BRPI0705621A2 - plastificantes primários de pvc derivados de óleos vegetais, processo de obtenção de plastificantes primários de pvc derivados de óleos vegetais e composição de pvc plastificado - Google Patents

plastificantes primários de pvc derivados de óleos vegetais, processo de obtenção de plastificantes primários de pvc derivados de óleos vegetais e composição de pvc plastificado

Info

Publication number
BRPI0705621A2
BRPI0705621A2 BRPI0705621-4A BRPI0705621A BRPI0705621A2 BR PI0705621 A2 BRPI0705621 A2 BR PI0705621A2 BR PI0705621 A BRPI0705621 A BR PI0705621A BR PI0705621 A2 BRPI0705621 A2 BR PI0705621A2
Authority
BR
Brazil
Prior art keywords
pvc
vegetable oils
plasticizers
derived
primary plasticizers
Prior art date
Application number
BRPI0705621-4A
Other languages
English (en)
Inventor
Quadros Jacyr Vianna De Jr
Carvalho Jose Augusto De
Original Assignee
Nexoleum Bioderivados Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40344406&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0705621(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Nexoleum Bioderivados Ltda filed Critical Nexoleum Bioderivados Ltda
Priority to BRPI0705621-4A priority Critical patent/BRPI0705621B1/pt
Priority to ES08021385.3T priority patent/ES2555781T3/es
Priority to SI200831529T priority patent/SI2070977T1/sl
Priority to DK08021385.3T priority patent/DK2070977T3/da
Priority to DK15002306.7T priority patent/DK2960282T3/da
Priority to PT80213853T priority patent/PT2070977E/pt
Priority to US12/331,092 priority patent/US20090149586A1/en
Priority to PT15002306T priority patent/PT2960282T/pt
Priority to TR2019/06236T priority patent/TR201906236T4/tr
Priority to EP15002306.7A priority patent/EP2960282B1/en
Priority to EP08021385.3A priority patent/EP2070977B1/en
Priority to ES15002306T priority patent/ES2726175T3/es
Publication of BRPI0705621A2 publication Critical patent/BRPI0705621A2/pt
Priority to US14/148,312 priority patent/US9303140B2/en
Priority to US14/223,090 priority patent/US9388292B2/en
Priority to CY20151100898T priority patent/CY1116883T1/el
Publication of BRPI0705621B1 publication Critical patent/BRPI0705621B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PLASTIFICANTES PRIMáRIOS DE PVC DERIVADOS DE óLEOS VEGETAIS, PROCESSO DE OBTENçãO DE PLASTIFICANTES PRIMáRIOS DE PVC DERIVADOS DE óLEOS VEGETAIS E COMPOSIçãO DE PVC PLASTIFICADO. O presente relatório descritivo refere-se a uma patente de invenção de plastificantes primários de PVC compostos por bioésteres epoxidados de ácidos graxos de óleos vegetais obtidos por transesterificação parcial de óleos vegetais com álcool etílico ou glicerina, seguida de acetilação e posterior epoxidação e composição de PVC plastificado com bioésteres epoxidados resultantes de transesterificação parcial, acetilação e epoxidação, pertencentes ao campo técnico de aditivos para polímeros e que foram desenvolvidos para aperfeiçoar as propriedades dos polímeros à base de resina de PVC, além de propiciar um menor custo e uso de compostos obtidos de fonte renovável, tais como os óleos vegetais. Os plastificantes da presente invenção são compostos por mono, di e trigliceril ésteres e etil ésteres epoxidados, ditos plastifícantes apresentam índice oxirânico igual ou menor que 8. Estes plastificantes conferem ao PVC a melhora de suas propriedades, melhoras estas que não estão previstas no estado da técnica, tais como maior resistência à degradação por luz ultravioleta, melhores características físicas a baixas temperaturas, maior eficiência de mistura da resina.
BRPI0705621-4A 2007-12-10 2007-12-10 Composição plastificte de pvc BRPI0705621B1 (pt)

Priority Applications (15)

Application Number Priority Date Filing Date Title
BRPI0705621-4A BRPI0705621B1 (pt) 2007-12-10 2007-12-10 Composição plastificte de pvc
ES15002306T ES2726175T3 (es) 2007-12-10 2008-12-09 Composición de plastificante adecuada para composiciones de PVC
US12/331,092 US20090149586A1 (en) 2007-12-10 2008-12-09 Primary pvc plasticizers derived from vegetable oils, process for obtaining primary pvc plasticizers derived from vegetable oils and plasticized pvc composition
TR2019/06236T TR201906236T4 (tr) 2007-12-10 2008-12-09 Pvc bileşimleri için uygun plastikleştirici bileşim.
DK08021385.3T DK2070977T3 (da) 2007-12-10 2008-12-09 Epoxiderede vegetabilske olier som pvc-blødgørere
DK15002306.7T DK2960282T3 (da) 2007-12-10 2008-12-09 Blødgøringssammensætning egnet til PVC-sammensætninger
PT80213853T PT2070977E (pt) 2007-12-10 2008-12-09 Plastificantes primários de pvc derivados de óleos vegetais, processo para a obtenção de plastificantes primários de pvc derivados de óleos vegetais e composição de pvc plastificado
ES08021385.3T ES2555781T3 (es) 2007-12-10 2008-12-09 Aceites vegetales epoxidados como plastificantes de PVC
PT15002306T PT2960282T (pt) 2007-12-10 2008-12-09 Composição de plastificante adequada para composições de pvc
SI200831529T SI2070977T1 (sl) 2007-12-10 2008-12-09 Epoksidirana rastlinska olja kot mehčala za pvc
EP15002306.7A EP2960282B1 (en) 2007-12-10 2008-12-09 Plasticizer composition suitable for pvc compositions
EP08021385.3A EP2070977B1 (en) 2007-12-10 2008-12-09 Epoxidised vegetable oils as pvc plasticizers
US14/148,312 US9303140B2 (en) 2007-12-10 2014-01-06 Primary PVC plasticizers derived from vegetable oils, process for obtaining primary PVC plasticizers derived from vegetable oils and plasticized PVC composition
US14/223,090 US9388292B2 (en) 2007-12-10 2014-03-24 Primary PVC plasticizers derived from vegetable oils, process for obtaining primary PVC plasticizers derived from vegetable oils and plasticized PVC composition
CY20151100898T CY1116883T1 (el) 2007-12-10 2015-10-07 Εποξειδωμενα φυτικα ελαια ως πλαστικοποιητες pvc

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0705621-4A BRPI0705621B1 (pt) 2007-12-10 2007-12-10 Composição plastificte de pvc

Publications (2)

Publication Number Publication Date
BRPI0705621A2 true BRPI0705621A2 (pt) 2009-08-18
BRPI0705621B1 BRPI0705621B1 (pt) 2019-04-09

Family

ID=40344406

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0705621-4A BRPI0705621B1 (pt) 2007-12-10 2007-12-10 Composição plastificte de pvc

Country Status (9)

Country Link
US (3) US20090149586A1 (pt)
EP (2) EP2070977B1 (pt)
BR (1) BRPI0705621B1 (pt)
CY (1) CY1116883T1 (pt)
DK (2) DK2070977T3 (pt)
ES (2) ES2726175T3 (pt)
PT (2) PT2960282T (pt)
SI (1) SI2070977T1 (pt)
TR (1) TR201906236T4 (pt)

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WO2021154925A1 (en) 2020-01-30 2021-08-05 Cargill, Incorporated Plasticizer composition and process to produce a plasticizer composition

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CA2775993C (en) * 2009-09-30 2017-07-18 Dow Global Technologies Llc Acetylated glycerin esters and their blends with epoxidized fatty acid esters
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BR112015008187B1 (pt) 2012-10-18 2020-10-06 Dow Global Technologies Llc. Processo para fazer um plastificante, composição polimérica e artigo de manufatura
KR102017370B1 (ko) 2012-11-12 2019-09-02 다우 글로벌 테크놀로지스 엘엘씨 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법
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Also Published As

Publication number Publication date
US9388292B2 (en) 2016-07-12
EP2960282A1 (en) 2015-12-30
CY1116883T1 (el) 2017-04-05
EP2960282B1 (en) 2019-02-13
EP2070977B1 (en) 2015-09-23
DK2960282T3 (da) 2019-05-13
TR201906236T4 (tr) 2019-05-21
US20140221538A1 (en) 2014-08-07
PT2070977E (pt) 2016-01-15
ES2726175T3 (es) 2019-10-02
BRPI0705621B1 (pt) 2019-04-09
US20140316038A1 (en) 2014-10-23
US20090149586A1 (en) 2009-06-11
SI2070977T1 (sl) 2015-12-31
EP2070977A2 (en) 2009-06-17
US9303140B2 (en) 2016-04-05
DK2070977T3 (da) 2015-10-05
PT2960282T (pt) 2019-05-27
EP2070977A3 (en) 2010-12-15
ES2555781T3 (es) 2016-01-08

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