BRPI0416549A - copolìmeros de monovinilareno/dieno conjugado tendo menores temperaturas de transição ao vidro - Google Patents
copolìmeros de monovinilareno/dieno conjugado tendo menores temperaturas de transição ao vidroInfo
- Publication number
- BRPI0416549A BRPI0416549A BRPI0416549-7A BRPI0416549A BRPI0416549A BR PI0416549 A BRPI0416549 A BR PI0416549A BR PI0416549 A BRPI0416549 A BR PI0416549A BR PI0416549 A BRPI0416549 A BR PI0416549A
- Authority
- BR
- Brazil
- Prior art keywords
- conjugated diene
- monovinylene
- glass transition
- transition temperatures
- lower glass
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Developing Agents For Electrophotography (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"COPOLìMEROS DE MONOVINILARENO/DIENO CONJUGADO TENDO MENORES TEMPERATURAS DE TRANSIçãO AO VIDRO". Divulgamos um copolímero de bloco de monovinilareno/ dieno conjugado, compreendendo: (i) um bloco aleatório (de monovinilareno~ y~ /dieno~ x~ conjugado)~ m~, onde x é de cerca de 2,5% em peso a cerca de 10% em peso, y é de cerca de 90% em peso a cerca de 97,5% em peso, e x + y é de cerca de 97,5% em peso a 100% em peso; e (ii) um bloco (de dieno conjugado)~ n~; onde n é de cerca de 20% em peso a cerca de 30% em peso, m é de cerca de 70% em peso a cerca de 80% em peso, e m + n é de cerca de 90% em peso a 100% em peso. Também divulgamos um processo para formação do copolímero de bloco e um processo para fabricação de um artigo, a partir do copolímero de bloco. O copolímero de bloco exibe tipicamente uma T~ g~ pelo menos cerca de 10 <198>C inferior à T~ g~ de um polímero de referência, diferindo apenas em que x é cerca de 0% em peso e y é cerca de 100% em peso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/705,704 US7037980B2 (en) | 2003-11-10 | 2003-11-10 | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
| PCT/US2004/037279 WO2005047355A2 (en) | 2003-11-10 | 2004-11-05 | Monovinylarene/conjugated diene copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0416549A true BRPI0416549A (pt) | 2007-01-09 |
Family
ID=34552431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0416549-7A BRPI0416549A (pt) | 2003-11-10 | 2004-11-05 | copolìmeros de monovinilareno/dieno conjugado tendo menores temperaturas de transição ao vidro |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7037980B2 (pt) |
| EP (1) | EP1687352A2 (pt) |
| JP (1) | JP4928269B2 (pt) |
| KR (1) | KR101168442B1 (pt) |
| CN (3) | CN100523032C (pt) |
| BR (1) | BRPI0416549A (pt) |
| CA (1) | CA2545747A1 (pt) |
| SG (1) | SG126933A1 (pt) |
| TW (1) | TW200535155A (pt) |
| WO (1) | WO2005047355A2 (pt) |
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| US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
| AU2003301053A1 (en) * | 2002-12-18 | 2004-07-22 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber contaiing same |
| US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
| US7205370B2 (en) * | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
| US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
| US7718737B2 (en) * | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
| US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
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| US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
| US7998554B2 (en) * | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
| US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
| US7579398B2 (en) * | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
| US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
| US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
| US9061900B2 (en) | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
| US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
| US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
| US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
| US8697775B2 (en) | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
| US7601772B2 (en) * | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
| US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
| US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
| WO2008014464A2 (en) | 2006-07-28 | 2008-01-31 | Bridgestone Corporation | Polymeric core-shell nanoparticles with interphase region |
| US8415429B2 (en) * | 2006-12-11 | 2013-04-09 | Chervron Phillips Chemical Company LP | Styrene butadiene block copolymers for film applications |
| US7597959B2 (en) | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
| US7649049B2 (en) * | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
| US7829624B2 (en) * | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| BRPI0704674A2 (pt) * | 2007-12-14 | 2009-08-11 | Petroflex Ind E Com S A | processo para preparação de copolìmero de 1,3-butadieno e estireno contendo em sua cadeia principal segmento aleatório, seguido de bloco com estrutura diferenciada da cadeia principal, homopolimérico ou copolimérico, funcionalizado e produto obtido a partir do mesmo |
| US8759445B2 (en) * | 2008-06-27 | 2014-06-24 | Styrolution GmbH | Styrene butadiene block copolymer mixtures for shrink-wrap films |
| EP2370349B1 (en) | 2008-12-31 | 2014-10-29 | Bridgestone Corporation | Core-first nanoparticle formation process, nanoparticle, and composition |
| US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
| US9115222B2 (en) | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
| US8344078B2 (en) | 2010-05-21 | 2013-01-01 | Chevron Phillips Chemical Company Lp | Continuous take off technique and pressure control of polymerization reactors |
| US9163564B2 (en) | 2010-06-21 | 2015-10-20 | Chevron Phillips Chemical Company Lp | Method and system for energy generation in a chemical plant by utilizing flare gas |
| US8703063B2 (en) | 2010-06-21 | 2014-04-22 | Chevron Phillips Chemical Company Lp | System and method for closed relief of a polyolefin loop reactor system |
| US9174377B2 (en) | 2011-05-12 | 2015-11-03 | Chevron Phillips Chemical Company Lp | Multilayer blown films for shrink applications |
| US8597582B2 (en) | 2011-06-30 | 2013-12-03 | Chevron Phillips Chemical Company Lp | Flashline heater system and method |
| US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
| CN103374109A (zh) * | 2012-04-24 | 2013-10-30 | 中国石油天然气股份有限公司 | 一种异戊二烯-苯乙烯星型共聚物及其制备方法 |
| JP6049865B2 (ja) | 2012-05-08 | 2016-12-21 | シェブロン フィリップス ケミカル カンパニー エルピー | ゴム及びブロック共重合体を含有する耐コールドフロー性組成物 |
| US10145075B2 (en) | 2013-11-14 | 2018-12-04 | MedVasis, LLC | Multilayer marine wraps |
| KR102641191B1 (ko) * | 2015-03-12 | 2024-02-26 | 이네오스 스티롤루션 그룹 게엠베하 | 튜빙 적용을 위한 스티렌-부타디엔 블록 공중합체 |
| US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
| US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
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| US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| EP3559064B1 (en) | 2016-12-23 | 2020-09-23 | INEOS Styrolution Group GmbH | Polymer compositions for shrink-wrap films |
| US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
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-
2003
- 2003-11-10 US US10/705,704 patent/US7037980B2/en not_active Expired - Lifetime
-
2004
- 2004-10-27 TW TW093132472A patent/TW200535155A/zh unknown
- 2004-11-05 CN CNB2004800382195A patent/CN100523032C/zh not_active Expired - Fee Related
- 2004-11-05 EP EP04818658A patent/EP1687352A2/en not_active Withdrawn
- 2004-11-05 WO PCT/US2004/037279 patent/WO2005047355A2/en not_active Ceased
- 2004-11-05 CN CNA2008100962665A patent/CN101429268A/zh active Pending
- 2004-11-05 SG SG200607044A patent/SG126933A1/en unknown
- 2004-11-05 BR BRPI0416549-7A patent/BRPI0416549A/pt not_active Application Discontinuation
- 2004-11-05 KR KR1020067008934A patent/KR101168442B1/ko not_active Expired - Fee Related
- 2004-11-05 JP JP2006539728A patent/JP4928269B2/ja not_active Expired - Fee Related
- 2004-11-05 CN CN2010105161340A patent/CN102030874A/zh active Pending
- 2004-11-05 CA CA002545747A patent/CA2545747A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007510803A (ja) | 2007-04-26 |
| CN101429268A (zh) | 2009-05-13 |
| KR101168442B1 (ko) | 2012-07-27 |
| CN102030874A (zh) | 2011-04-27 |
| US7037980B2 (en) | 2006-05-02 |
| CN1902248A (zh) | 2007-01-24 |
| WO2005047355A3 (en) | 2005-09-09 |
| TW200535155A (en) | 2005-11-01 |
| CA2545747A1 (en) | 2005-05-26 |
| SG126933A1 (en) | 2006-11-29 |
| WO2005047355A2 (en) | 2005-05-26 |
| CN100523032C (zh) | 2009-08-05 |
| JP4928269B2 (ja) | 2012-05-09 |
| KR20060120082A (ko) | 2006-11-24 |
| US20050101743A1 (en) | 2005-05-12 |
| EP1687352A2 (en) | 2006-08-09 |
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