BRPI0519615A2 - processo para a hidrogenaÇço de um reagente, e, composiÇço combustÍvel - Google Patents
processo para a hidrogenaÇço de um reagente, e, composiÇço combustÍvelInfo
- Publication number
- BRPI0519615A2 BRPI0519615A2 BRPI0519615-9A BRPI0519615A BRPI0519615A2 BR PI0519615 A2 BRPI0519615 A2 BR PI0519615A2 BR PI0519615 A BRPI0519615 A BR PI0519615A BR PI0519615 A2 BRPI0519615 A2 BR PI0519615A2
- Authority
- BR
- Brazil
- Prior art keywords
- carbon atom
- carbonyl group
- proton
- hydrogenation
- gamma
- Prior art date
Links
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 title 1
- 229910052799 carbon Inorganic materials 0.000 abstract 7
- 125000004432 carbon atom Chemical group C* 0.000 abstract 7
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002596 lactones Chemical class 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCESSO PARA A HIDROGENAÇçO DE UM REAGENTE, E, COMPOSIÇçO COMBUSTÍVEL. A invenção fornece um processo para a hidrogenação de um reagente selecionado do grupo que consiste de: (a) uma lactona de 5 ou 6 membros que é substituida no átomo de carbono de fechamento de anel e tem um próton em um átomo de carbono adjacente ao átomo de carbono de fechamento de anel; (b) um éster de um ácido carboxilico tendo um grupo gama-carbonila e um próton em um átomo de carbono adjacente ao átomo de carbono do grupo carbonila; e (c) um ácido carboxílico tendo um grupo gama-carbonila e um próton em um átomo de carbono adjacente ao átomo de carbono do grupo carbonila, em que o reagente é contactado com um catalisador heterogêneo fortemente ácido compreendendo um metal hidrogenante, na presença de hidrogênio, em uma temperatura na faixa de 100 a 350°C e uma pressão na faixa de 1 a 150 bar (absoluto). A invenção ainda fornece uma composição combustível, preferivelmente uma composição de diesel, compreendendo 4-metilnonanodioato de di-alquila ou 3-etil-4-metileptanodioato de di-alquila.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04106969 | 2004-12-23 | ||
| PCT/EP2005/057009 WO2006067171A1 (en) | 2004-12-23 | 2005-12-21 | A process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0519615A2 true BRPI0519615A2 (pt) | 2009-02-25 |
Family
ID=34930160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0519615-9A BRPI0519615A2 (pt) | 2004-12-23 | 2005-12-21 | processo para a hidrogenaÇço de um reagente, e, composiÇço combustÍvel |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8003818B2 (pt) |
| EP (1) | EP1828095B1 (pt) |
| JP (1) | JP2008525372A (pt) |
| CN (1) | CN101087749B (pt) |
| AT (1) | ATE527230T1 (pt) |
| BR (1) | BRPI0519615A2 (pt) |
| CA (1) | CA2591796C (pt) |
| MX (1) | MX2007007426A (pt) |
| WO (1) | WO2006067171A1 (pt) |
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|---|---|---|---|---|
| CN1894230A (zh) * | 2003-12-15 | 2007-01-10 | 国际壳牌研究有限公司 | 液化木素纤维素材料的方法 |
| CA2591796C (en) | 2004-12-23 | 2014-02-18 | Shell Internationale Research Maatschappij B.V. | A process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group |
| US20070034345A1 (en) * | 2005-06-15 | 2007-02-15 | Leonardus Petrus | Process for organosolv pulping and use of a gamma lactone in a solvent for organosolv pulping |
| JP2010527963A (ja) * | 2007-05-22 | 2010-08-19 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | レブリン酸のペンタン酸への転化方法 |
| DE602008005455D1 (de) * | 2007-07-12 | 2011-04-21 | Shell Int Research | Verfahren zum umwandeln von levulinsäure in pentansäure |
| ITPI20090032A1 (it) * | 2009-03-24 | 2009-06-23 | Univ Pisa | Nuovo procedimento catalitico di produzione del 5-metilbutirrolattone (gamma -valerolattone) a partire da acido levulinico o suoi esteri o direttamente da biomassa. |
| CA2759224A1 (en) * | 2009-06-05 | 2010-12-09 | Energy & Environmental Research Center Foundation | Multiproduct biorefinery for synthesis of fuel components and chemicals from lignocellulosics via levulinate condensations |
| US8148553B2 (en) * | 2009-06-23 | 2012-04-03 | Wisconsin Alumni Research Foundation | Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities |
| US8580978B2 (en) | 2009-08-07 | 2013-11-12 | Shell Oil Company | Process for preparing a hydroxyacid or hydroxyester |
| EP2462100A1 (en) | 2009-08-07 | 2012-06-13 | Shell Internationale Research Maatschappij B.V. | Process for hydrogenation |
| EP2462101B1 (en) | 2009-08-07 | 2013-07-31 | Shell Internationale Research Maatschappij B.V. | Process for preparing an ester |
| US20110112326A1 (en) * | 2009-08-07 | 2011-05-12 | Jean-Paul Lange | Process for hydrogenation |
| EP2569350A2 (en) | 2010-05-12 | 2013-03-20 | Shell Internationale Research Maatschappij B.V. | Process for liquefying a cellulosic material |
| WO2011141545A1 (en) | 2010-05-12 | 2011-11-17 | Shell Internationale Research Maatschappij B.V. | Process for liquefying a cellulosic material |
| WO2012175439A1 (en) * | 2011-06-21 | 2012-12-27 | Dsm Ip Assets B.V. | Process to produce valerolactone from levulinic acid |
| JP5785045B2 (ja) * | 2011-10-06 | 2015-09-24 | エヌ・イーケムキャット株式会社 | 選択的脱ベンジル化方法およびこれに用いる選択水素化触媒 |
| US10207960B2 (en) * | 2013-06-27 | 2019-02-19 | Wisconsin Alumni Research Foundation | Selective catalytic production of linear alpha olefins from lactones and unsaturated carboxylic acids |
| WO2015026234A1 (en) | 2013-08-20 | 2015-02-26 | Universiteit Utrecht Holding B.V. | Supported metal nanoparticle-based catalyst for the hydrogenation of a levulinic acid source |
| ES2762517T3 (es) * | 2014-03-26 | 2020-05-25 | Neste Oyj | Método para la conversión catalítica de cetoácidos e hidrotratamiento en hidrocarburos |
| PL3132005T3 (pl) | 2014-03-26 | 2022-03-28 | Neste Oyj | Sposób konwersji termicznej ketokwasów i hydrorafinacji do węglowodorów |
| CN105669456B (zh) * | 2014-11-18 | 2017-10-31 | 中国科学院兰州化学物理研究所 | 一种由乙酰丙酸制备戊酸酯的方法 |
| WO2016135542A1 (en) * | 2014-12-12 | 2016-09-01 | Eni S.P.A. | Process for the production of dipentyl ether from levulinic acid resulting from biomass |
| WO2017061865A1 (en) | 2015-10-06 | 2017-04-13 | Avantium Knowledge Centre B.V. | Process for the preparation of gamma-valerolactone |
| JP6558446B2 (ja) * | 2015-11-16 | 2019-08-14 | 宇部興産株式会社 | γ−バレロラクトンの製造方法 |
| EP3187567B1 (en) | 2015-12-29 | 2021-03-31 | Neste Oyj | Method for producing renewable middle-distillate composition, use of the composition and fuel containing the same |
| EP3187482A1 (en) | 2015-12-29 | 2017-07-05 | Neste Oyj | Renewable hydrocarbons, method for producing the same and use thereof |
| ES2845647T3 (es) * | 2016-12-30 | 2021-07-27 | Neste Oyj | Mejora de cetoácido |
| CN110117266B (zh) * | 2018-02-06 | 2022-05-31 | 中国科学院大连化学物理研究所 | 一种生物质平台化合物加氢制备生物质燃油分子的方法 |
| CN115181018B (zh) * | 2022-07-29 | 2023-10-03 | 武汉大学 | 一种利用γ-戊内酯定向合成戊酸的方法 |
| CN115448832B (zh) * | 2022-08-26 | 2023-11-21 | 武汉大学 | 一种生物质衍生物γ-戊内酯双导向转化的方法 |
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| CA2591796C (en) | 2004-12-23 | 2014-02-18 | Shell Internationale Research Maatschappij B.V. | A process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group |
| US20070034345A1 (en) | 2005-06-15 | 2007-02-15 | Leonardus Petrus | Process for organosolv pulping and use of a gamma lactone in a solvent for organosolv pulping |
-
2005
- 2005-12-21 CA CA2591796A patent/CA2591796C/en not_active Expired - Fee Related
- 2005-12-21 EP EP05826418A patent/EP1828095B1/en not_active Expired - Lifetime
- 2005-12-21 WO PCT/EP2005/057009 patent/WO2006067171A1/en not_active Ceased
- 2005-12-21 JP JP2007547507A patent/JP2008525372A/ja active Pending
- 2005-12-21 BR BRPI0519615-9A patent/BRPI0519615A2/pt not_active Application Discontinuation
- 2005-12-21 US US11/314,404 patent/US8003818B2/en not_active Expired - Fee Related
- 2005-12-21 AT AT05826418T patent/ATE527230T1/de not_active IP Right Cessation
- 2005-12-21 CN CN2005800443649A patent/CN101087749B/zh not_active Expired - Fee Related
- 2005-12-21 MX MX2007007426A patent/MX2007007426A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007007426A (es) | 2007-07-17 |
| EP1828095A1 (en) | 2007-09-05 |
| US8003818B2 (en) | 2011-08-23 |
| JP2008525372A (ja) | 2008-07-17 |
| ATE527230T1 (de) | 2011-10-15 |
| US20060162239A1 (en) | 2006-07-27 |
| CA2591796C (en) | 2014-02-18 |
| CN101087749A (zh) | 2007-12-12 |
| CA2591796A1 (en) | 2006-06-29 |
| WO2006067171A1 (en) | 2006-06-29 |
| EP1828095B1 (en) | 2011-10-05 |
| CN101087749B (zh) | 2010-06-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O, 11, 13 E 25 DA LPI |
|
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL. |