales ou animales et d'alcools
FR2772756B1 (fr) * 1997-12-18 2000-02-11 Inst Francais Du Petrole Procede de fabrication d'esters de corps gras et les esters de haute purete obtenus
US6396718B1 (en) * 2000-12-19 2002-05-28 Semiconductor Components Industries Llc Switch mode power supply using transformer flux sensing for duty cycle control
US8419810B2 (en) * 2004-02-24 2013-04-16 IFP Energies Nouvelles Method for producing biofuels, transforming triglycerides into at least two biofuel families: fatty acid monoesters and ethers and/or soluble glycerol acetals

Also Published As

Publication number Publication date
US7151187B2 (en) 2006-12-19
BRPI0501601B1 (pt) 2014-04-22
EP1593732A1 (fr) 2005-11-09
US20050261509A1 (en) 2005-11-24

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Legal Events

Date Code Title Description
B03A Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]
B03H Publication of an application: rectification [chapter 3.8 patent gazette]

Free format text: REFERENTE A RPI 1827 DE 10/01/2006, QUANTO AO ITEM (54)

B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/05/2005, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 11A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.