BRPI0507218A - método para controlar o fluxo de polìmero num processo de polimerização - Google Patents

método para controlar o fluxo de polìmero num processo de polimerização

Info

Publication number
BRPI0507218A
BRPI0507218A BRPI0507218-2A BRPI0507218A BRPI0507218A BR PI0507218 A BRPI0507218 A BR PI0507218A BR PI0507218 A BRPI0507218 A BR PI0507218A BR PI0507218 A BRPI0507218 A BR PI0507218A
Authority
BR
Brazil
Prior art keywords
sup
polymer
reactor
polymerization process
polymer flow
Prior art date
Application number
BRPI0507218-2A
Other languages
English (en)
Inventor
Gabriele Mei
Stefano Bertolini
Original Assignee
Basell Poliolefine Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Srl filed Critical Basell Poliolefine Srl
Publication of BRPI0507218A publication Critical patent/BRPI0507218A/pt
Publication of BRPI0507218B1 publication Critical patent/BRPI0507218B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00584—Controlling the density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/0069—Attrition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Método para controlar o fluxo de polímero num processo de polimerização. O presente invento descreve um método para controlar a fluidez de partículas poliméricas fluído para baixo numa forma densificada dentro de um reator de polimerização, em que um ou mais monómeros são polimerizados em fase gasosa na presença de um catalisador de polimerização, a densidade do sólido (kg de polímero por m¬ 3¬ de reator ocupado pelo polímero) sendo maior que 80% da "densidade aparente" do polímero, o método sendo caracterizado pelo fato que uma corrente líquida é continuamente alimentada ao reator de polimerização a uma taxa de fluxo de massa por unidade de superfície do reator maior que 30 kg/h m¬ 2¬.
BRPI0507218A 2004-03-03 2005-01-31 método para controlar o fluxo de polímero num processo de polimerização BRPI0507218B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04100856 2004-03-03
US55117904P 2004-03-08 2004-03-08
PCT/EP2005/001000 WO2005095465A1 (en) 2004-03-03 2005-01-31 Method for controlling the polymer flow in a polymerization process

Publications (2)

Publication Number Publication Date
BRPI0507218A true BRPI0507218A (pt) 2007-06-19
BRPI0507218B1 BRPI0507218B1 (pt) 2015-10-27

Family

ID=34960400

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0507218A BRPI0507218B1 (pt) 2004-03-03 2005-01-31 método para controlar o fluxo de polímero num processo de polimerização

Country Status (11)

Country Link
US (1) US7405260B2 (pt)
EP (1) EP1720913B1 (pt)
JP (1) JP4960858B2 (pt)
KR (1) KR101187244B1 (pt)
CN (1) CN100478361C (pt)
AT (1) ATE426621T1 (pt)
BR (1) BRPI0507218B1 (pt)
CA (1) CA2558097A1 (pt)
DE (1) DE602005013495D1 (pt)
RU (1) RU2380379C2 (pt)
WO (1) WO2005095465A1 (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2412207C2 (ru) * 2005-05-13 2011-02-20 Базелль Полиолефин Италия С.Р.Л. Способ газофазной полимеризации олефинов
US8198383B2 (en) * 2007-12-21 2012-06-12 Basell Poliolefine Italia, s.r.l. Process for the gas-phase polymerization of olefins
WO2010045091A2 (en) 2008-10-15 2010-04-22 Univation Technologies, Llc Circulating fluidized bed reactor
EP2516489B1 (en) 2009-12-21 2014-07-02 W.R. Grace & CO. - CONN. Gas-phase polymerization process having multiple flow regimes
JP5606144B2 (ja) * 2010-05-12 2014-10-15 出光興産株式会社 ポリオレフィンの製造方法
US9073027B2 (en) 2010-09-09 2015-07-07 Basell Poliolefine Italia S.R.L. Process and apparatus for the gas-phase polymerization of olefins
JP6466395B2 (ja) * 2013-03-14 2019-02-06 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット プロピレン／ブテンインターポリマー生成システム及び方法
EP2848635A1 (en) * 2013-09-16 2015-03-18 Ineos Europe AG Polymerization process
BR112016024633B1 (pt) 2014-05-06 2022-05-03 Basell Poliolefine Italia S.R.L. Copolímeros de propileno-etileno aleatórios, processo para a preparação dos mesmos e artigos compreendendo os mesmos
EP3535303B1 (en) * 2016-11-04 2023-10-04 Basell Poliolefine Italia S.r.l. Process for the polymerization of olefins
AR112897A1 (es) 2017-09-21 2019-12-26 Basell Poliolefine Italia Srl Proceso para la polimerización de olefinas en fase gaseosa
EP4225486B1 (en) * 2020-12-09 2025-07-30 Basell Polyolefine GmbH Reactor for a gas-phase olefin polymerization

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0574821B1 (en) * 1992-06-18 1998-03-11 Montell Technology Company bv Process and apparatus for the gas-phase polymerization of olefins
JP3315746B2 (ja) * 1993-02-03 2002-08-19 三井化学株式会社 オレフィンの重合方法
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
EP0824116A1 (en) * 1996-08-13 1998-02-18 Bp Chemicals S.N.C. Polymerisation process
FI981034A7 (fi) * 1998-05-08 1999-11-09 Borealis Polymers Oy HD-polyeteenikoostumukset ja menetelmä niiden valmistamiseksi
CN1137142C (zh) * 1998-07-08 2004-02-04 蒙特尔技术有限公司 气相聚合的方法和设备
DE69920954T2 (de) * 1998-11-30 2005-02-03 Bp Chemicals Ltd. Verfahren zur polymerisationskontrolle
US6306981B1 (en) * 1999-04-02 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization process
ES2259952T3 (es) * 2000-04-13 2006-11-01 Borealis Technology Oy Compuesto de polimero de hdpe.
JP2002121201A (ja) 2000-10-19 2002-04-23 Japan Polychem Corp α−オレフィンの重合方法
ATE347569T1 (de) * 2003-08-20 2006-12-15 Basell Poliolefine Srl Verfahren und vorrichtung zur polymerisation von ethylen
JP4843188B2 (ja) * 2003-09-11 2011-12-21 株式会社プライムポリマー ポリオレフィンの製造方法及び気相重合装置

Also Published As

Publication number Publication date
EP1720913A1 (en) 2006-11-15
BRPI0507218B1 (pt) 2015-10-27
KR20070003899A (ko) 2007-01-05
KR101187244B1 (ko) 2012-10-02
WO2005095465A1 (en) 2005-10-13
JP2007526372A (ja) 2007-09-13
RU2380379C2 (ru) 2010-01-27
JP4960858B2 (ja) 2012-06-27
CN1926158A (zh) 2007-03-07
US20080058484A1 (en) 2008-03-06
EP1720913B1 (en) 2009-03-25
US7405260B2 (en) 2008-07-29
CA2558097A1 (en) 2005-10-13
CN100478361C (zh) 2009-04-15
RU2006134738A (ru) 2008-04-10
DE602005013495D1 (de) 2009-05-07
ATE426621T1 (de) 2009-04-15

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 27/10/2015, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 21A ANUIDADE.