BRPI0417375A - filme de fibrida de para-aramida, composição, papel produzido de constituiente, e, método de manufatura do filme de fibrida - Google Patents
filme de fibrida de para-aramida, composição, papel produzido de constituiente, e, método de manufatura do filme de fibridaInfo
- Publication number
- BRPI0417375A BRPI0417375A BRPI0417375-9A BRPI0417375A BRPI0417375A BR PI0417375 A BRPI0417375 A BR PI0417375A BR PI0417375 A BRPI0417375 A BR PI0417375A BR PI0417375 A BRPI0417375 A BR PI0417375A
- Authority
- BR
- Brazil
- Prior art keywords
- para
- fibride
- film
- aramid
- polymer
- Prior art date
Links
- 229920003235 aromatic polyamide Polymers 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- 239000000470 constituent Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 239000011877 solvent mixture Substances 0.000 abstract 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004760 aramid Substances 0.000 abstract 1
- 150000004984 aromatic diamines Chemical class 0.000 abstract 1
- -1 aromatic dicarboxylic acid halide Chemical class 0.000 abstract 1
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 1
- 239000001110 calcium chloride Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/26—Polyamides; Polyimides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Paper (AREA)
- Artificial Filaments (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyamides (AREA)
- Nonwoven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
"FILME DE FIBRIDA DE PARA-ARAMIDA, COMPOSIçãO, PAPEL PRODUZIDO DE CONSTITUINTE, E, MéTODO DE MANUFATURA DO FILME DE FIBRIDA". A invenção refere-se a um filme de fibrida de para-aramida, caracterizado pelo fato de que pelo menos 95% das ligações do polímero são para-orientadas, e a um método para a produção do referido filme de fibrida de para-aramida através de a. polimerização de uma diamina aromática para-oríentada e de um halogeneto de ácido dicarboxílico aromático para-orientado para um polímero de aramida tendo apenas ligações para-orientadas em uma mistura de solventes consistindo de N-metilpirrolidona ou dimetilacetamida e cloreto de cálcio ou cloreto de lítio para obter um dope, em que o polimero é dissolvido na mistura de solvente e a concentração de polímero é de 2 a 6% em peso, e b. conversão do dope para o filme de fibrida de para -aramida através do uso de métodos convencionais para a produção de fibrida de metaaramida.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03028090 | 2003-12-09 | ||
| PCT/EP2004/013543 WO2005059247A1 (en) | 2003-12-09 | 2004-11-30 | Para-aramid fibrid film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0417375A true BRPI0417375A (pt) | 2007-04-10 |
Family
ID=34684524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0417375-9A BRPI0417375A (pt) | 2003-12-09 | 2004-11-30 | filme de fibrida de para-aramida, composição, papel produzido de constituiente, e, método de manufatura do filme de fibrida |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9194061B2 (pt) |
| EP (1) | EP1694914B1 (pt) |
| JP (1) | JP4651041B2 (pt) |
| KR (1) | KR101131452B1 (pt) |
| CN (1) | CN1890432B (pt) |
| AR (1) | AR046461A1 (pt) |
| AU (1) | AU2004299598B2 (pt) |
| BR (1) | BRPI0417375A (pt) |
| CA (1) | CA2548745C (pt) |
| MY (1) | MY145156A (pt) |
| RU (1) | RU2366670C2 (pt) |
| TW (1) | TWI362441B (pt) |
| WO (1) | WO2005059247A1 (pt) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007177113A (ja) | 2005-12-28 | 2007-07-12 | Teijin Techno Products Ltd | 有機高分子重合体微粒子およびその製造方法 |
| MX2009010680A (es) | 2007-04-05 | 2009-10-23 | Teijin Aramid Bv | Particulas que comprenden material mixto para-aramidico y material aditivo. |
| US7780889B2 (en) * | 2007-12-19 | 2010-08-24 | E.I. Du Pont De Nemours And Company | Multistage draw with relaxation step |
| US7771638B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Rapid plasticization of quenched yarns |
| US7771637B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | High-speed meta-aramid fiber production |
| US7771636B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Single stage drawing for MPD-I yarn |
| US8603221B2 (en) | 2009-05-08 | 2013-12-10 | Uop Llc | Rapid cycle, gas permeable, adsorbent-containing paper containing p-aramid fibrids and zeolite |
| US9437348B2 (en) | 2010-12-17 | 2016-09-06 | 3M Innovative Properties Company | Electrical insulation material |
| CN108086041B (zh) | 2011-01-04 | 2021-06-01 | 帝人芳纶有限公司 | 包含微丝的纸 |
| JP5886320B2 (ja) * | 2011-01-04 | 2016-03-16 | テイジン・アラミド・ビー.ブイ. | 電気絶縁紙 |
| WO2013045366A1 (en) | 2011-09-27 | 2013-04-04 | Teijin Aramid B.V. | Antistatic aramid material |
| CN102517976A (zh) * | 2011-12-08 | 2012-06-27 | 烟台民士达特种纸业股份有限公司 | 一种纯对位芳纶纸的制备方法 |
| WO2013117462A1 (en) | 2012-02-07 | 2013-08-15 | Teijin Aramid B.V. | Aramid paper having increased strength and process for manufacturing thereof |
| EP2861418B1 (en) | 2012-06-15 | 2021-02-17 | 3M Innovative Properties Company | Electrical insulation material |
| EP3373309B1 (en) * | 2012-11-23 | 2020-01-22 | Teijin Aramid B.V. | Electrical insulating paper |
| US10519569B2 (en) | 2013-02-13 | 2019-12-31 | President And Fellows Of Harvard College | Immersed rotary jet spinning devices (IRJS) and uses thereof |
| CN103937238B (zh) * | 2014-04-16 | 2016-04-20 | 鲁东大学 | 一种球形纳米芳纶材料及其制备方法 |
| CN104088131B (zh) * | 2014-06-23 | 2016-04-13 | 华南理工大学 | 一种绝缘芳纶材料及其制备方法 |
| TWI613336B (zh) * | 2014-06-26 | 2018-02-01 | 財團法人紡織產業綜合研究所 | 紡絲設備 |
| CN104630924B (zh) * | 2015-01-12 | 2017-01-04 | 烟台泰和新材料股份有限公司 | 一种芳香族聚酰胺薄膜状沉析纤维的制备方法 |
| CN105506769B (zh) * | 2016-01-07 | 2019-11-08 | 江苏先诺新材料科技有限公司 | 一种聚酰胺酸沉析纤维和聚酰亚胺沉析纤维及其制备方法 |
| CN106436440B (zh) * | 2016-10-11 | 2018-12-07 | 四川辉腾科技股份有限公司 | 间位芳纶沉析纤维的纤维成型控制生产方法 |
| EP3548657B1 (en) | 2016-11-30 | 2022-08-17 | Teijin Aramid B.V. | Aramid paper suitable for use in electronic applications |
| CN108048938B (zh) * | 2018-01-17 | 2020-01-10 | 烟台泰和新材料股份有限公司 | 一种对位芳纶沉析纤维的生产方法 |
| EP3802937A1 (en) | 2018-05-28 | 2021-04-14 | Teijin Aramid B.V. | Aramid-based paper with improved properties |
| US11228037B2 (en) | 2018-07-12 | 2022-01-18 | GM Global Technology Operations LLC | High-performance electrodes with a polymer network having electroactive materials chemically attached thereto |
| US10868307B2 (en) | 2018-07-12 | 2020-12-15 | GM Global Technology Operations LLC | High-performance electrodes employing semi-crystalline binders |
| KR102140310B1 (ko) * | 2018-10-01 | 2020-07-31 | 주식회사 휴비스 | 강도가 우수한 메타아라미드 섬유 및 그의 제조방법 |
| CA3124904A1 (en) | 2019-01-14 | 2020-07-23 | President And Fellows Of Harvard College | Focused rotary jet spinning devices and methods of use thereof |
| CN110042664A (zh) * | 2019-04-23 | 2019-07-23 | 鲁东大学 | Ppta寡聚物在对位芳纶纤维增强中的应用 |
| CN110129912B (zh) * | 2019-06-10 | 2021-10-26 | 黄河三角洲京博化工研究院有限公司 | 一种对位芳纶沉析纤维及其连续生产方法 |
| CN114423892A (zh) * | 2019-10-07 | 2022-04-29 | 帝人株式会社 | 制造包含间位芳族聚酰胺的纤维的方法 |
| JP2023507132A (ja) * | 2019-12-20 | 2023-02-21 | テイジン・アラミド・ビー.ブイ. | リサイクルのための連続的な方法 |
| CN113668089B (zh) * | 2020-05-13 | 2023-07-28 | 中蓝晨光化工有限公司 | 一种芳香族聚酰胺膜状沉析纤维的制备方法 |
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| CN115369505B (zh) * | 2022-07-08 | 2024-05-03 | 株洲时代新材料科技股份有限公司 | 一种多级分散盘沉析成型装置及成型工艺、沉析纤维沉析纯化装置及其工艺 |
| CN115787123B (zh) * | 2022-09-16 | 2024-11-15 | 株洲时代华先材料科技有限公司 | 一种长度分布集中的高保水值间位芳纶沉析纤维及其制备方法 |
| CN116120746B (zh) * | 2022-12-01 | 2025-02-11 | 湖北美辰环保股份有限公司 | 一种模版法制备水凝胶光热材料 |
| CN116199920A (zh) * | 2022-12-27 | 2023-06-02 | 东华大学 | 一种低膨胀系数ppta薄膜及其制备方法 |
| WO2025209975A1 (en) | 2024-04-03 | 2025-10-09 | Teijin Aramid B.V. | Resin-impregnated aramid-based honeycomb core and paper suitable for use therein |
| WO2026008752A1 (en) | 2024-07-05 | 2026-01-08 | Teijin Aramid B.V. | Recycling of aramid honeycombs |
| EP4703131A1 (en) | 2024-09-03 | 2026-03-04 | Teijin Aramid B.V. | Method and apparatus for manufacturing an assembly of honeycomb structures and articles comprising the assembly of honeycomb structures |
| CN119145077B (zh) * | 2024-10-18 | 2025-06-13 | 长春赛诺方材料有限公司 | 一种超薄型间位芳纶沉析纤维及其制备方法和应用 |
| CN119593243B (zh) * | 2024-12-25 | 2025-11-18 | 烟台民士达特种纸业股份有限公司 | 一种对位芳纶纸及其制备方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL246230A (pt) | 1958-12-09 | |||
| US3018091A (en) * | 1959-04-10 | 1962-01-23 | Du Pont | Precipitation apparatus |
| US3756908A (en) | 1971-02-26 | 1973-09-04 | Du Pont | Synthetic paper structures of aromatic polyamides |
| US3869429A (en) * | 1971-08-17 | 1975-03-04 | Du Pont | High strength polyamide fibers and films |
| US4049493A (en) * | 1974-08-09 | 1977-09-20 | Champion International Corporation | Self-bonding synthetic wood pulp and paper-like films thereof and method for production of same |
| FR2496678B1 (fr) * | 1980-12-22 | 1985-10-11 | Rhone Poulenc Textile | Compositions de polyparaphenyleneterephtalamide ainsi que leur preparation et un procede d'obtention de fibres a partir de telles compositions |
| US4515656A (en) * | 1981-08-28 | 1985-05-07 | E. I. Du Pont De Nemours And Company | Low density nonwoven sheets |
| US4842924A (en) * | 1986-08-25 | 1989-06-27 | Farris Richard J | Novel compositions based on reinforcement with microfibrillar networks of rigid-rod polymers |
| US4785038A (en) * | 1987-07-27 | 1988-11-15 | E. I. Du Pont De Nemours And Company | Solvent system for difficultly soluble polymers |
| RU2059027C1 (ru) * | 1988-06-30 | 1996-04-27 | Е.И.Дюпон Де Немур Энд Компани | Пульпа и способ ее получения |
| US4921900A (en) * | 1988-12-14 | 1990-05-01 | E. I. Du Pont De Nemours And Company | Stable solutions of poly(paraphenylene terephthalamide) acid crumb |
| US5094913A (en) * | 1989-04-13 | 1992-03-10 | E. I. Du Pont De Nemours And Company | Oriented, shaped articles of pulpable para-aramid/meta-aramid blends |
| US5021516A (en) | 1989-06-26 | 1991-06-04 | E. I. Du Pont De Nemours And Company | Poly(perfluoroether)acyl peroxides |
| US5026456A (en) * | 1990-06-14 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Aramid papers containing aramid paper pulp |
| US5474842A (en) * | 1991-08-20 | 1995-12-12 | Hoiness; David E. | Aramid particles as wear additives |
| JP2897592B2 (ja) * | 1992-05-28 | 1999-05-31 | 住友化学工業株式会社 | 低重合度パラアラミドドープ、それから製造されるパラアラミド繊維およびパラアラミドパルプならびにそれらの製造方法 |
| TW226417B (pt) * | 1992-05-28 | 1994-07-11 | Sumitomo Chemical Co | |
| US5416164A (en) * | 1993-04-12 | 1995-05-16 | E. I. Du Pont De Nemours And Company | Solution of PPD-T and PVP and articles made therefrom |
| US5532059A (en) * | 1994-09-29 | 1996-07-02 | E. I. Du Pont De Nemours And Company | Poly(p-phenylene terephthalamide) pulp |
| JP2981146B2 (ja) * | 1995-03-30 | 1999-11-22 | 財団法人工業技術研究院 | 可溶性全芳香族ポリアミドの成形製品の製造法 |
| JP3141727B2 (ja) * | 1995-06-09 | 2001-03-05 | 住友化学工業株式会社 | パラアラミドパルプおよびその製造方法 |
| JP2732822B2 (ja) * | 1995-12-28 | 1998-03-30 | デュポン帝人アドバンスドペーパー株式会社 | 複合体シートおよびその製造方法 |
| NL1002882C2 (nl) * | 1996-04-17 | 1997-10-21 | Akzo Nobel Nv | Zwavelhoudend p-aramide garen. |
| JPH101894A (ja) * | 1996-06-12 | 1998-01-06 | Unitika Ltd | ポリイミド紙及びその製造方法 |
| AU6763798A (en) | 1997-03-31 | 1998-10-22 | Fibermark, Inc. | Method of making a metal fiber sheet |
| JP3869559B2 (ja) * | 1998-09-28 | 2007-01-17 | 新神戸電機株式会社 | 電気絶縁用不織布ならびにプリプレグ及び積層板 |
| US6120643A (en) * | 1999-10-27 | 2000-09-19 | E. I. Du Pont De Nemours And Company | Aramid and glass fiber absorbent papers |
-
2004
- 2004-11-25 MY MYPI20044888A patent/MY145156A/en unknown
- 2004-11-29 AR ARP040104429 patent/AR046461A1/es not_active Application Discontinuation
- 2004-11-30 EP EP04803347.6A patent/EP1694914B1/en not_active Expired - Lifetime
- 2004-11-30 BR BRPI0417375-9A patent/BRPI0417375A/pt not_active IP Right Cessation
- 2004-11-30 RU RU2006124555A patent/RU2366670C2/ru active
- 2004-11-30 KR KR1020067011451A patent/KR101131452B1/ko not_active Expired - Lifetime
- 2004-11-30 US US10/582,119 patent/US9194061B2/en active Active
- 2004-11-30 WO PCT/EP2004/013543 patent/WO2005059247A1/en not_active Ceased
- 2004-11-30 CA CA 2548745 patent/CA2548745C/en not_active Expired - Fee Related
- 2004-11-30 CN CN2004800364708A patent/CN1890432B/zh not_active Expired - Lifetime
- 2004-11-30 JP JP2006543428A patent/JP4651041B2/ja not_active Expired - Lifetime
- 2004-11-30 AU AU2004299598A patent/AU2004299598B2/en not_active Ceased
- 2004-12-07 TW TW93137751A patent/TWI362441B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060123301A (ko) | 2006-12-01 |
| MY145156A (en) | 2011-12-30 |
| JP4651041B2 (ja) | 2011-03-16 |
| CA2548745C (en) | 2012-07-10 |
| AR046461A1 (es) | 2005-12-07 |
| AU2004299598A1 (en) | 2005-06-30 |
| EP1694914A1 (en) | 2006-08-30 |
| CN1890432B (zh) | 2012-11-07 |
| RU2006124555A (ru) | 2008-01-20 |
| RU2366670C2 (ru) | 2009-09-10 |
| TW200533809A (en) | 2005-10-16 |
| TWI362441B (en) | 2012-04-21 |
| EP1694914B1 (en) | 2018-05-30 |
| KR101131452B1 (ko) | 2012-04-23 |
| US20070087178A1 (en) | 2007-04-19 |
| US9194061B2 (en) | 2015-11-24 |
| CN1890432A (zh) | 2007-01-03 |
| WO2005059247A1 (en) | 2005-06-30 |
| CA2548745A1 (en) | 2005-06-30 |
| JP2007514066A (ja) | 2007-05-31 |
| HK1097014A1 (en) | 2007-06-15 |
| AU2004299598B2 (en) | 2010-03-04 |
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