BRPI0608332A2 - processo para produção de ácido acético - Google Patents
processo para produção de ácido acéticoInfo
- Publication number
- BRPI0608332A2 BRPI0608332A2 BRPI0608332-3A BRPI0608332A BRPI0608332A2 BR PI0608332 A2 BRPI0608332 A2 BR PI0608332A2 BR PI0608332 A BRPI0608332 A BR PI0608332A BR PI0608332 A2 BRPI0608332 A2 BR PI0608332A2
- Authority
- BR
- Brazil
- Prior art keywords
- acetic acid
- carbonylation
- disclosed
- reducing
- acid production
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 12
- 238000000034 method Methods 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 230000006315 carbonylation Effects 0.000 abstract 4
- 238000005810 carbonylation reaction Methods 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000001577 simple distillation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCESSO PARA PRODUçAO DE ACIDO ACéTICO. é revelado um processo para redução e/ou remoção de compostos de redução de permanganato formatos pela carbonilação de metanol, na presença de um catalisador de carbonilação de metal do Grupo VIII, para produzir ácido acético. Mais especificamente, é revelado um processo para redução e/ou remoção de compostos de redução de permanganato ou seus precursores de correntes intermediárias, durante a formação do ácido acético pelos processos de carbonilação. Especificamente, é revelado um processo no qual uma corrente de vapor aérea de carbonilação baixa da coluna de extremidades leves é submetida a uma destilação simples para obter uma parte superior que é submetida a uma extração para remover e/ou reduzir seletivamente os PRCs do processo.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/116,771 US7855306B2 (en) | 2005-04-28 | 2005-04-28 | Process for the production of acetic acid |
| PCT/US2006/012822 WO2006115721A1 (en) | 2005-04-28 | 2006-04-06 | Process for the production of acetic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0608332A2 true BRPI0608332A2 (pt) | 2009-12-01 |
| BRPI0608332B1 BRPI0608332B1 (pt) | 2016-07-05 |
Family
ID=36954738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0608332A BRPI0608332B1 (pt) | 2005-04-28 | 2006-04-06 | processo para produção de ácido acético |
Country Status (19)
| Country | Link |
|---|---|
| US (3) | US7855306B2 (pt) |
| EP (2) | EP1879845B1 (pt) |
| JP (1) | JP4976383B2 (pt) |
| KR (1) | KR101060894B1 (pt) |
| CN (1) | CN101163658B (pt) |
| AR (1) | AR056330A1 (pt) |
| AU (1) | AU2006240399B2 (pt) |
| BR (1) | BRPI0608332B1 (pt) |
| CA (1) | CA2605494C (pt) |
| ES (2) | ES2584186T3 (pt) |
| MX (1) | MX2007013566A (pt) |
| MY (1) | MY145002A (pt) |
| NO (1) | NO20076115L (pt) |
| NZ (1) | NZ562496A (pt) |
| RU (1) | RU2404960C2 (pt) |
| TW (1) | TWI410403B (pt) |
| UA (1) | UA90310C2 (pt) |
| WO (1) | WO2006115721A1 (pt) |
| ZA (1) | ZA200709028B (pt) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7855306B2 (en) * | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
| EP2562153B1 (en) * | 2006-04-14 | 2015-07-22 | Celanese International Corporation | Process for the reduction of aldehyde concentration in a target stream |
| US7619113B2 (en) * | 2007-09-27 | 2009-11-17 | Celanese International Corporation | Method and apparatus for making acetic acid with improved purification |
| US8062482B2 (en) * | 2007-10-30 | 2011-11-22 | Celanese International Corporation | Acetaldehyde removal from methyl acetate by distillation at elevated pressure |
| US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| US7884237B2 (en) * | 2008-11-07 | 2011-02-08 | Celanese International Corp. | Methanol carbonylation with improved aldehyde removal |
| US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
| JP5837576B2 (ja) * | 2010-05-18 | 2015-12-24 | セラニーズ・インターナショナル・コーポレーション | 過マンガン酸塩還元性化合物を除去することによって酢酸流を精製する方法 |
| US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| WO2012148509A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
| US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
| US8378141B2 (en) | 2010-08-16 | 2013-02-19 | Celanese International Corporation | Process and system for supplying vapor from drying column to light ends column |
| US8461379B2 (en) | 2010-10-12 | 2013-06-11 | Celanese International Corporation | Production of acetic acid comprising feeding at least one reactant to a recycle stream |
| EP2627624B1 (en) | 2010-10-13 | 2019-02-13 | Celanese International Corporation | Process for recovering halogen promoters and removing permanganate reducing compounds |
| US8637698B2 (en) | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
| BR112013014808B1 (pt) | 2010-12-15 | 2021-03-02 | Daicel Corporation | processo para produzir ácido acético |
| TW201302684A (zh) | 2011-04-26 | 2013-01-16 | Celanese Int Corp | 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程 |
| US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
| US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
| US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
| US8697908B2 (en) | 2011-05-05 | 2014-04-15 | Celanese International Corporation | Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants |
| SG194198A1 (en) | 2011-05-05 | 2013-12-30 | Celanese Int Corp | Removal of aromatics from carbonylation process |
| US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
| TW201332950A (zh) * | 2011-11-09 | 2013-08-16 | Celanese Int Corp | 藉由乙酸萃取鹵化物的乙醇整合製程 |
| WO2013070212A1 (en) | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Producing ethanol using two different streams from acetic acid carbonylation process |
| US8704013B2 (en) | 2011-11-09 | 2014-04-22 | Celanese International Corporation | Integrated process for producing ethanol |
| WO2013070211A1 (en) | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Integrated process for producing ethanol from methanol |
| US8614359B2 (en) | 2011-11-09 | 2013-12-24 | Celanese International Corporation | Integrated acid and alcohol production process |
| US8809598B2 (en) | 2011-11-09 | 2014-08-19 | Celanese International Corporation | Producing ethanol using two different streams from acetic acid carbonylation process |
| WO2013070216A1 (en) | 2011-11-09 | 2013-05-16 | Celanese International Corporation | Integrated ethanol production from methanol via carbonylation and hydrogenation by extracting halides from acetic acid |
| US9079121B2 (en) | 2011-12-02 | 2015-07-14 | Celanese International Corporation | Distillation column having enlarged downcomers and method of downcomer enlargement |
| US9051258B2 (en) * | 2011-12-21 | 2015-06-09 | Lyondellbasell Acetyls, Llc | Process for the manufacture of acetic acid |
| US9090554B2 (en) | 2011-12-21 | 2015-07-28 | Lyondellbasell Acetyls, Llc | Process for the manufacture of acetic acid |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| US9193657B2 (en) * | 2012-08-17 | 2015-11-24 | Celanese International Corporation | Catalyst stability in carbonylation processes |
| US8859810B2 (en) * | 2012-08-21 | 2014-10-14 | Celanese International Corporation | Process for recovering permanganate reducing compounds from an acetic acid production process |
| WO2014143840A2 (en) | 2013-03-15 | 2014-09-18 | Celanese International Corporation | Process for separating product gas using carbonylation processes |
| MX2017004287A (es) | 2014-10-02 | 2017-07-19 | Celanese Int Corp | Proceso para la produccion de acido acetico. |
| US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
| SG11201703392WA (en) | 2014-11-14 | 2017-05-30 | Celanese Int Corp | Processes for producing acetic acid from a reaction medium having low ethyl iodide content |
| EP3218343B1 (en) | 2014-11-14 | 2019-10-02 | Celanese International Corporation | Processes for producing acetic acid with decanter control |
| US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9233907B1 (en) | 2014-11-14 | 2016-01-12 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| US9540304B2 (en) | 2014-11-14 | 2017-01-10 | Celanese International Corporation | Processes for producing an acetic acid product having low butyl acetate content |
| RS59401B1 (sr) * | 2015-01-30 | 2019-11-29 | Celanese Int Corp | Postupci proizvodnje sirćetne kiseline |
| US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
| KR102493740B1 (ko) | 2015-01-30 | 2023-01-30 | 셀라니즈 인터내셔날 코포레이션 | 아세트산의 제조 방법 |
| US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
| US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
| US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9512056B2 (en) | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| JP6822969B2 (ja) | 2015-09-30 | 2021-01-27 | 株式会社ダイセル | 酢酸の製造方法及び製造装置 |
| MY181882A (en) | 2015-10-02 | 2021-01-12 | Celanese Int Corp | Process to produce acetic acid with recycle of water |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| WO2018078924A1 (ja) | 2016-10-28 | 2018-05-03 | 株式会社ダイセル | 酢酸の製造方法 |
| US10428003B2 (en) | 2017-01-18 | 2019-10-01 | Daicel Corporation | Method for producing acetic acid |
| US10807935B2 (en) | 2018-11-02 | 2020-10-20 | Celanese International Corporation | Process for continuous acetic acid production |
| US20230127564A1 (en) | 2020-04-01 | 2023-04-27 | Celanese International Corporation | Processes for removing and/or reducing permanganate reducing compounds and alkyl iodides |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| DE3107731A1 (de) | 1981-02-28 | 1982-09-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur abtrennung organischer jod-verbindungen von carbonylierungsprodukten des methanols, methylacetates und dimethylethers |
| US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| CA1228867A (en) | 1984-05-03 | 1987-11-03 | Celanese Corporation | Methanol carbonylation process |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| AU8790391A (en) | 1990-11-19 | 1992-05-21 | Hoechst Celanese Corporation | Removal of carbonyl impurities from a carbonylation process stream |
| AU639630B2 (en) | 1991-01-28 | 1993-07-29 | Celanese International Corporation | Removal of carbonyl impurities from carbonylation process stream |
| GB9211671D0 (en) | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
| TW283702B (pt) | 1993-07-08 | 1996-08-21 | Daicel Chem | |
| SG44317A1 (en) | 1994-06-15 | 1997-12-19 | Daicel Chem | Process for producing high purity acetic acid |
| JP3332594B2 (ja) * | 1994-08-12 | 2002-10-07 | ダイセル化学工業株式会社 | 酢酸の精製方法 |
| US5599976A (en) | 1995-04-07 | 1997-02-04 | Hoechst Celanese Corporation | Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process |
| JP3927237B2 (ja) | 1995-04-27 | 2007-06-06 | ダイセル化学工業株式会社 | 酢酸の製造法 |
| JP3883221B2 (ja) | 1995-08-03 | 2007-02-21 | ダイセル化学工業株式会社 | アセトアルデヒドの分離除去方法 |
| US5783731A (en) | 1995-09-11 | 1998-07-21 | Hoechst Celanese Corporation | Removal of carbonyl impurities from a carbonylation process stream |
| IN192600B (pt) * | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
| US6339171B1 (en) | 1996-10-18 | 2002-01-15 | Celanese International Corporation | Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream |
| GB9816385D0 (en) | 1998-07-29 | 1998-09-23 | Bp Chem Int Ltd | Process |
| JP2004131389A (ja) | 2002-10-08 | 2004-04-30 | Daicel Chem Ind Ltd | カルボン酸の製造方法及び製造システム |
| US7223883B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
| US7223886B2 (en) * | 2004-03-02 | 2007-05-29 | Celanese International Corporation | Removal of permanganate reducing compounds from methanol carbonylation process stream |
| US7855306B2 (en) * | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
-
2005
- 2005-04-28 US US11/116,771 patent/US7855306B2/en active Active
-
2006
- 2006-04-06 NZ NZ562496A patent/NZ562496A/en not_active IP Right Cessation
- 2006-04-06 ES ES06749420.3T patent/ES2584186T3/es not_active Expired - Lifetime
- 2006-04-06 KR KR1020077027623A patent/KR101060894B1/ko not_active Expired - Lifetime
- 2006-04-06 RU RU2007144082/04A patent/RU2404960C2/ru not_active IP Right Cessation
- 2006-04-06 UA UAA200713221A patent/UA90310C2/ru unknown
- 2006-04-06 CA CA2605494A patent/CA2605494C/en not_active Expired - Lifetime
- 2006-04-06 CN CN2006800137351A patent/CN101163658B/zh not_active Expired - Lifetime
- 2006-04-06 BR BRPI0608332A patent/BRPI0608332B1/pt active IP Right Grant
- 2006-04-06 WO PCT/US2006/012822 patent/WO2006115721A1/en not_active Ceased
- 2006-04-06 ZA ZA200709028A patent/ZA200709028B/xx unknown
- 2006-04-06 EP EP06749420.3A patent/EP1879845B1/en not_active Expired - Lifetime
- 2006-04-06 AU AU2006240399A patent/AU2006240399B2/en not_active Ceased
- 2006-04-06 JP JP2008508883A patent/JP4976383B2/ja not_active Expired - Lifetime
- 2006-04-06 ES ES15000741.7T patent/ES2623827T3/es not_active Expired - Lifetime
- 2006-04-06 EP EP15000741.7A patent/EP2902380B1/en not_active Expired - Lifetime
- 2006-04-06 MX MX2007013566A patent/MX2007013566A/es active IP Right Grant
- 2006-04-26 MY MYPI20061937A patent/MY145002A/en unknown
- 2006-04-27 AR ARP060101697A patent/AR056330A1/es not_active Application Discontinuation
- 2006-04-28 TW TW095115414A patent/TWI410403B/zh not_active IP Right Cessation
-
2007
- 2007-11-27 NO NO20076115A patent/NO20076115L/no not_active Application Discontinuation
-
2010
- 2010-12-02 US US12/959,085 patent/US8207377B2/en not_active Expired - Lifetime
-
2012
- 2012-06-25 US US13/532,290 patent/US8501990B2/en not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 05/07/2016, OBSERVADAS AS CONDICOES LEGAIS. |