BRPI0515805A - método de sintetização de álcool de alta molecularidade - Google Patents
método de sintetização de álcool de alta molecularidadeInfo
- Publication number
- BRPI0515805A BRPI0515805A BRPI0515805-2A BRPI0515805A BRPI0515805A BR PI0515805 A BRPI0515805 A BR PI0515805A BR PI0515805 A BRPI0515805 A BR PI0515805A BR PI0515805 A BRPI0515805 A BR PI0515805A
- Authority
- BR
- Brazil
- Prior art keywords
- high molecular
- phosphate
- ethanol
- calcium
- molecular alcohol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"MéTODO DE SINTETIZAçãO DE áLCOOL DE ALTA MOLECULARIDADE". A presente invenção refere-se a um método de produção com o qual álccois de alta molecuralidade que têm um número par de átomos de carbono tais como 1-butanol, hexanol, octanol e decanol e uma mistura dos mesmos são coletados eficazmente por meio de processos limpos, com o uso de etanol como uma matéria-prima. Pela utilização de compostos à base de fosfato de cálcio tais como hidroxiapatita Ca~ 10~(PO~ 4~)~ 6~(OH)~ 2~, fosfato tricálcico Ca~ 3~(PO~ 4~)~ 2~, fosfato de monohidrogenado de cálcio CaHPO~ 4~ (0 ~ 2)H~ 2~O, difosfato de cálcio Ca~ 2~P~ 2~O~ 7~, fosfato de octacálcio Ca~ 8~H~ 2~(PO~ 4~)~ 6~ 5H~ 2~O, fosfato de tetracálcio Ca~ 4~(PO~ 4~)~ 2~O, fosfato de cálcio amorfo Ca~ 3~(PO~ 4~)~ 2~ nH~ 2~O, de preferência hidroxiapatita, como um catalisador, usando-se etanol como um material de partida e ajustando-se um tempo de contato a 0,4 segundo ou mais longo, são produzidos álccois de alta molecuralidade partindo de etanol.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004-351307 | 2004-12-03 | ||
| JP2004351307 | 2004-12-03 | ||
| PCT/JP2005/022217 WO2006059729A1 (ja) | 2004-12-03 | 2005-12-02 | 高分子アルコールの合成法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0515805A true BRPI0515805A (pt) | 2008-08-05 |
| BRPI0515805B1 BRPI0515805B1 (pt) | 2015-07-28 |
Family
ID=36565161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0515805-2A BRPI0515805B1 (pt) | 2004-12-03 | 2005-12-02 | Método de sintetização de álcool de alto peso molecular, em particular 1-butanol |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8080695B2 (pt) |
| EP (1) | EP1829851B1 (pt) |
| JP (1) | JP4903582B2 (pt) |
| KR (2) | KR20070085516A (pt) |
| CN (2) | CN101065345A (pt) |
| AU (1) | AU2005310507B2 (pt) |
| BR (1) | BRPI0515805B1 (pt) |
| CA (1) | CA2589125C (pt) |
| RU (1) | RU2422428C2 (pt) |
| WO (1) | WO2006059729A1 (pt) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008090703A (ja) * | 2006-10-04 | 2008-04-17 | Sangi Co Ltd | 化学工業原料製造販売管理システム |
| JP2008303160A (ja) * | 2007-06-06 | 2008-12-18 | Mitsubishi Chemicals Corp | アルコールの製造方法 |
| WO2009026510A1 (en) | 2007-08-22 | 2009-02-26 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst |
| WO2009026523A1 (en) | 2007-08-22 | 2009-02-26 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
| US7700812B2 (en) | 2007-08-22 | 2010-04-20 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid |
| US8603201B2 (en) | 2007-08-24 | 2013-12-10 | Kabushiki Kaisha Sangi | Method of synthesizing chemical industry raw materials and fuel compositions |
| JP5382902B2 (ja) * | 2007-08-24 | 2014-01-08 | 株式会社サンギ | 化学工業原料及び燃料組成物の合成方法 |
| AU2008298827B2 (en) | 2007-09-13 | 2011-12-01 | Kabushiki Kaisha Sangi | Process for production of composition by using alcohol as starting material |
| BRPI0817390A2 (pt) * | 2007-11-13 | 2017-06-13 | Du Pont | "processo para fazer uma composição e composição para uso como combustível diesel ou aditivo de combustível" |
| JP5849259B2 (ja) * | 2008-02-21 | 2016-01-27 | 国立大学法人高知大学 | 触媒およびアルコールの合成法 |
| US8318989B2 (en) | 2008-12-22 | 2012-11-27 | E I Du Pont De Nemours And Company | Process for producing guerbet alcohols using water tolerant basic catalysts |
| US8232433B2 (en) | 2009-08-17 | 2012-07-31 | Kabushiki Kaisha Sangi | Catalyst and alcohol synthesis method |
| BR112012005321B1 (pt) * | 2009-09-11 | 2018-06-05 | E.I. Du Pont De Nemours And Company | "Processo" |
| FR2951163B1 (fr) * | 2009-10-13 | 2012-09-28 | Total Raffinage Marketing | Procede de production de distillat par oligomerisation catalytique d'olefines en presence de composes oxygenes |
| FR2951161B1 (fr) * | 2009-10-13 | 2012-03-02 | Total Raffinage Marketing | Procede de production de distillat a partir d'une charge hydrocarbonee comprenant une condensation d'alcool |
| US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
| BR112012009658B1 (pt) * | 2009-10-29 | 2018-06-19 | Kochi University | Método para a sintetização de ácido carboxílico insaturado e/ou seu derivado |
| CN101823938B (zh) * | 2010-04-23 | 2012-12-05 | 浙江大学 | 正丁醇催化缩合制备异辛醇的方法 |
| DE102010024099A1 (de) | 2010-06-17 | 2011-12-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Katalytische Konversion von Alkoholen und Aldehyden |
| BR112013005849B1 (pt) * | 2010-09-15 | 2019-04-24 | Kabushiki Kaisha Sangi | Método para a produção de álcool por reação de guerbet. |
| AU2011327947B2 (en) * | 2010-11-11 | 2016-05-05 | Lucite International Uk Limited | A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor |
| US8431753B2 (en) | 2011-03-09 | 2013-04-30 | E I Du Pont De Nemours And Company | Conversion of butanol to a reaction product comprising 2-ethylhexanol using hydroxyapatite catalysts |
| FR2980791A1 (fr) * | 2011-10-03 | 2013-04-05 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
| FR2984312A1 (fr) * | 2011-12-20 | 2013-06-21 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
| FR2984313B1 (fr) * | 2011-12-20 | 2014-01-17 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
| US9079851B2 (en) | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
| US20130303363A1 (en) | 2012-03-01 | 2013-11-14 | E I Du Pont De Nemours And Company | Conversion of ethanol to a reaction product comprising 1-butanol using hydroxyapatite catalysts |
| EP2679304A1 (en) | 2012-06-29 | 2014-01-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide |
| ES2855323T3 (es) | 2012-06-29 | 2021-09-23 | Abengoa Bioenergia Nuevas Tecnologias Sa | Catalizador para la obtención de alcoholes superiores |
| US8809594B2 (en) | 2012-09-21 | 2014-08-19 | Eastman Chemical Company | Dual catalyst system for the self-condensation of alcohols |
| US9024090B2 (en) | 2012-12-19 | 2015-05-05 | Celanese International Corporation | Catalysts and processes for producing butanol |
| US8962897B2 (en) | 2012-12-19 | 2015-02-24 | Celanese International Corporation | Catalysts and processes for producing butanol |
| US20140171693A1 (en) | 2012-12-19 | 2014-06-19 | Celanese International Corporation | Coated Hydrotalcite Catalysts and Processes for Producing Butanol |
| FR3001728B1 (fr) | 2013-02-04 | 2015-11-13 | Adisseo France Sas | Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool |
| WO2014130465A1 (en) * | 2013-02-19 | 2014-08-28 | Greenyug, Llc | Production of higher alcohols |
| JP2014040415A (ja) * | 2013-08-06 | 2014-03-06 | Sangi Co Ltd | 化学工業原料及び燃料組成物の合成方法 |
| BR112016012629B1 (pt) | 2013-12-04 | 2020-12-01 | Rescurve, Llc | método e sistema de destilação reativa |
| US9018426B1 (en) | 2013-12-19 | 2015-04-28 | Celanese International Corporation | Processes for producing multi-carbon alcohols |
| EP2889280A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
| HUE043870T2 (hu) | 2013-12-27 | 2019-09-30 | Abengoa Bioenergia Nuevas Tecnologias Sa | Eljárás nagyobb szénatomszámú alkoholok elõállítására alacsonyabb szénatomszámú alkoholokból Guerbet kondenzációval |
| EP2889282A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
| EP2889281A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
| EP2889283A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
| WO2016075531A1 (en) | 2014-11-14 | 2016-05-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Process for the preparation of higher alcohols from ethanol and n-hexanol by guerbet condensation |
| ES2570227B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
| ES2570231B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
| CA3225290A1 (en) | 2015-08-19 | 2017-02-23 | Viridis Chemical, Llc | Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols |
| US9828322B2 (en) | 2016-01-28 | 2017-11-28 | Eastman Chemical Company | Efficient synthesis of methacroelin and other alpha, beta-unsaturated aldehydes over a regenerable anatase titania catalyst |
| US9834501B2 (en) | 2016-01-28 | 2017-12-05 | Eastman Chemical Company | Efficient synthesis of methacroelin and other alpha, beta—unsaturated aldehydes from methanol and an aldehyde |
| WO2018039609A1 (en) * | 2016-08-25 | 2018-03-01 | Rescurve, Llc | Production of higher alcohols |
| CN108117480B (zh) * | 2016-11-26 | 2021-09-03 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇和乙醇混合液制备异丁醇的方法 |
| CN109529897B (zh) * | 2018-12-04 | 2020-07-31 | 西南化工研究设计院有限公司 | 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用 |
| EP4000728B1 (en) * | 2020-11-18 | 2023-03-29 | B. Braun Surgical, S.A. | Composition or material, a process for its production and uses thereof |
| EP4370493A1 (en) * | 2021-07-12 | 2024-05-22 | Omya International AG | Process for preparing an alcohol using a surface-reacted calcium carbonate catalyst |
| CN117602599B (zh) * | 2023-11-20 | 2026-03-06 | 大连理工大学 | 一种强碱性羟基磷灰石的机械化学制备方法及在乙醇偶联反应中的应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2645667A (en) * | 1951-10-01 | 1953-07-14 | Phillips Petroleum Co | Condensation of alcohols in the presence of calcium hydroxide |
| DE3236307C2 (de) * | 1982-09-30 | 1985-11-14 | IMA - Klessmann GmbH & Co KG, 4830 Gütersloh | Maschine zum Bohren und Einsetzen von Beschlagteilen in plattenförmige Werkstücke |
| CA2094629C (en) * | 1992-04-28 | 1999-10-05 | Shuji Sakuma | Catalyst and method for contact cracking of lower alkanols |
| JPH11217343A (ja) | 1998-01-30 | 1999-08-10 | Sangi Co Ltd | 化学工業原料及びハイオク燃料の合成法 |
-
2005
- 2005-12-02 JP JP2006546656A patent/JP4903582B2/ja not_active Expired - Lifetime
- 2005-12-02 AU AU2005310507A patent/AU2005310507B2/en not_active Ceased
- 2005-12-02 KR KR1020077012087A patent/KR20070085516A/ko not_active Ceased
- 2005-12-02 RU RU2007124714/04A patent/RU2422428C2/ru active
- 2005-12-02 EP EP05811784.7A patent/EP1829851B1/en not_active Expired - Lifetime
- 2005-12-02 CA CA2589125A patent/CA2589125C/en not_active Expired - Lifetime
- 2005-12-02 CN CNA2005800400535A patent/CN101065345A/zh active Pending
- 2005-12-02 CN CN201210270715.XA patent/CN102911010B/zh not_active Expired - Fee Related
- 2005-12-02 BR BRPI0515805-2A patent/BRPI0515805B1/pt not_active IP Right Cessation
- 2005-12-02 WO PCT/JP2005/022217 patent/WO2006059729A1/ja not_active Ceased
- 2005-12-02 KR KR1020087031303A patent/KR101113050B1/ko not_active Expired - Lifetime
-
2007
- 2007-06-04 US US11/757,588 patent/US8080695B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2007124714A (ru) | 2009-01-10 |
| RU2422428C2 (ru) | 2011-06-27 |
| WO2006059729A1 (ja) | 2006-06-08 |
| CN101065345A (zh) | 2007-10-31 |
| EP1829851A4 (en) | 2009-11-25 |
| CN102911010A (zh) | 2013-02-06 |
| AU2005310507B2 (en) | 2010-02-25 |
| CN102911010B (zh) | 2016-03-02 |
| JPWO2006059729A1 (ja) | 2008-06-05 |
| CA2589125C (en) | 2010-10-19 |
| AU2005310507A1 (en) | 2006-06-08 |
| JP4903582B2 (ja) | 2012-03-28 |
| KR20090009330A (ko) | 2009-01-22 |
| EP1829851B1 (en) | 2013-06-19 |
| KR20070085516A (ko) | 2007-08-27 |
| BRPI0515805B1 (pt) | 2015-07-28 |
| CA2589125A1 (en) | 2006-06-08 |
| US20070255079A1 (en) | 2007-11-01 |
| US8080695B2 (en) | 2011-12-20 |
| EP1829851A1 (en) | 2007-09-05 |
| KR101113050B1 (ko) | 2012-03-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 02/12/2005, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 20A ANUIDADE. |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2857 DE 07-10-2025 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |