BRPI0707874B1 - composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida - Google Patents

composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida Download PDF

Info

Publication number: BRPI0707874B1
Authority: BR; Brazil
Prior art keywords: emulsifier; pesticide; composition; pesticidal; weight
Prior art date: 2006-02-15

Application number

BRPI0707874A

Other languages

English (en)

Portuguese (pt)

Inventor

Alefesh Hailu

Michael P Pompeo

Original Assignee

Cognis Ip Man Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-02-15

Filing date

2007-02-13

Publication date

2016-12-06

2007-02-13 Application filed by Cognis Ip Man Gmbh filed Critical Cognis Ip Man Gmbh

2011-05-10 Publication of BRPI0707874A2 publication Critical patent/BRPI0707874A2/pt

2016-12-06 Publication of BRPI0707874B1 publication Critical patent/BRPI0707874B1/pt

Links

239000000203 mixture Substances 0.000 title claims abstract description 80
239000003995 emulsifying agent Substances 0.000 title claims abstract description 42
239000002671 adjuvant Substances 0.000 title claims abstract description 30
230000000361 pesticidal effect Effects 0.000 title claims abstract description 21
238000009472 formulation Methods 0.000 title claims abstract description 13
239000004094 surface-active agent Substances 0.000 claims abstract description 39
239000002904 solvent Substances 0.000 claims abstract description 31
239000002736 nonionic surfactant Substances 0.000 claims abstract description 25
239000003945 anionic surfactant Substances 0.000 claims abstract description 18
239000000575 pesticide Substances 0.000 claims description 59
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 19
230000001804 emulsifying effect Effects 0.000 claims description 18
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 15
229920001400 block copolymer Polymers 0.000 claims description 8
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 7
230000002209 hydrophobic effect Effects 0.000 claims description 4
229920005604 random copolymer Polymers 0.000 claims description 4
WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 2
239000005949 Malathion Substances 0.000 claims description 2
239000005627 Triclopyr Substances 0.000 claims description 2
HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 2
JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 2
229960000453 malathion Drugs 0.000 claims description 2
229920002994 synthetic fiber Polymers 0.000 claims description 2
REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 claims description 2
239000012141 concentrate Substances 0.000 abstract description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 40
-1 alkyl benzenesulfonate Chemical compound 0.000 description 21
239000000839 emulsion Substances 0.000 description 13
239000003090 pesticide formulation Substances 0.000 description 13
239000003921 oil Substances 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
239000000463 material Substances 0.000 description 9
238000002156 mixing Methods 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
229940077388 benzenesulfonate Drugs 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
229920001577 copolymer Polymers 0.000 description 6
238000000034 method Methods 0.000 description 6
239000003960 organic solvent Substances 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
239000000243 solution Substances 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N Butanol Natural products CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
238000004945 emulsification Methods 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
239000003208 petroleum Substances 0.000 description 4
238000000926 separation method Methods 0.000 description 4
239000007787 solid Substances 0.000 description 4
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
241000607479 Yersinia pestis Species 0.000 description 3
230000002411 adverse Effects 0.000 description 3
239000006071 cream Substances 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
239000004495 emulsifiable concentrate Substances 0.000 description 3
229940050906 magnesium chloride hexahydrate Drugs 0.000 description 3
DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000004703 alkoxides Chemical group 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
229930182470 glycoside Natural products 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000011344 liquid material Substances 0.000 description 2
238000001223 reverse osmosis Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011343 solid material Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000003643 water by type Substances 0.000 description 2
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 1
206010067484 Adverse reaction Diseases 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000005946 Cypermethrin Substances 0.000 description 1
229920005682 EO-PO block copolymer Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000005769 Etridiazole Substances 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
239000004147 Sorbitan trioleate Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000001241 acetals Chemical class 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
230000000570 adjustive effect Effects 0.000 description 1
230000006838 adverse reaction Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
150000008052 alkyl sulfonates Chemical class 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
229960005424 cypermethrin Drugs 0.000 description 1
KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
125000004494 ethyl ester group Chemical group 0.000 description 1
KQTVWCSONPJJPE-UHFFFAOYSA-N etridiazole Chemical compound CCOC1=NC(C(Cl)(Cl)Cl)=NS1 KQTVWCSONPJJPE-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
230000002363 herbicidal effect Effects 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
239000002917 insecticide Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
229940073769 methyl oleate Drugs 0.000 description 1
230000035515 penetration Effects 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000003389 potentiating effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
229960000391 sorbitan trioleate Drugs 0.000 description 1
235000019337 sorbitan trioleate Nutrition 0.000 description 1
230000003068 static effect Effects 0.000 description 1
229920006301 statistical copolymer Polymers 0.000 description 1
239000004558 technical concentrate Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/16—Agglomerates; Granulates; Microbeadlets ; Microspheres; Pellets; Solid products obtained by spray drying, spray freeze drying, spray congealing,(multiple) emulsion solvent evaporation or extraction
- A61K9/1605—Excipients; Inactive ingredients
- A61K9/1629—Organic macromolecular compounds

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Zoology (AREA)
Plant Pathology (AREA)
Pest Control & Pesticides (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Agronomy & Crop Science (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Chemical & Material Sciences (AREA)
Bioinformatics & Cheminformatics (AREA)
Medicinal Chemistry (AREA)
Pharmacology & Pharmacy (AREA)
Epidemiology (AREA)
Animal Behavior & Ethology (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Dispersion Chemistry (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

BRPI0707874A 2006-02-15 2007-02-13 composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida BRPI0707874B1 (pt)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US77358006P	2006-02-15	2006-02-15
US60/773,580		2006-02-15
US11/600,991		2006-11-17
US11/600,991 US9072294B2 (en)	2006-02-15	2006-11-17	Emulsifier system and pesticidal formulations containing the emulsifier system
PCT/US2007/003658 WO2007095163A2 (fr)	2006-02-15	2007-02-13	Systeme emulsifiant et formulations pesticides le contenant

Publications (2)

Publication Number	Publication Date
BRPI0707874A2 BRPI0707874A2 (pt)	2011-05-10
BRPI0707874B1 true BRPI0707874B1 (pt)	2016-12-06

Family

ID=38369402

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI0707874A BRPI0707874B1 (pt)	2006-02-15	2007-02-13	composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida

Country Status (6)

Country	Link
US (1)	US9072294B2 (fr)
EP (1)	EP1996016A4 (fr)
CN (1)	CN101389217B (fr)
BR (1)	BRPI0707874B1 (fr)
CA (1)	CA2642339C (fr)
WO (1)	WO2007095163A2 (fr)

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MY172146A (en) *	2012-05-16	2019-11-14	Bayer Cropscience Ag	Insecticidal water-in-oil (w/o) formulation
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AU2015218092B2 (en) *	2014-02-14	2017-09-21	Nanjing Scienx Biological Technology Co., Ltd.	Environmentally-friendly emamectin benzoate preparation and preparation method therefor
CN108135159A (zh) *	2015-10-21	2018-06-08	巴斯夫欧洲公司	液体农药组合物
CN119486595A (zh) *	2021-02-16	2025-02-18	帕瑞亚特工业(印度)私人有限公司	恶唑酰草胺的协同除草组合物
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US7651977B2 (en)	2004-10-28	2010-01-26	Valent U.S.A. Corporation	Herbicidal compositions
EP1809308B1 (fr)	2004-11-08	2011-05-18	Oro-Agri, Inc.	Formule d'additif pour herbicides, pesticides, insecticides, ovicides et fongicides et méthode d'emploi de ladite formule
US20060183642A1 (en) *	2005-02-16	2006-08-17	Sumitomo Chemical Company, Limited	Herbicidal composition
AU2006224071B2 (en)	2005-03-14	2012-04-12	Ishihara Sangyo Kaisha, Ltd.	Herbicidal suspension
WO2007030886A1 (fr)	2005-09-16	2007-03-22	Nufarm Australia Limited	Melanges herbicides et leur processus de preparation

2006
- 2006-11-17 US US11/600,991 patent/US9072294B2/en active Active
2007
- 2007-02-13 BR BRPI0707874A patent/BRPI0707874B1/pt active IP Right Grant
- 2007-02-13 WO PCT/US2007/003658 patent/WO2007095163A2/fr not_active Ceased
- 2007-02-13 CA CA2642339A patent/CA2642339C/fr active Active
- 2007-02-13 EP EP07750491A patent/EP1996016A4/fr not_active Withdrawn
- 2007-02-13 CN CN200780006889.2A patent/CN101389217B/zh not_active Expired - Fee Related

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Publication number	Publication date
WO2007095163A2 (fr)	2007-08-23
CA2642339C (fr)	2014-06-10
US9072294B2 (en)	2015-07-07
EP1996016A4 (fr)	2012-09-26
CN101389217B (zh)	2013-03-13
CN101389217A (zh)	2009-03-18
US20070191230A1 (en)	2007-08-16
CA2642339A1 (fr)	2007-08-23
WO2007095163A3 (fr)	2007-12-27
BRPI0707874A2 (pt)	2011-05-10
EP1996016A2 (fr)	2008-12-03

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2016-05-31	B06A	Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law
2016-09-20	B09A	Decision: intention to grant
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