BRPI0510300A - composto, composição contendo poliolefina, método de provisão da mesma, artigo de poliolefina, acetal de um alditol substituìdo e seu método de fabricação - Google Patents
composto, composição contendo poliolefina, método de provisão da mesma, artigo de poliolefina, acetal de um alditol substituìdo e seu método de fabricaçãoInfo
- Publication number
- BRPI0510300A BRPI0510300A BRPI0510300-2A BRPI0510300A BRPI0510300A BR PI0510300 A BRPI0510300 A BR PI0510300A BR PI0510300 A BRPI0510300 A BR PI0510300A BR PI0510300 A BRPI0510300 A BR PI0510300A
- Authority
- BR
- Brazil
- Prior art keywords
- polyolefin
- compound
- acetal
- provision
- manufacture
- Prior art date
Links
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 2
- 229920000098 polyolefin Polymers 0.000 title 2
- -1 alditol acetal Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920001223 polyethylene glycol Polymers 0.000 title 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000008395 clarifying agent Substances 0.000 abstract 1
- 239000003349 gelling agent Substances 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000002667 nucleating agent Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920005606 polypropylene copolymer Polymers 0.000 abstract 1
- 230000008719 thickening Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/26—Hexahydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D321/00—Heterocyclic compounds containing rings having two oxygen atoms as the only ring hetero atoms, not provided for by groups C07D317/00 - C07D319/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
- C08K5/1575—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Abstract
COMPOSTO, COMPOSIçãO CONTENDO POLUOLEFINA, MéTODO DE PROVISãO DA MESMA, ARTIGO DE POLIOLEFINA, ACETAL DE UM ALDITOL SUBSTITUìDO E SEU MéTODO DE FABRICAçãO. A presente invenção refere-se a uma composição baseada em acetal útil como um agente de nucleação, geleificação, espessamento ou clarificação é descrita. A composição pode ser sintetizada ou provida em muitas formas diferentes, incluindo diacetais multicarbono formados de carboidratos. Uma vez sintetizado, o composto pode ser empregado como um aditivo em uma composição plástica, tal como (por exemplo) um copolímero de polipropileno. Co-aditivos podem ser também empregados. Várias estruturas arila podem residir na estrutura principal da cadeia hidrocarbono. Uma estrutura de tal composição baseada em acetal é um sorbitol modificado com um ou mais grupos arila e pelo menos um grupo substituído em um carbono terminal na cadeia.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/831,920 US7262236B2 (en) | 2004-04-26 | 2004-04-26 | Acetal-based compositions |
| US10/893,633 US7157510B2 (en) | 2004-04-26 | 2004-07-16 | Method of nucleating a polyolefin composition with acetal-based compounds |
| PCT/US2005/011686 WO2005111134A2 (en) | 2004-04-26 | 2005-04-05 | Method of nucleating a polyolefin composition with acetal-based compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0510300A true BRPI0510300A (pt) | 2007-10-02 |
| BRPI0510300B1 BRPI0510300B1 (pt) | 2016-01-26 |
Family
ID=35137358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0510300A BRPI0510300B1 (pt) | 2004-04-26 | 2005-04-05 | composto, composição contendo poliolefina, método de provisão da mesma e artigo de poliolefina |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7262236B2 (pt) |
| EP (2) | EP1740653B1 (pt) |
| JP (1) | JP4939402B2 (pt) |
| KR (1) | KR101154076B1 (pt) |
| CN (2) | CN1984949B (pt) |
| AT (1) | ATE478077T1 (pt) |
| BR (1) | BRPI0510300B1 (pt) |
| DE (1) | DE602005023000D1 (pt) |
| RU (1) | RU2348637C2 (pt) |
| WO (2) | WO2005108479A2 (pt) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7888454B2 (en) * | 2004-04-26 | 2011-02-15 | Milliken & Company | Substituted alditol compounds, compositions, and methods |
| US20060079720A1 (en) * | 2004-10-13 | 2006-04-13 | Milliken & Company | Method for preparing acetal-containing compositions |
| US8022133B2 (en) * | 2005-01-28 | 2011-09-20 | Milliken & Company | Co-additive compositions and methods for applying co-additive compositions into nucleated polymer compounds |
| US20080038500A1 (en) * | 2006-02-16 | 2008-02-14 | Page Richard D | Stretch-blow molded polypropylene article |
| US7662978B2 (en) * | 2006-04-24 | 2010-02-16 | Milliken & Company | Dibenzylidene sorbitol (DBS)-based compounds, compositions and methods for using such compounds |
| JP4872477B2 (ja) * | 2006-06-16 | 2012-02-08 | マツダ株式会社 | 熱可塑性エラストマー組成物及びその成形部材 |
| JP5433196B2 (ja) * | 2007-10-12 | 2014-03-05 | 日本ポリプロ株式会社 | 医療用ポリプロピレン系樹脂組成物及び成形品 |
| JP2009120797A (ja) * | 2007-10-24 | 2009-06-04 | Japan Polypropylene Corp | 押出しシートおよびそれからなる包装製品 |
| JP2010024428A (ja) * | 2007-10-24 | 2010-02-04 | Japan Polypropylene Corp | ポリプロピレン系包装用フィルム |
| BRPI0818130A2 (pt) * | 2007-10-30 | 2015-07-14 | Milliken & Co | Composição aditiva e composições termoplásticas compreendendo a mesma |
| WO2009139350A1 (ja) * | 2008-05-16 | 2009-11-19 | 株式会社Adeka | ポリオレフィン系樹脂組成物 |
| RU2515981C2 (ru) * | 2008-08-05 | 2014-05-20 | Бриджстоун Корпорейшн | Способ улучшения сопротивления хладотекучести полимеров |
| JP5426120B2 (ja) * | 2008-08-06 | 2014-02-26 | 南海化学株式会社 | ジベンジリデンアルジトール類の製造方法 |
| JP5191469B2 (ja) * | 2008-10-24 | 2013-05-08 | 日本ポリプロ株式会社 | 医療用プロピレン系樹脂組成物およびその成形品 |
| JP5183556B2 (ja) * | 2009-04-10 | 2013-04-17 | 日本ポリプロ株式会社 | プロピレン系樹脂組成物および成形品 |
| JP5183561B2 (ja) * | 2009-04-24 | 2013-04-17 | 日本ポリプロ株式会社 | プロピレン系成形品 |
| JP2010254874A (ja) * | 2009-04-28 | 2010-11-11 | Japan Polypropylene Corp | プロピレン系樹脂組成物およびそれを用いた照明カバー |
| CN102449059B (zh) * | 2009-05-29 | 2014-11-05 | 美利肯公司 | 聚合物组合物、由该组合物制造的制品及模制该组合物的方法 |
| JP2011063781A (ja) * | 2009-09-18 | 2011-03-31 | Japan Polypropylene Corp | 押出しシートおよびそれを用いた成形体 |
| JP5522777B2 (ja) * | 2009-10-14 | 2014-06-18 | 日本ポリプロ株式会社 | 防曇性プロピレン系樹脂シート |
| US8779045B2 (en) * | 2009-10-15 | 2014-07-15 | Milliken & Company | Thermoplastic polymer composition |
| US8198351B2 (en) * | 2009-10-21 | 2012-06-12 | Milliken & Company | Thermoplastic polymer composition |
| JP5590907B2 (ja) * | 2010-02-09 | 2014-09-17 | 三井化学株式会社 | ポリプロピレン樹脂組成物とこれからなる成形体 |
| HUE034073T2 (hu) | 2011-08-04 | 2018-01-29 | Prysmian Spa | Energiakábel termoplasztikus elektromosan szigetelõ réteggel |
| EP2935433B1 (en) | 2012-12-21 | 2019-09-18 | Milliken & Company | Additive composition and process for using the same |
| JP6466396B2 (ja) | 2013-03-15 | 2019-02-06 | アルベマール・コーポレーシヨン | パラプロピルベンズアルデヒドの生成 |
| US9193845B2 (en) | 2013-09-23 | 2015-11-24 | Milliken & Company | Thermoplastic polymer composition |
| US9200142B2 (en) | 2013-09-23 | 2015-12-01 | Milliken & Company | Thermoplastic polymer composition |
| US9580575B2 (en) | 2013-09-23 | 2017-02-28 | Milliken & Company | Polyethylene articles |
| US9200144B2 (en) | 2013-09-23 | 2015-12-01 | Milliken & Company | Thermoplastic polymer composition |
| US9120914B2 (en) | 2013-09-23 | 2015-09-01 | Milliken & Company | Thermoplastic polymer composition |
| CN103497198B (zh) * | 2013-10-11 | 2015-09-30 | 山西大学 | 1,3-2,4-二(对甲基)亚苄基-1-烯丙基山梨醇的制备方法 |
| JP5837156B2 (ja) * | 2014-07-29 | 2015-12-24 | 三井化学株式会社 | ポリプロピレン樹脂組成物とこれからなる成形体 |
| CN104496961B (zh) * | 2014-12-10 | 2016-08-24 | 天津大学 | 缩醛取代的葡萄糖酸酯及制备方法及用途 |
| TWI633143B (zh) | 2014-12-31 | 2018-08-21 | 美力肯及公司 | 聚烯烴組成物及其製備方法 |
| KR101953505B1 (ko) | 2015-03-31 | 2019-02-28 | 가부시키가이샤 프라임 폴리머 | 필름 콘덴서용 폴리프로필렌, 필름 콘덴서용 이축 연신 필름, 필름 콘덴서 및 이들의 제조 방법 |
| US10450440B2 (en) | 2015-12-31 | 2019-10-22 | Milliken & Company | Clarifying agent composition and polyolefin composition comprising the same |
| EP3397450B1 (en) | 2015-12-31 | 2021-05-26 | Milliken & Company | Method for molding a polymer composition |
| JP6657405B2 (ja) | 2015-12-31 | 2020-03-04 | ミリケン・アンド・カンパニーMilliken & Company | ポリオレフィン組成物 |
| CN108291051B (zh) | 2015-12-31 | 2021-03-30 | 美利肯公司 | 聚烯烃组合物 |
| JP2019518834A (ja) | 2016-05-31 | 2019-07-04 | ミリケン・アンド・カンパニーMilliken & Company | ポリマー組成物、そのような組成物から製造された物品、およびそのような組成物を成形するための方法 |
| BR112019000438B1 (pt) * | 2016-09-05 | 2022-01-18 | Gch Technology Co., Ltd | Composição do nucleador compreendendo acetato de sorbitol, diacetato de sorbitol e tiracetal de sorbitol, seu uso, método para a preparação da mesma, composição de polímero e método de preparação de um polímero aperfeiçoado |
| CN110072932B (zh) | 2016-12-21 | 2022-01-25 | 美利肯公司 | 添加剂组合物及其使用方法 |
| BR112020008996B1 (pt) * | 2017-11-09 | 2023-11-28 | Milliken & Company | Composição aditiva e composições poliméricas compreendendo a mesma |
| EP3543286A1 (en) | 2018-03-22 | 2019-09-25 | Clariant International Ltd | Polymer composition comprising diacetal derivatives |
| EP3543244A1 (en) | 2018-03-22 | 2019-09-25 | Clariant International Ltd | Diacetal derivatives and their use as clarifier |
| WO2019189431A1 (ja) | 2018-03-27 | 2019-10-03 | 日油株式会社 | マルチアーム型ポリエチレングリコール誘導体の製造方法 |
| WO2019240896A1 (en) * | 2018-06-15 | 2019-12-19 | Exxonmobil Chemical Patents Inc. | Process for producing polymers |
| CN109060999A (zh) * | 2018-09-13 | 2018-12-21 | 淄博润源化工有限公司 | 山梨醇缩醛成核剂含量的测定方法 |
| US11834558B2 (en) | 2018-12-21 | 2023-12-05 | Milliken & Company | Additive compositions and thermoplastic polymer compositions comprising the same |
| TWI839561B (zh) | 2019-10-15 | 2024-04-21 | 美商美力肯及公司 | 用於製造聚合物組成物的方法以及適合使用於該方法中的組成物 |
| CN111635558B (zh) * | 2020-06-15 | 2022-03-22 | 南京淳达科技发展有限公司 | 一种具有成核作用的聚丙烯复合助剂及其制备方法 |
| CN116390986A (zh) | 2020-10-15 | 2023-07-04 | 美利肯公司 | 聚合物组合物及其制备方法 |
| US11148131B1 (en) | 2021-04-16 | 2021-10-19 | APC Packaging, LLC. | Dropper |
| CA3214026A1 (en) | 2021-04-22 | 2022-10-27 | Darin Dotson | Polypropylene polymer compositions and articles made from the same |
| JP2024514697A (ja) | 2021-04-22 | 2024-04-02 | ミリケン・アンド・カンパニー | ポリエチレンポリマー組成物およびそれから作製された物品 |
| CN114835949B (zh) * | 2022-06-06 | 2023-12-12 | 中海油天津化工研究设计院有限公司 | 一种基于葡萄糖缩醛衍生物的聚丙烯复合成核剂 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US597043A (en) * | 1898-01-11 | Ratchet-wrench | ||
| JPS5122740A (pt) | 1974-08-16 | 1976-02-23 | Kenzo Hamada | |
| JPS5630449A (en) | 1979-08-21 | 1981-03-27 | Mitsui Toatsu Chem Inc | Polypropylene composition |
| US4371645A (en) | 1980-04-24 | 1983-02-01 | Milliken Research Corporation | Polyolefin plastic compositions comprising meta- or papa-derivatives (choro- or bromo-) of di-benzyuidene sorbitol |
| FR2613713B1 (fr) * | 1987-04-07 | 1989-08-04 | Roquette Freres | Procede de preparation de diacetals d'alditols, notamment du dibenzylidene-sorbitol, en milieu aqueux |
| JPH089679B2 (ja) | 1988-09-16 | 1996-01-31 | 新日本理化株式会社 | 樹脂改質用ジアセタール組成物及び結晶性樹脂組成物 |
| US5049605A (en) * | 1989-09-20 | 1991-09-17 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| US5106999A (en) * | 1990-06-26 | 1992-04-21 | The Procter & Gamble Company | Process for preparing dibenzylidene-d-sorbitol compounds |
| KR0170000B1 (ko) | 1990-06-29 | 1999-02-01 | 레나토 스가르비 | 순수한 결정 형태의 리파펜틴 |
| JPH05117435A (ja) * | 1991-10-24 | 1993-05-14 | Sekisui Chem Co Ltd | 発泡性塩化ビニル系樹脂組成物 |
| US5198484A (en) * | 1992-05-01 | 1993-03-30 | Milliken Research Corporation | Polyolefin composition containing ultrafine sorbitol and xylitol acetals |
| US5470898A (en) * | 1993-06-30 | 1995-11-28 | Montell North America Inc. | Sorbitol derivatives as nucleators and clarifiers for polyolefins, and polyolefin compositions obtained therewith |
| JP3067972B2 (ja) * | 1995-03-03 | 2000-07-24 | 新日本理化株式会社 | ジアセタールの六方晶結晶、該六方晶結晶を含む核剤、該六方晶結晶を含むポリオレフィン系樹脂組成物及び成形物、並びに該組成物の成形方法 |
| DE69726309T2 (de) * | 1996-11-28 | 2004-09-16 | New Japan Chemical Co., Ltd. | Zuckerderivate, geliermittel, geliermittelzubereitungen, verfahren zu ihrer herstellung und gelzubereitungen |
| KR100511244B1 (ko) * | 1997-01-17 | 2005-08-31 | 신닛폰 리카 가부시키가이샤 | 폴리올레핀 수지중에서의 디아세탈의 재결정화 방법 |
| US5973043A (en) * | 1997-11-26 | 1999-10-26 | Milliken & Company | Carbamoyl substituted acetals and compositions containing the same |
| EP1313741B1 (en) * | 2000-09-01 | 2007-05-23 | Milliken & Company | Fluorinated and alkylated alditol derivatives and polyolefin articles containing same |
| US6500964B2 (en) * | 2001-03-23 | 2002-12-31 | Milliken & Company | Method of producing high yield alditol acetals with mineral acids and surfactants |
| US20060079720A1 (en) * | 2004-10-13 | 2006-04-13 | Milliken & Company | Method for preparing acetal-containing compositions |
| US8022133B2 (en) * | 2005-01-28 | 2011-09-20 | Milliken & Company | Co-additive compositions and methods for applying co-additive compositions into nucleated polymer compounds |
-
2004
- 2004-04-26 US US10/831,920 patent/US7262236B2/en not_active Expired - Lifetime
- 2004-07-16 US US10/893,633 patent/US7157510B2/en not_active Expired - Lifetime
-
2005
- 2005-04-05 CN CN2005800132974A patent/CN1984949B/zh not_active Expired - Lifetime
- 2005-04-05 BR BRPI0510300A patent/BRPI0510300B1/pt active IP Right Grant
- 2005-04-05 WO PCT/US2005/011685 patent/WO2005108479A2/en not_active Ceased
- 2005-04-05 EP EP05778280A patent/EP1740653B1/en not_active Expired - Lifetime
- 2005-04-05 DE DE602005023000T patent/DE602005023000D1/de not_active Expired - Lifetime
- 2005-04-05 RU RU2006141650/04A patent/RU2348637C2/ru active
- 2005-04-05 WO PCT/US2005/011686 patent/WO2005111134A2/en not_active Ceased
- 2005-04-05 AT AT05778280T patent/ATE478077T1/de not_active IP Right Cessation
- 2005-04-05 EP EP10158625.3A patent/EP2199290B1/en not_active Expired - Lifetime
- 2005-04-05 CN CN201110411219.7A patent/CN102532640B/zh not_active Expired - Lifetime
- 2005-04-05 JP JP2007510753A patent/JP4939402B2/ja not_active Expired - Lifetime
- 2005-04-05 KR KR1020067022196A patent/KR101154076B1/ko not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007534827A (ja) | 2007-11-29 |
| CN1984949B (zh) | 2012-01-04 |
| KR20070017365A (ko) | 2007-02-09 |
| EP2199290A3 (en) | 2011-03-09 |
| ATE478077T1 (de) | 2010-09-15 |
| CN102532640B (zh) | 2014-11-26 |
| JP4939402B2 (ja) | 2012-05-23 |
| US7262236B2 (en) | 2007-08-28 |
| US20050239926A1 (en) | 2005-10-27 |
| RU2348637C2 (ru) | 2009-03-10 |
| BRPI0510300B1 (pt) | 2016-01-26 |
| WO2005111134A3 (en) | 2007-02-22 |
| KR101154076B1 (ko) | 2012-06-11 |
| EP1740653A4 (en) | 2007-07-04 |
| EP1740653A2 (en) | 2007-01-10 |
| CN102532640A (zh) | 2012-07-04 |
| EP1740653B1 (en) | 2010-08-18 |
| WO2005111134A2 (en) | 2005-11-24 |
| EP2199290A2 (en) | 2010-06-23 |
| US7157510B2 (en) | 2007-01-02 |
| US20050239928A1 (en) | 2005-10-27 |
| WO2005108479A2 (en) | 2005-11-17 |
| CN1984949A (zh) | 2007-06-20 |
| WO2005108479A3 (en) | 2006-12-14 |
| RU2006141650A (ru) | 2008-06-10 |
| DE602005023000D1 (de) | 2010-09-30 |
| EP2199290B1 (en) | 2018-06-06 |
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