BRPI0511027A - ligantes de cicloolefina fosfina e seu uso em catálise - Google Patents

ligantes de cicloolefina fosfina e seu uso em catálise

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Publication number
BRPI0511027A
BRPI0511027A BRPI0511027-0A BRPI0511027A BRPI0511027A BR PI0511027 A BRPI0511027 A BR PI0511027A BR PI0511027 A BRPI0511027 A BR PI0511027A BR PI0511027 A BRPI0511027 A BR PI0511027A
Authority
BR
Brazil
Prior art keywords
catalysis
cyclolefin
phosphine ligands
phosphine
cycloolephine
Prior art date
Application number
BRPI0511027-0A
Other languages
English (en)
Inventor
Renat Kadyrov
Juan Jose Almena Perea
Axel Monsees
Thomas Riermeier
Ilias Z Ilaldinov
Original Assignee
Degussa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa filed Critical Degussa
Publication of BRPI0511027A publication Critical patent/BRPI0511027A/pt

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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/655345—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a five-membered ring
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
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    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
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    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

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Abstract

LIGANTES DE CICLOOLEFINA FOSFINA E SEU USO EM CATáLISE. A presente invenção refere-se a ligantes P contendo N opcionalmente bidentados da fórmula geral (I) compreendendo um sistema de dois anéis e processos para sua sintetização, complexos de metal de transição desses compostos e seu uso como catalisadores.
BRPI0511027-0A 2004-05-11 2005-04-14 ligantes de cicloolefina fosfina e seu uso em catálise BRPI0511027A (pt)

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EP1595888A1 (en) * 2004-05-11 2005-11-16 Degussa AG Cycloolefin phosphine ligands and their use in catalysis
DE102005030400A1 (de) * 2005-06-27 2006-12-28 Archimica Gmbh Verfahren zur Herstellung von Arylaminen, Arylethern und Arylthioethern
RU2476422C2 (ru) * 2008-04-17 2013-02-27 Юнайтед Фосфорус Лимитед Гидрирование иминов
FR2984319B1 (fr) * 2011-12-20 2013-12-27 Servier Lab Nouveau procede de synthese de l'ivabradine et de ses sels d'addition a un acide pharmaceutiquement acceptable
JP2015063511A (ja) * 2013-08-30 2015-04-09 高砂香料工業株式会社 リン化合物及びその遷移金属錯体
TWI688609B (zh) 2014-11-13 2020-03-21 美商道康寧公司 含硫聚有機矽氧烷組成物及相關態樣
EP3202758A1 (de) 2016-02-03 2017-08-09 Evonik Degussa GmbH Reduktive alkylierung von aminen mit orthocarbonsäureestern
CN109021013B (zh) * 2017-06-08 2020-05-12 中国科学技术大学 杂环芳烃取代的膦磺酸钯和镍催化剂及其配体、制备方法和用途
RU2020133186A (ru) * 2018-03-09 2022-04-12 Ппг Индастриз Огайо, Инк. Составы для координирования с металлом, композиции, содержащие такие составы, и способы катализирования реакций
JP7337174B2 (ja) 2018-09-18 2023-09-01 ニカング セラピューティクス， インコーポレイテッド Ｓｒｃホモロジー－２ホスファターゼ阻害剤としての三置換ヘテロアリール誘導体
CN113135955B (zh) * 2020-01-17 2023-03-14 西湖大学 一种新型光学纯Trost配体及其制备方法
CN111440213B (zh) * 2020-04-07 2022-10-25 西安近代化学研究所 一种过渡金属催化芳香硝基c-no2转化为c-p键方法
CN114436831A (zh) * 2020-11-02 2022-05-06 中国科学院大连化学物理研究所 一种手性1-乙酸苯丙酯类化合物的合成方法
CN115368411B (zh) * 2021-05-19 2024-06-11 北京服装学院 锌配合物及其制备方法
CN115722267B (zh) * 2021-08-25 2024-02-02 万华化学集团股份有限公司 一种氢甲酰化反应催化剂及其催化丙烯氢甲酰化反应制备醛的方法
CN115785155B (zh) * 2021-09-09 2025-05-27 凯特立斯（深圳）科技有限公司 一种新型二吲哚配体化合物及其合成方法与应用

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TR199802588T2 (xx) * 1996-06-14 2000-12-21 The Penn State Research Foundation Siklik kiral fosfin ligandlar�yla ge�i� metali komplekslerinin katalizledi�i asimetrik sentez.
IT1286497B1 (it) * 1996-11-20 1998-07-15 Italfarmaco Sud Spa Difosfine di tipo misto eteroariliche-ariliche come leganti chirali, relativi complessi con metalli di transizione e impiego di detti
IT1299068B1 (it) * 1998-04-10 2000-02-07 Chemi Spa Legandi fosforati chirali e loro complessi organometallici, utili come catalizzatori in sintesi stereoselettive
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IL179121A0 (en) 2007-03-08
CA2559242A1 (en) 2005-11-17
EP1745058A1 (en) 2007-01-24
US20080306264A1 (en) 2008-12-11
US7763739B2 (en) 2010-07-27
JP2007537171A (ja) 2007-12-20
CN1946730A (zh) 2007-04-11
KR20070007923A (ko) 2007-01-16
RU2006143603A (ru) 2008-06-20
WO2005108407A1 (en) 2005-11-17
EP1595888A1 (en) 2005-11-16

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