BRPI0707874B1 - composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida - Google Patents
composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida Download PDFInfo
- Publication number
- BRPI0707874B1 BRPI0707874B1 BRPI0707874A BRPI0707874A BRPI0707874B1 BR PI0707874 B1 BRPI0707874 B1 BR PI0707874B1 BR PI0707874 A BRPI0707874 A BR PI0707874A BR PI0707874 A BRPI0707874 A BR PI0707874A BR PI0707874 B1 BRPI0707874 B1 BR PI0707874B1
- Authority
- BR
- Brazil
- Prior art keywords
- emulsifier
- pesticide
- composition
- pesticidal
- weight
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 42
- 239000002671 adjuvant Substances 0.000 title claims abstract description 30
- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 21
- 238000009472 formulation Methods 0.000 title claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 39
- 239000002904 solvent Substances 0.000 claims abstract description 31
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 25
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
- 239000000575 pesticide Substances 0.000 claims description 59
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 19
- 230000001804 emulsifying effect Effects 0.000 claims description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 15
- 229920001400 block copolymer Polymers 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 229920005604 random copolymer Polymers 0.000 claims description 4
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005949 Malathion Substances 0.000 claims description 2
- 239000005627 Triclopyr Substances 0.000 claims description 2
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 2
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 2
- 229960000453 malathion Drugs 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 40
- -1 alkyl benzenesulfonate Chemical compound 0.000 description 21
- 239000000839 emulsion Substances 0.000 description 13
- 239000003090 pesticide formulation Substances 0.000 description 13
- 239000003921 oil Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N Butanol Natural products CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000004495 emulsifiable concentrate Substances 0.000 description 3
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 3
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000004703 alkoxides Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 238000001223 reverse osmosis Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005769 Etridiazole Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000570 adjustive effect Effects 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- KQTVWCSONPJJPE-UHFFFAOYSA-N etridiazole Chemical compound CCOC1=NC(C(Cl)(Cl)Cl)=NS1 KQTVWCSONPJJPE-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 239000004558 technical concentrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/16—Agglomerates; Granulates; Microbeadlets ; Microspheres; Pellets; Solid products obtained by spray drying, spray freeze drying, spray congealing,(multiple) emulsion solvent evaporation or extraction
- A61K9/1605—Excipients; Inactive ingredients
- A61K9/1629—Organic macromolecular compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Pharmacology & Pharmacy (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Medicinal Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77358006P | 2006-02-15 | 2006-02-15 | |
| US60/773,580 | 2006-02-15 | ||
| US11/600,991 US9072294B2 (en) | 2006-02-15 | 2006-11-17 | Emulsifier system and pesticidal formulations containing the emulsifier system |
| US11/600,991 | 2006-11-17 | ||
| PCT/US2007/003658 WO2007095163A2 (fr) | 2006-02-15 | 2007-02-13 | Systeme emulsifiant et formulations pesticides le contenant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0707874A2 BRPI0707874A2 (pt) | 2011-05-10 |
| BRPI0707874B1 true BRPI0707874B1 (pt) | 2016-12-06 |
Family
ID=38369402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0707874A BRPI0707874B1 (pt) | 2006-02-15 | 2007-02-13 | composição emulsificante e adjuvante para uma formulação pesticida, e composição pesticida |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9072294B2 (fr) |
| EP (1) | EP1996016A4 (fr) |
| CN (1) | CN101389217B (fr) |
| BR (1) | BRPI0707874B1 (fr) |
| CA (1) | CA2642339C (fr) |
| WO (1) | WO2007095163A2 (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX336009B (es) * | 2009-04-30 | 2016-01-07 | Cheminova As | Formulaciones de dimetoato bajas en voc. |
| EP2305030A1 (fr) * | 2009-09-14 | 2011-04-06 | Bayer CropScience AG | Alkyl-polypropylène-glycol comprenant des compositions agrochimiques |
| EP2603075B1 (fr) * | 2010-08-10 | 2017-07-12 | Rhodia Operations | Compositions pesticides agricoles |
| PE20142455A1 (es) * | 2012-05-16 | 2015-01-17 | Bayer Cropscience Ag | Formulacion insecticida de agua en aceite (ag/ac) |
| HK1212154A1 (en) * | 2012-09-04 | 2016-06-10 | Dow Agrosciences Llc | Compositions and methods for improving the compatibility of water soluble herbicide salts |
| EP3027018A1 (fr) * | 2013-07-31 | 2016-06-08 | Akzo Nobel Chemicals International B.V. | Composition de sulfonate d'alkylbenzène liquide sans solvant et son utilisation dans des formulations agrochimiques |
| EP3106031B1 (fr) * | 2014-02-14 | 2019-11-06 | Nanjing Scienx Biological Technology Co., Ltd. | Préparation de benzoate d'émamectine respectueuse de l'environnement et son procédé de préparation |
| EP3364756B1 (fr) * | 2015-10-21 | 2021-12-08 | Basf Se | Composition pesticide liquide |
| WO2022175808A1 (fr) * | 2021-02-16 | 2022-08-25 | Parijat Industries (India) Private Limited | COMPOSITIONS HERBICIDES SYNERGIQUES DE MÉTAMIFOP <u /> |
| EP4566448A1 (fr) | 2023-12-07 | 2025-06-11 | Basf Se | Combinaison de tensioactifs |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2861108A (en) * | 1953-06-30 | 1958-11-18 | Olin Mathieson | Production of polyethyenoxy alkyl phenate ethers |
| US4195083A (en) * | 1968-09-11 | 1980-03-25 | Emby Gordon N | Veterinary compositions and method for controlling anthropod ectoparasites |
| US4450001A (en) * | 1980-02-19 | 1984-05-22 | Basf Wyandotte Corporation | Anionic biocide emulsions in aqueous solutions of strongly ionizable salts |
| US4931086A (en) * | 1982-03-05 | 1990-06-05 | Moucharafieh Nadim C | Thiolcarbamate-triazine liquid herbicide composition |
| JPS6084201A (ja) * | 1983-10-14 | 1985-05-13 | Kao Corp | 殺生剤乳剤組成物 |
| DE3685920D1 (de) * | 1985-09-13 | 1992-08-13 | Ciba Geigy Ag | Verfahren zur herstellung von mikrokapseln. |
| US4966728A (en) | 1988-08-26 | 1990-10-30 | Basf Corporation | Adjuvants for use with postemergent herbicides |
| US5084087A (en) * | 1989-04-26 | 1992-01-28 | Basf Corporation | Ready to dilute adjuvant-containing postemergent herbicide formulations |
| US5834006A (en) * | 1990-04-05 | 1998-11-10 | Dow Agrosciences Llc | Latex-based agricultural compositions |
| US5558806A (en) * | 1992-07-23 | 1996-09-24 | Osi Specialties, Inc. | Surfactant blend of a polyalkleneoxide polysiloxane and an organic compound having a short chain hydrophobic moiety |
| US5466659A (en) * | 1993-01-15 | 1995-11-14 | Dowelanco | Triclopyr butoxyethyl ester compositions comprising vegetable oil esters as carriers |
| CA2120375A1 (fr) * | 1993-04-02 | 1994-10-03 | John Klier | Produit de pretraitement pour la lessive a proprietes nettoyantes ameliorees pour les souillures huileuses |
| GB9315501D0 (en) * | 1993-07-27 | 1993-09-08 | Ici Plc | Surfactant compositions |
| US5500219A (en) * | 1993-09-21 | 1996-03-19 | Basf Corporation | Pesticide compositions containing blends of block copolymers with anionic surfactants having improved dissolution rates |
| GB9414318D0 (en) * | 1994-07-15 | 1994-09-07 | Dowelanco Ltd | Preparation of aqueous emulsions |
| IT1275167B (it) * | 1995-02-23 | 1997-07-30 | Isagro Spa | Adiuvanti per fungicidi sistemici composizioni fungicide che li contengono e loro impiego |
| AU4392597A (en) | 1996-09-25 | 1998-04-17 | Rhone-Poulenc, Inc. | Spontaneously water dispersible carrier for pesticides |
| JPH10130104A (ja) * | 1996-11-01 | 1998-05-19 | Sumitomo Chem Co Ltd | 農薬乳剤 |
| TW460508B (en) * | 1997-05-02 | 2001-10-21 | Rohm & Haas | Aqueous composition comprising a mixed surfactant/associative thickener, its use in a formulated composition, and method for enhancing thickening efficiency of aqueous composition |
| US6432884B1 (en) * | 1997-12-08 | 2002-08-13 | Cognis Corporation | Agricultural adjuvant |
| AU739286B2 (en) * | 1998-03-09 | 2001-10-11 | Monsanto Technology Llc | Concentrate herbicidal composition |
| US6143830A (en) * | 1998-08-17 | 2000-11-07 | Basf Corporation | Emulsifier composition comprising ethylene oxide/propylene oxide block copolymers and amine-containing ethylene oxide/propylene oxide block copolymers |
| US6566308B1 (en) * | 1999-01-29 | 2003-05-20 | Basf Aktiengesellschaft | Emulsifiable concentrate containing one or more pesticides and adjuvants |
| US20050124738A1 (en) * | 1999-05-26 | 2005-06-09 | The Procter & Gamble Company | Compositions and methods for using zwitterionic polymeric suds enhancers |
| WO2001082694A1 (fr) * | 2000-04-28 | 2001-11-08 | Ecolab Inc. | Composition antimicrobienne |
| DE10035930A1 (de) * | 2000-07-21 | 2002-01-31 | Clariant Gmbh | Feinemulsionen |
| EP1318720A2 (fr) * | 2000-09-14 | 2003-06-18 | Stepan Company | Melange de tensio-actifs ternaires antimicrobiens comprenant des tensio-actifs cationiques, anioniques et de pontage, et procedes de preparation |
| US6831038B2 (en) * | 2001-02-20 | 2004-12-14 | Helena Holding Company | Agricultural formulation |
| EP1424106A1 (fr) | 2002-09-27 | 2004-06-02 | Vib Line Establishment | Connecteur de golf swing et rotation des hanches |
| AU2004100006A4 (en) | 2003-01-06 | 2004-03-11 | Nufarm Australia Limited | Herbicidal composition |
| CN1449660A (zh) * | 2003-04-25 | 2003-10-22 | 内蒙古宏裕农药股份有限公司 | 乙草胺无溶剂乳油 |
| US7651977B2 (en) | 2004-10-28 | 2010-01-26 | Valent U.S.A. Corporation | Herbicidal compositions |
| US20080214400A1 (en) | 2004-11-08 | 2008-09-04 | Erroll Pullen | Adjuvant Composition for use with Herbicides, Pesticides, Insecticides, Ovicides and Fungicides and Method of Application |
| US20060183642A1 (en) * | 2005-02-16 | 2006-08-17 | Sumitomo Chemical Company, Limited | Herbicidal composition |
| MEP10208A (en) | 2005-03-14 | 2010-06-10 | Ishihara Sangyo Kaisha | Herbicidal suspension |
| WO2007030886A1 (fr) | 2005-09-16 | 2007-03-22 | Nufarm Australia Limited | Melanges herbicides et leur processus de preparation |
-
2006
- 2006-11-17 US US11/600,991 patent/US9072294B2/en active Active
-
2007
- 2007-02-13 CN CN200780006889.2A patent/CN101389217B/zh not_active Expired - Fee Related
- 2007-02-13 EP EP07750491A patent/EP1996016A4/fr not_active Withdrawn
- 2007-02-13 CA CA2642339A patent/CA2642339C/fr active Active
- 2007-02-13 BR BRPI0707874A patent/BRPI0707874B1/pt active IP Right Grant
- 2007-02-13 WO PCT/US2007/003658 patent/WO2007095163A2/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20070191230A1 (en) | 2007-08-16 |
| WO2007095163A2 (fr) | 2007-08-23 |
| CN101389217B (zh) | 2013-03-13 |
| EP1996016A4 (fr) | 2012-09-26 |
| CA2642339A1 (fr) | 2007-08-23 |
| CA2642339C (fr) | 2014-06-10 |
| US9072294B2 (en) | 2015-07-07 |
| EP1996016A2 (fr) | 2008-12-03 |
| WO2007095163A3 (fr) | 2007-12-27 |
| CN101389217A (zh) | 2009-03-18 |
| BRPI0707874A2 (pt) | 2011-05-10 |
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| B07A | Technical examination (opinion): publication of technical examination (opinion) | ||
| B06A | Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law | ||
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/02/2007, OBSERVADAS AS CONDICOES LEGAIS. |