BRPI0418699A - processo para a produção de ácido (met) acrìlico ou (met) acroleìna - Google Patents
processo para a produção de ácido (met) acrìlico ou (met) acroleìnaInfo
- Publication number
- BRPI0418699A BRPI0418699A BRPI0418699-0A BRPI0418699A BRPI0418699A BR PI0418699 A BRPI0418699 A BR PI0418699A BR PI0418699 A BRPI0418699 A BR PI0418699A BR PI0418699 A BRPI0418699 A BR PI0418699A
- Authority
- BR
- Brazil
- Prior art keywords
- acrolein
- meth
- acrylic acid
- met
- catalyst
- Prior art date
Links
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title abstract 10
- 238000000034 method Methods 0.000 title abstract 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 229910001882 dioxygen Inorganic materials 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 125000000393 L-methionino group Chemical group [H]OC(=O)[C@@]([H])(N([H])[*])C([H])([H])C(SC([H])([H])[H])([H])[H] 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
PROCESSO PARA A PRODUçãO DE áCIDO (MET) ACRìLICO OU (MET) ACROLEìNA A presente invenção refere-se a um processo para produzir (mat) acroleína ou ácido (met) acrílico, compreendendo a realização de reação de oxidação catalítica em fase vapor de propileno, propano, isobutileno ou met (acroleína) com a utilização de oxigênio molecular ou gás contendo oxigênio molecular na presença de um catalisador de óxido composto por meio de um reator multitubular apresentando tubos de reações múltiplas carregados com o catalisador, de forma que (met) acroleína ou ácido (met) acrílico podem ser obtidos com alto rendimento estavelmente por prolongado período de tempo sem diminuição local (desigualmente distribuído) estrema de atividade catalítica. é fornecido um processo em que, em um estágio inicial de operação, a diferença entre a temperatura do meio de aquecimento a temperatura de pico de catalisador é ajustada para 20 a 80<198> e em que durante a operação, qualquer mudança de temperatura de pico (T) de catalsador na direção de eixo de tubo é regulada de modo permanecer dentro de uma dada faixa.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004108736A JP2005289919A (ja) | 2004-04-01 | 2004-04-01 | (メタ)アクリル酸または(メタ)アクロレインの製造方法 |
| PCT/JP2004/016292 WO2005100293A1 (ja) | 2004-04-01 | 2004-10-27 | (メタ)アクリル酸または(メタ)アクロレインの製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0418699A true BRPI0418699A (pt) | 2007-06-12 |
Family
ID=35149920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0418699-0A BRPI0418699A (pt) | 2004-04-01 | 2004-10-27 | processo para a produção de ácido (met) acrìlico ou (met) acroleìna |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7563927B2 (pt) |
| JP (1) | JP2005289919A (pt) |
| CN (1) | CN100424064C (pt) |
| BR (1) | BRPI0418699A (pt) |
| RU (1) | RU2349573C2 (pt) |
| WO (1) | WO2005100293A1 (pt) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101657408B (zh) | 2007-04-03 | 2012-10-03 | Lg化学株式会社 | 使用固定床催化部分氧化反应器制备不饱和醛和/或不饱和脂肪酸的方法 |
| JP5902374B2 (ja) * | 2009-03-26 | 2016-04-13 | 株式会社日本触媒 | アクリル酸の製造方法 |
| JP5526408B2 (ja) | 2010-01-19 | 2014-06-18 | 国立大学法人東北大学 | 燃料物性決定方法及び燃料物性決定装置 |
| JP5590382B2 (ja) * | 2010-04-19 | 2014-09-17 | 三菱レイヨン株式会社 | 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法 |
| US9149799B2 (en) * | 2010-04-28 | 2015-10-06 | Basf Se | Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body |
| JP5453221B2 (ja) | 2010-11-18 | 2014-03-26 | 国立大学法人東北大学 | 燃焼実験装置 |
| CN102992980B (zh) * | 2011-09-08 | 2014-11-26 | 中国石油天然气股份有限公司 | 一种制备丙烯醛的方法 |
| CN102992977B (zh) * | 2011-09-08 | 2014-11-26 | 中国石油天然气股份有限公司 | 一种丙烯醛的制备方法 |
| US9115067B1 (en) | 2014-12-22 | 2015-08-25 | Novus International, Inc. | Process for the manufacture of acrolein |
| CN112337408B (zh) * | 2020-11-20 | 2024-10-01 | 深圳太科飞天科技有限公司 | 小型氢气和二氧化碳合成甲醇的反应装置 |
| JP7551027B2 (ja) * | 2022-10-12 | 2024-09-13 | 日本化薬株式会社 | 不飽和アルデヒドの製造方法および不飽和アルデヒドの製造装置 |
| CN119948003A (zh) * | 2022-10-12 | 2025-05-06 | 日本化药株式会社 | 不饱和醛的制造方法和不饱和醛的制造装置 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6029290B2 (ja) | 1977-07-20 | 1985-07-10 | 株式会社日本触媒 | 接触気相酸化方法 |
| DE4431957A1 (de) * | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein |
| DE19717165A1 (de) * | 1997-04-23 | 1998-10-29 | Basf Ag | Vorrichtung und Verfahren zur Temperaturmessung in Rohrreaktoren |
| JP3948837B2 (ja) | 1998-08-10 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
| WO2001042184A1 (en) | 1999-12-10 | 2001-06-14 | Mitsubishi Rayon Co., Ltd. | Method for producing methacrylic acid |
| JP3943311B2 (ja) * | 2000-05-19 | 2007-07-11 | 株式会社日本触媒 | 不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
| AU2002344613A1 (en) * | 2001-10-30 | 2003-06-10 | Mitsubishi Chemical Corporation | Method for purifying (meth)acrylic acid |
| EP1460053A4 (en) * | 2001-12-27 | 2006-03-22 | Mitsubishi Chem Corp | VAPOR CATALYST OXIDATION PROCESS AND PROCESS FOR PRODUCING (METH) ACROLEIN OR (METH) ACRYLIC ACID |
| JP4194359B2 (ja) * | 2001-12-28 | 2008-12-10 | 三菱化学株式会社 | 気相接触酸化方法 |
| JP4295462B2 (ja) * | 2002-01-11 | 2009-07-15 | 三菱化学株式会社 | 気相接触酸化方法 |
| JP2003261501A (ja) * | 2002-01-07 | 2003-09-19 | Mitsubishi Chemicals Corp | 気相接触酸化方法 |
| JP4145607B2 (ja) * | 2002-08-23 | 2008-09-03 | 三菱化学株式会社 | 多管式反応器を用いた気相接触酸化方法 |
| CN1304349C (zh) * | 2003-11-28 | 2007-03-14 | 三菱化学株式会社 | 收集(甲基)丙烯醛或(甲基)丙烯酸的方法及其收集设备 |
| JP4586381B2 (ja) * | 2004-02-27 | 2010-11-24 | 三菱化学株式会社 | (メタ)アクリル酸またはそのエステルの受入れ又は払出し方法 |
-
2004
- 2004-04-01 JP JP2004108736A patent/JP2005289919A/ja active Pending
- 2004-10-27 RU RU2006134655/04A patent/RU2349573C2/ru active
- 2004-10-27 BR BRPI0418699-0A patent/BRPI0418699A/pt not_active Application Discontinuation
- 2004-10-27 US US11/547,004 patent/US7563927B2/en not_active Expired - Lifetime
- 2004-10-27 WO PCT/JP2004/016292 patent/WO2005100293A1/ja not_active Ceased
- 2004-10-27 CN CNB2004800006286A patent/CN100424064C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2006134655A (ru) | 2008-04-10 |
| US7563927B2 (en) | 2009-07-21 |
| WO2005100293A1 (ja) | 2005-10-27 |
| US20070208201A1 (en) | 2007-09-06 |
| RU2349573C2 (ru) | 2009-03-20 |
| CN100424064C (zh) | 2008-10-08 |
| CN1697814A (zh) | 2005-11-16 |
| JP2005289919A (ja) | 2005-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O, 13, 24 E 25 DA LPI |
|
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL. |