BRPI0514491A - processo para extrusão/peletização de um polietileno - Google Patents
processo para extrusão/peletização de um polietilenoInfo
- Publication number
- BRPI0514491A BRPI0514491A BRPI0514491-4A BRPI0514491A BRPI0514491A BR PI0514491 A BRPI0514491 A BR PI0514491A BR PI0514491 A BRPI0514491 A BR PI0514491A BR PI0514491 A BRPI0514491 A BR PI0514491A
- Authority
- BR
- Brazil
- Prior art keywords
- polyethylene
- oxygen
- conformation
- polyethylenes
- mixer
- Prior art date
Links
- 239000004698 Polyethylene Substances 0.000 title abstract 5
- -1 polyethylene Polymers 0.000 title abstract 5
- 229920000573 polyethylene Polymers 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 238000005453 pelletization Methods 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/42—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
- B29B7/421—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix with screw and additionally other mixing elements on the same shaft, e.g. paddles, discs, bearings, rotor blades of the Banbury type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0017—Combinations of extrusion moulding with other shaping operations combined with blow-moulding or thermoforming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/12—Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
- B29C48/295—Feeding the extrusion material to the extruder in gaseous form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/0641—MDPE, i.e. medium density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/256—Sheets, plates, blanks or films
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
PROCESSO PARA EXTRUSãO/PELETIZAçãO DE UM POLIETILENO. A presente invenção refere-se a métodos de conformação polietilenos que são contemplados utilizando-se de 0,5 a 7,95 por cento em volume de gases contendo oxigênio. A conformação ocorre em uma zona de transporte de massa fundida de um misturador/extrusora, e não nas zonas de alimentação ou de massa fundida de um misturador/extrusora. O efeito de conformação é aumentar elasticidade (G<39>/G") dos polietilenos mais do que 10 por cento sabre polietilenos similares que são extrudados/misturados na ausência substancial de oxigênio ou gases contendo oxigênio.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60293604P | 2004-08-19 | 2004-08-19 | |
| PCT/US2005/026352 WO2006023213A1 (en) | 2004-08-19 | 2005-07-25 | Oxygen tailoring of polyethylene resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0514491A true BRPI0514491A (pt) | 2008-06-17 |
Family
ID=35967846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0514491-4A BRPI0514491A (pt) | 2004-08-19 | 2005-07-25 | processo para extrusão/peletização de um polietileno |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060038315A1 (pt) |
| EP (1) | EP1778745A4 (pt) |
| KR (1) | KR20070055539A (pt) |
| CN (1) | CN101014631A (pt) |
| AU (1) | AU2005277807B2 (pt) |
| BR (1) | BRPI0514491A (pt) |
| CA (1) | CA2577548A1 (pt) |
| MX (1) | MX2007001862A (pt) |
| WO (1) | WO2006023213A1 (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050012235A1 (en) * | 2001-11-30 | 2005-01-20 | Schregenberger Sandra D | Oxygen tailoring of polyethylene resins |
| US7892466B2 (en) | 2004-08-19 | 2011-02-22 | Univation Technologies, Llc | Oxygen tailoring of polyethylene resins |
| US8202940B2 (en) * | 2004-08-19 | 2012-06-19 | Univation Technologies, Llc | Bimodal polyethylene compositions for blow molding applications |
| US7451600B2 (en) * | 2005-07-06 | 2008-11-18 | Pratt & Whitney Canada Corp. | Gas turbine engine combustor with improved cooling |
| JP2010534255A (ja) * | 2007-07-23 | 2010-11-04 | アドバンスド ポリメリク プロプライエタリー リミテッド | ポリオレフィンの改質 |
| WO2011090914A1 (en) * | 2010-01-19 | 2011-07-28 | Dow Global Technologies LLC (Formerly known as Dow Global Technologies Inc.) | Method for improving the bubble stability of a polyethylene composition suitable for blown film extrusion process |
| US20120205832A1 (en) * | 2011-02-15 | 2012-08-16 | Waseem Rahim | Polyolefin manufacturing process |
| KR101331556B1 (ko) | 2012-03-30 | 2013-11-20 | 대림산업 주식회사 | 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체 |
| DE102012222991A1 (de) * | 2012-12-12 | 2014-06-12 | Henkel Ag & Co. Kgaa | Verfahren zur Degradierung von (Co)polymeren |
| CN105085725A (zh) * | 2015-08-24 | 2015-11-25 | 华南理工大学 | 一种臭氧氧化工艺制备氧化聚丙烯的装置及方法 |
| EP3450127A1 (en) * | 2017-09-01 | 2019-03-06 | Basell Polyolefine GmbH | Process for preparing a polyolefin composition |
| MX2022004720A (es) | 2019-10-28 | 2022-05-11 | Univation Tech Llc | Metodo para aumentar la estabilidad de burbujas de una resina de polietileno. |
| CN111516176B (zh) * | 2020-04-28 | 2021-01-08 | 上海宝明化纤原料有限公司 | 一种通用塑料粒子制备工艺 |
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| JPS5231269B2 (pt) * | 1974-06-13 | 1977-08-13 | ||
| US4115107A (en) * | 1976-12-14 | 1978-09-19 | Aluminum Company Of America | Method of producing metal flake |
| US4302565A (en) * | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
| US4173445A (en) * | 1978-07-17 | 1979-11-06 | Monsanto Company | Plastics extrusion apparatus |
| US4414364A (en) * | 1979-04-23 | 1983-11-08 | Mcalister Roy E | Stabilization of polyester |
| JPS5887013A (ja) * | 1981-11-18 | 1983-05-24 | Japan Steel Works Ltd:The | 連続混練造粒装置 |
| JPS59166507A (ja) * | 1983-03-12 | 1984-09-19 | Nissan Chem Ind Ltd | 中空成形用樹脂の製造方法 |
| US4814135A (en) * | 1987-12-22 | 1989-03-21 | Union Carbide Corporation | Process for extrusion |
| US5032562A (en) * | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
| JP2607965B2 (ja) * | 1990-01-26 | 1997-05-07 | 東洋化成工業株式会社 | ポリオレフイン系樹脂組成物 |
| DE69119688T2 (de) * | 1990-10-10 | 1997-01-16 | Minnesota Mining & Mfg | Pfropfcopolymere und Pfropfcopolymer-/Protein- Zusammensetzungen |
| US5405917A (en) * | 1992-07-15 | 1995-04-11 | Phillips Petroleum Company | Selective admixture of additives for modifying a polymer |
| CA2077580A1 (en) * | 1992-09-04 | 1994-03-05 | Kam Ho | Asphalt/o-modified polyethylene |
| US5284613A (en) * | 1992-09-04 | 1994-02-08 | Mobil Oil Corporation | Producing blown film and blends from bimodal high density high molecular weight film resin using magnesium oxide-supported Ziegler catalyst |
| JP3040041B2 (ja) * | 1993-04-26 | 2000-05-08 | 日東電工株式会社 | アルカリ二次電池及びその製造方 |
| EP0629479B1 (en) * | 1993-06-16 | 1999-02-10 | Union Carbide Chemicals And Plastics Company, Inc. | Apparatus and process for continuously pelletizing synthetic thermoplastic materials |
| JP3390446B2 (ja) * | 1993-10-21 | 2003-03-24 | モービル・オイル・コーポレーション | 高分子量成分及び低分子量成分を含む樹脂組成物 |
| FR2723880B1 (fr) * | 1994-08-30 | 1997-01-03 | Bp Chemicals Snc | Procede pour modifier un polyethylene dans une extrudeuse |
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| US5587434A (en) * | 1995-10-13 | 1996-12-24 | Union Carbide Chemicals & Plastics Technology Corporation | Process for polymer degradation |
| US5728335A (en) * | 1996-06-26 | 1998-03-17 | Union Carbide Chemicals & Plastics Technology Corporation | Process for extrusion |
| US6454976B1 (en) * | 1996-06-26 | 2002-09-24 | Union Carbide Chemicals & Plastics Technology Corporation | Pelletizing of broad molecular weight polyethylene |
| US5962598A (en) * | 1996-07-26 | 1999-10-05 | Equistar Chemicals, Lp | Polyethlene film composition having broad molecular weight distribution and improved bubble stability |
| KR20010052195A (ko) * | 1998-03-04 | 2001-06-25 | 엑손 케미칼 패턴츠 인코포레이티드 | 폴리올레핀 중합체 분산액을 제조하기 위한 생성물 및 방법 |
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| US6248840B1 (en) * | 1998-12-28 | 2001-06-19 | Phillips Petroleum Company | Process to produce a composition |
| US20020014717A1 (en) * | 1999-03-31 | 2002-02-07 | Susan Marie Kling | Process for producing thermoplastic films by blown film extrusion and films produced thereby |
| DE10013948A1 (de) * | 2000-03-21 | 2001-09-27 | Basell Polyolefine Gmbh | Verfahren zum Granulieren von thermoplastischen Polymeren |
| JP4054510B2 (ja) * | 2000-04-27 | 2008-02-27 | 住友化学株式会社 | メタクリル酸メチル系樹脂加工品の製造方法 |
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| DE10033197C1 (de) * | 2000-07-07 | 2002-01-10 | Fraunhofer Ges Forschung | Verfahren zur Herstellung von hochsubstituierter Carboxymethylstärke |
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| US20050012235A1 (en) * | 2001-11-30 | 2005-01-20 | Schregenberger Sandra D | Oxygen tailoring of polyethylene resins |
| KR100642156B1 (ko) * | 2001-11-30 | 2006-11-08 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리에틸렌 수지의 산소 처리 |
| US6989423B2 (en) * | 2002-07-03 | 2006-01-24 | Exxonmobil Chemical Patents, Inc. | Oxygen tailoring of polyethylene film resins |
-
2005
- 2005-07-19 US US11/185,068 patent/US20060038315A1/en not_active Abandoned
- 2005-07-25 MX MX2007001862A patent/MX2007001862A/es active IP Right Grant
- 2005-07-25 WO PCT/US2005/026352 patent/WO2006023213A1/en not_active Ceased
- 2005-07-25 EP EP05778036A patent/EP1778745A4/en not_active Withdrawn
- 2005-07-25 KR KR1020077006241A patent/KR20070055539A/ko not_active Ceased
- 2005-07-25 CN CNA200580027836XA patent/CN101014631A/zh active Pending
- 2005-07-25 BR BRPI0514491-4A patent/BRPI0514491A/pt not_active Application Discontinuation
- 2005-07-25 AU AU2005277807A patent/AU2005277807B2/en not_active Ceased
- 2005-07-25 CA CA002577548A patent/CA2577548A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1778745A4 (en) | 2010-02-03 |
| EP1778745A1 (en) | 2007-05-02 |
| KR20070055539A (ko) | 2007-05-30 |
| CA2577548A1 (en) | 2006-03-02 |
| AU2005277807A1 (en) | 2006-03-02 |
| MX2007001862A (es) | 2008-10-24 |
| WO2006023213A1 (en) | 2006-03-02 |
| AU2005277807B2 (en) | 2011-04-28 |
| CN101014631A (zh) | 2007-08-08 |
| US20060038315A1 (en) | 2006-02-23 |
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