BRPI0600357A - processo para produção de éster de ácido carboxìlico por meio de uma destilação reativa - Google Patents

processo para produção de éster de ácido carboxìlico por meio de uma destilação reativa

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Publication number
BRPI0600357A
BRPI0600357A BRPI0600357-5A BRPI0600357A BRPI0600357A BR PI0600357 A BRPI0600357 A BR PI0600357A BR PI0600357 A BRPI0600357 A BR PI0600357A BR PI0600357 A BRPI0600357 A BR PI0600357A
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BR
Brazil
Prior art keywords
carboxylic acid
acid ester
production
reactive distillation
column
Prior art date
Application number
BRPI0600357-5A
Other languages
English (en)
Inventor
Laurent Zuber
Oliver Bailer
Stefan Sander
Heinz Meierhofer
Original Assignee
Sulzer Chemtech Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sulzer Chemtech Ag filed Critical Sulzer Chemtech Ag
Publication of BRPI0600357A publication Critical patent/BRPI0600357A/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D11/00—Carrying forward or transferring entries from one page to another, e.g. for book-keeping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D1/00—Books or other bound products
    • B42D1/009—Books or other bound products characterised by printed matter not otherwise provided for
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D15/00—Printed matter of special format or style not otherwise provided for
    • B42D15/0006—Paper provided with guiding marks, e.g. ruled, squared or scaled paper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32206—Flat sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32213—Plurality of essentially parallel sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32224—Sheets characterised by the orientation of the sheet
    • B01J2219/32227—Vertical orientation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B01J2219/32475—Composition or microstructure of the elements comprising catalytically active material involving heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32491—Woven or knitted materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Engineering & Computer Science (AREA)
  • Educational Administration (AREA)
  • Educational Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA PRODUçãO DE éSTER DE áCIDO CARBOXìLICO POR MEIO DE UMA DESTILAçãO REATIVA". A presente invenção refere-se a um processo para produção de éster de ácido carboxílico (E) por uma esterificação que é conduzido por meio de uma destilação reativa em uma primeira coluna (1). O éster de ácido carboxílico ferve a uma temperatura mais alta do que os edutos de ácido carboxílico (S) e álcool (A). Um catalisador de material sólido é usado na esterificação. A esterificação e uma separação destilativa ocorrem em três zonas, Isto é, em uma zona reacional (3), em uma zona separatória superior (8) e também em uma zona separatória inferior (4). Um primeiro produto superior (61) e um primeiro produto de drenagem (52) são produzidos. Uma fase aquosa (63) é separada de uma fase orgânica (62) do primeiro produto superior. O calor (Q~ +~), que é necessário para acionar a destilação reativa, é fornecido a uma temperatura para a qual uma pressão não superior à pressão ambiente é ajustada no produto de drenagem evaporado. O éster de ácido carboxílico é obtido do primeiro produto de drenagem, com a remoção de um traço de ácido carboxílico e álcool. A remoção de ácido carboxílico e álcool do primeiro produto de drenagem é conduzida por destilação em uma segunda coluna (71). Nessa disposição, o calor é fornecido a um segundo produto de drenagem (71), isto é, ao produto de drenagem da segunda coluna, que consiste, em grande parte, em éster de ácido carboxílico e pequenas proporções de outros materiais, a uma temperatura para a qual uma pressão superior à pressão ambiente é ajustada no produto de drenagem evaporado.
BRPI0600357-5A 2005-02-10 2006-02-09 processo para produção de éster de ácido carboxìlico por meio de uma destilação reativa BRPI0600357A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05405063 2005-02-10

Publications (1)

Publication Number Publication Date
BRPI0600357A true BRPI0600357A (pt) 2006-10-03

Family

ID=34942907

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0600357-5A BRPI0600357A (pt) 2005-02-10 2006-02-09 processo para produção de éster de ácido carboxìlico por meio de uma destilação reativa

Country Status (9)

Country Link
US (1) US7329774B2 (pt)
JP (1) JP5009539B2 (pt)
KR (1) KR20060090764A (pt)
CN (1) CN1817847B (pt)
AT (1) ATE440813T1 (pt)
BR (1) BRPI0600357A (pt)
DE (1) DE502006004625D1 (pt)
MY (1) MY149893A (pt)
TW (1) TW200635892A (pt)

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ES2712067T3 (es) * 2011-10-12 2019-05-09 Greenyug Llc Producción de acetato de etilo
US9090556B2 (en) * 2011-12-09 2015-07-28 Board Of Trustees Of Michigan State University Method for producing acyloxy carboxylic acids and derivatives thereof
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US12338211B2 (en) 2019-07-29 2025-06-24 Eastman Chemical Company Recycle content (C4)alkanal
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Also Published As

Publication number Publication date
CN1817847B (zh) 2012-05-09
US7329774B2 (en) 2008-02-12
DE502006004625D1 (de) 2009-10-08
JP2006219492A (ja) 2006-08-24
ATE440813T1 (de) 2009-09-15
MY149893A (en) 2013-10-31
JP5009539B2 (ja) 2012-08-22
KR20060090764A (ko) 2006-08-16
US20060178524A1 (en) 2006-08-10
CN1817847A (zh) 2006-08-16
TW200635892A (en) 2006-10-16

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