TR201906236T4 - Pvc bileşimleri için uygun plastikleştirici bileşim. - Google Patents
Pvc bileşimleri için uygun plastikleştirici bileşim. Download PDFInfo
- Publication number
- TR201906236T4 TR201906236T4 TR2019/06236T TR201906236T TR201906236T4 TR 201906236 T4 TR201906236 T4 TR 201906236T4 TR 2019/06236 T TR2019/06236 T TR 2019/06236T TR 201906236 T TR201906236 T TR 201906236T TR 201906236 T4 TR201906236 T4 TR 201906236T4
- Authority
- TR
- Turkey
- Prior art keywords
- pvc
- epoxidized
- bioesters
- properties
- epoxidation
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 230000021736 acetylation Effects 0.000 abstract 2
- 238000006640 acetylation reaction Methods 0.000 abstract 2
- 238000006735 epoxidation reaction Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000005809 transesterification reaction Methods 0.000 abstract 2
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 2
- 239000008158 vegetable oil Substances 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 239000008037 PVC plasticizer Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000004494 ethyl ester group Chemical group 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
- C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Mevcut açıklayıcı rapor, bitkisel yağların kullanımı ile elde edilenler gibi, yenilenebilir bileşiklere daha düşük maliyet sağlamaya ek olarak, PVC polimerlerinin özelliklerini geliştirmek için oluşturulmuş polimer katkı maddelerinin teknik alanına ait, bitkisel yağların yağ asitlerinin etanol ve gliserin ile kısmi transesterifikasyondan ve dahası asetilasyondan ve epoksidasyondan elde edilmiş olan epoksitlenmiş biyoesterlerinden oluşan PVC plastikleştiricilerin ve kısmi transesterifikasyondan, asetilasyondan ve epoksidasyondan kaynaklanan biyoesterler ile plastikleştirilmiş PVC bileşiklerinin buluşunun patentini ifade etmektedir. Mevcut buluşun epoksitlenmiş biyoesterleri epoksitlenmiş etil esterler ve asetillenmiş ve epoksitlenmiş mono, di ve trigliseril esterlerin karışımı ile oluşur, 8?den az veya eşit oksiran endeksi gösterir. Bu primer plastikleştiriciler tekniğin şimdiki bilinen durumunda öngörülmeyen PVC bileşiğinin özelliklerine geliştirmeler sağlamaktadırlar, örneğin düşük sıcaklıklarda daha iyi fiziksel özellikler, nihai bileşiğin daha esnek olması, reçinenin yüksek karıştırma verimliliği, alifatik çözücülerin ekstresine karşı geliştirilmiş direnç ve UV bozulmasına karşı geliştirilmiş direnç gibi.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0705621-4A BRPI0705621B1 (pt) | 2007-12-10 | 2007-12-10 | Composição plastificte de pvc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR201906236T4 true TR201906236T4 (tr) | 2019-05-21 |
Family
ID=40344406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2019/06236T TR201906236T4 (tr) | 2007-12-10 | 2008-12-09 | Pvc bileşimleri için uygun plastikleştirici bileşim. |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US20090149586A1 (tr) |
| EP (2) | EP2070977B1 (tr) |
| BR (1) | BRPI0705621B1 (tr) |
| CY (1) | CY1116883T1 (tr) |
| DK (2) | DK2960282T3 (tr) |
| ES (2) | ES2555781T3 (tr) |
| PT (2) | PT2070977E (tr) |
| SI (1) | SI2070977T1 (tr) |
| TR (1) | TR201906236T4 (tr) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102007176A (zh) | 2008-02-15 | 2011-04-06 | 联合碳化化学及塑料技术有限责任公司 | 用于邻苯二甲酸酯增塑制剂的替代增塑剂体系 |
| US8552098B2 (en) * | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
| TW201118163A (en) | 2009-09-30 | 2011-06-01 | Dow Global Technologies Inc | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
| TWI607048B (zh) | 2009-09-30 | 2017-12-01 | 陶氏全球科技有限責任公司 | 具有經環氧化之脂肪酸酯塑化劑的熱穩定聚合組成物 |
| EP2470598B1 (en) | 2009-09-30 | 2013-07-17 | Dow Global Technologies LLC | Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters |
| CA2775993C (en) * | 2009-09-30 | 2017-07-18 | Dow Global Technologies Llc | Acetylated glycerin esters and their blends with epoxidized fatty acid esters |
| BR112012017956B1 (pt) | 2010-01-22 | 2020-04-07 | Archer Daniels Midland Co | composição de poli (haleto de vinila) |
| BR112012028732B1 (pt) | 2010-05-10 | 2020-04-07 | Dow Global Technologies Llc | composição e fio ou cabo |
| TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
| WO2012019073A1 (en) * | 2010-08-06 | 2012-02-09 | Arkema Inc. | Epoxidized composition and methods for making the same |
| KR20140000238A (ko) * | 2010-11-05 | 2014-01-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 개선된 전기 특성을 갖는 가소제 시스템 |
| WO2013003225A2 (en) * | 2011-06-29 | 2013-01-03 | Dow Global Technologies Llc | Vegetable-oil derived plasticizer |
| JP6165779B2 (ja) | 2012-02-08 | 2017-07-19 | ダウ グローバル テクノロジーズ エルエルシー | 可塑剤組成物及び可塑剤組成物を製作するための方法 |
| WO2013191812A1 (en) | 2012-06-22 | 2013-12-27 | Dow Global Technologies Llc | Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions |
| EP2864406B1 (en) | 2012-06-26 | 2017-03-08 | Dow Global Technologies LLC | Plasticizers and plasticized polymeric compositions |
| KR101993956B1 (ko) | 2012-10-18 | 2019-06-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법 |
| EP2917275B1 (en) | 2012-11-12 | 2017-12-20 | Dow Global Technologies LLC | Methods for making epoxidized fatty acid alkyl esters |
| KR102017370B1 (ko) | 2012-11-12 | 2019-09-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법 |
| EP2738774A1 (en) | 2012-11-30 | 2014-06-04 | Borealis AG | A cable construction |
| US9586918B2 (en) * | 2013-02-25 | 2017-03-07 | Arkema Inc. | Unsaturated fatty acid ester-based compositions useful as plastic additives |
| US10398625B2 (en) | 2013-03-13 | 2019-09-03 | Fenwal, Inc. | Medical containers with terephthalate plasticizer for storing red blood cell products |
| EP3016938A4 (en) * | 2013-07-01 | 2017-05-24 | Polymer Additives, Inc. | Biobased epoxidized fatty acid ester plasticizers |
| KR102554521B1 (ko) | 2014-02-20 | 2023-07-11 | 프레제니우스 카비 도이치란트 게엠베하 | 적혈구 제품, 혈장 및 혈소판의 보관을 위한 비-dehp 가소제를 갖는 의료용 컨테이너 및 시스템 구성요소 |
| EP3124540B1 (en) * | 2014-03-27 | 2020-12-23 | New Japan Chemical Co., Ltd. | Plasticizer for vinyl chloride resin containing non-phthalate ester and vinyl chloride resin composition containing such plasticizer |
| EP2924063A1 (de) * | 2014-03-28 | 2015-09-30 | LANXESS Deutschland GmbH | Weichmacherzusammensetzung |
| US10087346B2 (en) | 2014-05-13 | 2018-10-02 | Magink Comérico Imagem Gráfica Ltda.—Me | Dispersion of homopolymer of vinyl chloride |
| SI24879A (sl) | 2014-11-06 | 2016-05-31 | Eurel D.O.O. | Postopek za izdelavo oplaščenih vodilnih cevi, ki ne bodo vsebovale ftalatov, in oplaščene vodilne cevi narejene po tem postopku |
| EP3369771B1 (en) * | 2015-10-27 | 2021-06-09 | LG Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| CN106519081B (zh) * | 2016-09-22 | 2018-06-26 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
| CN108863987B (zh) * | 2018-07-25 | 2020-10-30 | 浙江工业大学 | 一种利用表面活性剂强化油脂环氧化的生产方法 |
| CN110804029B (zh) * | 2019-11-08 | 2022-04-29 | 浙江工业大学 | 一种环氧类增塑剂及其制备方法 |
| WO2021154925A1 (en) | 2020-01-30 | 2021-08-05 | Cargill, Incorporated | Plasticizer composition and process to produce a plasticizer composition |
| CN111234421B (zh) * | 2020-03-31 | 2021-11-02 | 安徽和佳医疗用品科技有限公司 | 一种具有抑菌功能的pvc手套及其制备方法 |
| CN113817226B (zh) * | 2021-10-12 | 2022-05-10 | 南京工业大学 | 一种高分子复合材料添加剂及其应用 |
| CN115433363A (zh) * | 2022-09-30 | 2022-12-06 | 明达光电(厦门)有限公司 | 一种复合植物油增塑剂及其制备方法与应用 |
| CN118325196B (zh) * | 2024-03-12 | 2026-03-03 | 广东联塑科技实业有限公司 | 一种pvc电线管添加剂及其应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT518189A (tr) * | 1953-07-15 | |||
| US2895966A (en) * | 1954-04-12 | 1959-07-21 | Waldo C Ault | Monoglyceride diacetates |
| US3281382A (en) * | 1956-08-27 | 1966-10-25 | Swift & Co | Halogenated polymers containing complex epoxy fatty esters |
| US3070608A (en) * | 1958-07-07 | 1962-12-25 | Swift & Co | Selective alcoholysis of epoxy fatty acid esters |
| GB934689A (en) | 1959-04-22 | 1963-08-21 | Swift & Co | Epoxy fatty acid esters and polyvinyl resin compositions containing them |
| US3377304A (en) * | 1959-04-22 | 1968-04-09 | Swift & Co | High oxirane fatty esters |
| DE2652328A1 (de) | 1976-11-17 | 1978-05-18 | Neynaber Chemie Gmbh | Bleiverbindungen enthaltende stabilisator-gleitmittel-kombination fuer formmassen auf basis von polyvinylchlorid |
| US4605694A (en) | 1985-10-31 | 1986-08-12 | Hercules Incorporated | Plasticizing compositions for polyvinylchloride |
| US5886072A (en) | 1993-05-24 | 1999-03-23 | Teknor Apex Company | Flame retardant composition |
| US5430108A (en) | 1994-01-14 | 1995-07-04 | Exxon Chemical Patents Inc. | Polyol ester PVC plasticizers |
| US6797753B2 (en) | 2000-06-20 | 2004-09-28 | Battelle Memorial Institute | Plasticizers derived from vegetable oils |
| DE10104815A1 (de) * | 2001-02-01 | 2002-08-08 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von epoxidierten Glyceridacetaten |
| EP2470596B1 (en) * | 2009-09-30 | 2013-07-17 | Dow Global Technologies LLC | Acetylated polyglycerine fatty acid ester and a pvc insulator plasticised therewith |
-
2007
- 2007-12-10 BR BRPI0705621-4A patent/BRPI0705621B1/pt active IP Right Grant
-
2008
- 2008-12-09 ES ES08021385.3T patent/ES2555781T3/es active Active
- 2008-12-09 PT PT80213853T patent/PT2070977E/pt unknown
- 2008-12-09 ES ES15002306T patent/ES2726175T3/es active Active
- 2008-12-09 PT PT15002306T patent/PT2960282T/pt unknown
- 2008-12-09 SI SI200831529T patent/SI2070977T1/sl unknown
- 2008-12-09 DK DK15002306.7T patent/DK2960282T3/da active
- 2008-12-09 DK DK08021385.3T patent/DK2070977T3/da active
- 2008-12-09 TR TR2019/06236T patent/TR201906236T4/tr unknown
- 2008-12-09 US US12/331,092 patent/US20090149586A1/en not_active Abandoned
- 2008-12-09 EP EP08021385.3A patent/EP2070977B1/en not_active Not-in-force
- 2008-12-09 EP EP15002306.7A patent/EP2960282B1/en active Active
-
2014
- 2014-01-06 US US14/148,312 patent/US9303140B2/en active Active
- 2014-03-24 US US14/223,090 patent/US9388292B2/en active Active
-
2015
- 2015-10-07 CY CY20151100898T patent/CY1116883T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0705621A2 (pt) | 2009-08-18 |
| US9388292B2 (en) | 2016-07-12 |
| CY1116883T1 (el) | 2017-04-05 |
| PT2960282T (pt) | 2019-05-27 |
| ES2726175T3 (es) | 2019-10-02 |
| DK2070977T3 (da) | 2015-10-05 |
| EP2070977A2 (en) | 2009-06-17 |
| DK2960282T3 (da) | 2019-05-13 |
| PT2070977E (pt) | 2016-01-15 |
| ES2555781T3 (es) | 2016-01-08 |
| EP2070977B1 (en) | 2015-09-23 |
| US20090149586A1 (en) | 2009-06-11 |
| BRPI0705621B1 (pt) | 2019-04-09 |
| SI2070977T1 (sl) | 2015-12-31 |
| US9303140B2 (en) | 2016-04-05 |
| US20140316038A1 (en) | 2014-10-23 |
| EP2960282B1 (en) | 2019-02-13 |
| US20140221538A1 (en) | 2014-08-07 |
| EP2960282A1 (en) | 2015-12-30 |
| EP2070977A3 (en) | 2010-12-15 |
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