BRPI0513108A - processo para produzir polìmeros de buteno-1 fracionáveis - Google Patents

processo para produzir polìmeros de buteno-1 fracionáveis

Info

Publication number
BRPI0513108A
BRPI0513108A BRPI0513108-1A BRPI0513108A BRPI0513108A BR PI0513108 A BRPI0513108 A BR PI0513108A BR PI0513108 A BRPI0513108 A BR PI0513108A BR PI0513108 A BRPI0513108 A BR PI0513108A
Authority
BR
Brazil
Prior art keywords
different
same
butene
hydrocarbon radicals
formula
Prior art date
Application number
BRPI0513108-1A
Other languages
English (en)
Inventor
Maria Silvia Tonti
Luigi Resconi
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BRPI0513108A publication Critical patent/BRPI0513108A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Processo para produzir polímeros de buteno-1 fracionáveis. O presente invento descreve um processo para produzir um polímero de buteno-1 compreendendo a etapa de polimerizar buteno-1 na presença de um sistema catalítico obtenível ao contatar:a) pelo menos um composto metaloceno de fórmula (Ia) na forma meso ou similar a meso, em que M é um átomo de um metal de transição, p é um inteiro de 0 a 3, X, iguais ou diferentes, são átomos de hidrogênio, átomos de halogênio ou grupos hidrocarboneto, L é um radical hidrocarboneto divalente C~1~ - C~40~, R¬ 1¬ e R¬ 2¬, iguais ou diferentes entre si, são radicais hidrocarboneto C~1~ - C~40~; T, iguais ou diferentes, são uma porção de fórmula (IIa), (IIb) ou (IIc), em que R¬3¬ e R¬5 ¬ são radicais hidrocarboneto C~1~ - C~ 40~; R¬ 4¬ e ¬R¬ 6¬, iguais ou diferentes entre si, são átomos de hidrogênio ou radicais hidrocarboneto C~1~ - C~ 40~ R¬ 7¬ e R¬ 8¬, iguais ou diferentes entre si, são átomos de hidrogênio ou radicais hidrocarboneto C~ 1~ - C~ 40~; b) pelo menos um composto metaloceno de fórmula (Ib) na forma racêmica ou similar a racêmica; c) um composto alumoxano ou um composto capaz de formar um cátion alquilmetaloceno.
BRPI0513108-1A 2004-07-22 2005-06-10 processo para produzir polìmeros de buteno-1 fracionáveis BRPI0513108A (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP04103525 2004-07-22
US59234604P 2004-07-28 2004-07-28
EP05100415 2005-01-24
US65218405P 2005-02-10 2005-02-10
PCT/EP2005/052690 WO2006008212A1 (en) 2004-07-22 2005-06-10 Process for producing fractionable 1-butene polymers

Publications (1)

Publication Number Publication Date
BRPI0513108A true BRPI0513108A (pt) 2008-04-29

Family

ID=34971113

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0513108-1A BRPI0513108A (pt) 2004-07-22 2005-06-10 processo para produzir polìmeros de buteno-1 fracionáveis

Country Status (8)

Country Link
US (1) US7776978B2 (pt)
EP (1) EP1769009A1 (pt)
JP (1) JP2008506825A (pt)
KR (1) KR20070043798A (pt)
AU (1) AU2005263671A1 (pt)
BR (1) BRPI0513108A (pt)
CA (1) CA2573984A1 (pt)
WO (1) WO2006008212A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8178636B2 (en) * 2004-05-04 2012-05-15 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
PL1769030T3 (pl) 2004-07-22 2008-08-29 Basell Polyolefine Gmbh Kompozycja polimerów 1-butenu
EP2057226B1 (en) * 2006-08-30 2009-12-09 Basell Polyolefine GmbH 1-butene propylene copolymer compositions
JP5580589B2 (ja) * 2006-08-30 2014-08-27 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンプロピレンコポリマー組成物
DE102008005949A1 (de) * 2008-01-24 2009-07-30 Evonik Degussa Gmbh Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung
US9346998B2 (en) 2009-04-23 2016-05-24 The University Of Chicago Materials and methods for the preparation of nanocomposites
WO2013183600A1 (ja) * 2012-06-04 2013-12-12 出光興産株式会社 粘接着剤組成物及びこれを用いた粘着テープ
US9505958B2 (en) 2012-09-14 2016-11-29 Mitsui Chemicals, Inc. 1-butene α-olefin copolymer composition
US9458257B2 (en) 2012-09-25 2016-10-04 Mitsui Chemicals, Inc. Process for producing olefin polymer and olefin polymer
JP2020529504A (ja) * 2017-08-04 2020-10-08 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 高い溶融流量を有するブテン−１重合体組成物
RU2713805C1 (ru) * 2019-06-26 2020-02-07 Федеральное государственное бюджетное учреждение "Научный центр экспертизы средств медицинского применения" Министерства здравоохранения Российской Федерации (ФГБУ "НЦЭСМП" Минздрава России) Способ одновременного определения степеней окисления и алкилирования азоксимера бромида - действующего вещества полиоксидония - методом 13C спектроскопии ЯМР
JPWO2022270629A1 (pt) * 2021-06-25 2022-12-29
WO2022270625A1 (ja) * 2021-06-25 2022-12-29 サンアロマー株式会社 ポリプロピレン系樹脂組成物及びその製造方法、並びにフィルム成形体、食品に接する包装体、食品に接する容器及びレトルト用パウチ
US20240239942A1 (en) * 2021-06-25 2024-07-18 Basell Poliolefine Italia S.R.L. Polypropylene resin composition, method for producing same, sheet molded body and container

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1915061B2 (de) 1969-03-25 1972-03-23 Chemische Werke Hüls AG, 4370 Mari Leitfaehige kunststoffmasse fuer den kabelsektor
DE2254128C3 (de) 1972-11-04 1975-08-14 Chemische Werke Huels Ag, 4370 Marl Thermoplastische Formmasse aus Polybuten-I
US4298722A (en) 1980-03-11 1981-11-03 E. I. Du Pont De Nemours And Company Fractionable, elastomeric poly (1-butene)
ATE38044T1 (de) 1984-08-30 1988-11-15 Mitsui Petrochemical Ind Buten-1-polymer und seine verwendung.
PL286365A1 (en) 1989-08-03 1991-04-22 Exxon Chemical Patents Inc Method of polymerizing especially ethylene any polymerization catalyst and method of obtaining same
EP0672689A1 (en) 1990-06-22 1995-09-20 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
ATE177436T1 (de) 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
IT1256259B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
ES2182950T3 (es) * 1995-05-16 2003-03-16 Univation Tech Llc Produccion de polietileno utilizando metalocenos estereosomericos.
KR20000068602A (ko) 1997-07-22 2000-11-25 나까니시 히로유끼 에틸렌/α-올레핀 공중합체, 그 조성물 및, 공중합체 및 조성물
DE59807129D1 (de) * 1997-07-28 2003-03-13 Basell Polyolefine Gmbh Verfahren zur herstellung von metallocenen
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
KR19990067851A (ko) 1998-01-14 1999-08-25 고오사이 아끼오 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법
DE19806918A1 (de) * 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
RU2219190C2 (ru) 1998-03-05 2003-12-20 Монтелл Текнолоджи Компани Б.В. (со)полимеры полибутена-1 и способ их получения
DE59914158D1 (de) * 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
US6900343B1 (en) 1998-11-25 2005-05-31 Basell Polyolefine Gmbh Method for the purification of metallocenes
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
ES2220725T3 (es) 2000-02-24 2004-12-16 Basell Polyolefine Gmbh Compuesto organometalico utilizable como c-catalizador para polimerizar olefinas.
DE60112307T8 (de) * 2000-06-30 2007-02-15 Exxonmobil Chemical Patents Inc., Baytown Metallocenverbindungen mit einem verbrückten 4-phenylindenyl-ligandsystem zur polymerisation von olefinen
US6662428B2 (en) * 2000-07-31 2003-12-16 Fuji Photo Film Co., Ltd. System for manufacturing film case
US20020123538A1 (en) 2000-12-29 2002-09-05 Peiguang Zhou Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding
US7459511B2 (en) * 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
ATE444975T1 (de) 2001-06-12 2009-10-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von buten-1
ATE315559T1 (de) 2001-08-01 2006-02-15 Basell Polyolefine Gmbh Verfahren zur herstellung von heterocyclischen pentalen derivaten
EP1448578B1 (en) 2001-11-30 2006-07-26 Basell Polyolefine GmbH Metallocene compounds and process for the preparation of propylene polymers
EP1507806B1 (en) 2002-05-29 2006-10-11 Basell Poliolefine Italia S.r.l. Butene-1 (co)polymers and process for their preparation
KR101021829B1 (ko) 2002-12-04 2011-03-17 바젤 폴리올레핀 게엠베하 1-부텐 공중합체 및 이들의 제조 방법
US7390862B2 (en) 2003-05-12 2008-06-24 Basell Polyolefine Gmbh Process for polymerizing 1-butene
JP2007505947A (ja) 2003-05-28 2007-03-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 特定の置換パターンを有する有機遷移金属化合物、ビスシクロペンタジエニル配位子組成物、触媒組成物、及ポリオレフィンの製造法
DE10324541A1 (de) 2003-05-28 2004-12-16 Basell Polyolefine Gmbh Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
KR20070004712A (ko) 2004-03-12 2007-01-09 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매 시스템
US8178636B2 (en) 2004-05-04 2012-05-15 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
PL1769030T3 (pl) 2004-07-22 2008-08-29 Basell Polyolefine Gmbh Kompozycja polimerów 1-butenu

Also Published As

Publication number Publication date
AU2005263671A1 (en) 2006-01-26
CA2573984A1 (en) 2006-01-26
US7776978B2 (en) 2010-08-17
EP1769009A1 (en) 2007-04-04
KR20070043798A (ko) 2007-04-25
US20080027190A1 (en) 2008-01-31
JP2008506825A (ja) 2008-03-06
WO2006008212A1 (en) 2006-01-26

Similar Documents

Publication Publication Date Title
BRPI0612170A2 (pt) processo para a polimerização de olefinas
BR0207072A (pt) Processo para a polimerização de olefinas
CN107406646B (zh) 树脂组合物及其用途
BR0317911A (pt) Catalisador bimetálico, processo de polimerização, e poliolefinas bimodais do mesmo
AR070938A2 (es) Composiciones poly-hema de baja polidispersion
BRPI0413961A (pt) processo multi-etapas para preparar copolìmeros heterofásicos de propileno
WO2008014217A3 (en) Fluorenyl catalyst compositions and olefin polymerization process
AR070087A1 (es) Proceso para polimerizar polimeros a base de olefinas
BR112014013764A2 (pt) processo para a produção de polietileno bimodal na presença desse sistema de catalisador
ATE449053T1 (de) Indanverbindungen mit negativer dielektrischer anisotropie
BRPI0512555A (pt) ativadores ácidos-suportes e catalisadores aperfeiçoados para polimerização de olefina
BRPI0411780A (pt) polìmero inibidor de incrustação marcado, copolìmero, composição, e, método para prevenir ou controlar a formação de incrustação em sistemas
BR112015010489A2 (pt) apresentação de resultados de pesquisa baseada em intenção
TW200634035A (en) Solid titanium catalyst component, catalyst for polymerization of olefin and process for producing olefin polymer
BR112017014081A2 (pt) uma composição de poliolefina e método para produção da mesma
BRPI0520401A2 (pt) catalisador de metal de transição com base em arilfenóxi, sistema catalisador de arilfenóxi para a produção de um homopolìmero, método de produção de um homopolìmero e método de produção de um copolìmero
BR112013000616A2 (pt) polímero enxertado por moléculas associativas nitrogenadas
BRPI0408714A (pt) processo
BRPI0705805A (pt) método para produzir cis-1,4-polidienos funcionalizados com elevado teor de ligação cis-1,4 e elevada funcionalidade
TW200740737A (en) Sulfonium salts
BRPI0416440A (pt) processo para a (co)polimerização de etileno
BR0304880A (pt) Homopolìmeros ou copolìmeros de buteno-1 e processo para a sua preparação
EP1803742A4 (en) PROCESS FOR PREPARING PROPYLENE POLYMER
BR9806141A (pt) Componente catalisador sólido e catalisador para a polimerização de olefinas ch2=chr.
ATE519787T1 (de) Komponenten und katalysatoren für die polymerisation von olefinen

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE AS 6A E 7A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2158 DE 15/05/2012.