BRPI0714518B8 - método para produzir um catalisador altamente estável para hidrodessulfurização de hidrocarbonetos pesados e processo para dessulfurizar um suprimento de hidrocarbonetos pesados - Google Patents

método para produzir um catalisador altamente estável para hidrodessulfurização de hidrocarbonetos pesados e processo para dessulfurizar um suprimento de hidrocarbonetos pesados

Info

Publication number
BRPI0714518B8
BRPI0714518B8 BRPI0714518A BRPI0714518A BRPI0714518B8 BR PI0714518 B8 BRPI0714518 B8 BR PI0714518B8 BR PI0714518 A BRPI0714518 A BR PI0714518A BR PI0714518 A BRPI0714518 A BR PI0714518A BR PI0714518 B8 BRPI0714518 B8 BR PI0714518B8
Authority
BR
Brazil
Prior art keywords
heavy hydrocarbon
hydrocarbon supply
catalyst
producing
mixture
Prior art date
Application number
BRPI0714518A
Other languages
English (en)
Inventor
Kishan Bhan Opinder
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of BRPI0714518A2 publication Critical patent/BRPI0714518A2/pt
Publication of BRPI0714518B1 publication Critical patent/BRPI0714518B1/pt
Publication of BRPI0714518B8 publication Critical patent/BRPI0714518B8/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Light Guides In General And Applications Therefor (AREA)

Abstract

catalisador altamente estável para hidrodessulfuração de hidrocarbonetos pesados, métodos para a sua fabricação e utilização e processo para dessulfuração de suprimento de hidrocarbonetos pesados. é descrito um catalisador útil no hidroprocessamento de um suprimento de hidro-carbonetos pesados em que o catalisador compreende uma mistura calcinada produzida mediante calcinar uma partícula formada de uma mistura compreendendo triáxido de molibdênio, um composto de níquel, e um material óxido inorgânico. o catalisador pode produzido mediante misturar um material óxido inorgânico, triáxido de molibdênio, e um composto de níquel para formar uma mistura que é transformada na forma de uma partícula e calcinada para proporcionar uma mistura calcinada. o processo envolve a hidrodessulfuração e hidro-conversão de um suprimento de hidrocarbonetos pesados processo esse que pode incluir a conversão de uma parcela do teor de asfalto do suprimento de hidrocarbonetos pesados e a produção de um produto tratado possuindo uma aprimorada estabilidade como refletido por seu valor-p.
BRPI0714518A 2006-08-03 2007-08-01 método para produzir um catalisador altamente estável para hidrodessulfurização de hidrocarbonetos pesados e processo para dessulfurizar um suprimento de hidrocarbonetos pesados BRPI0714518B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US82134106P 2006-08-03 2006-08-03
US60/821.341 2006-08-03
PCT/US2007/074961 WO2008016969A2 (en) 2006-08-03 2007-08-01 A highly stable heavy hydrocarbon hydrodesulfurization catalyst and methods of making and use thereof

Publications (3)

Publication Number Publication Date
BRPI0714518A2 BRPI0714518A2 (pt) 2013-07-02
BRPI0714518B1 BRPI0714518B1 (pt) 2017-03-28
BRPI0714518B8 true BRPI0714518B8 (pt) 2017-05-16

Family

ID=38961881

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0714518A BRPI0714518B8 (pt) 2006-08-03 2007-08-01 método para produzir um catalisador altamente estável para hidrodessulfurização de hidrocarbonetos pesados e processo para dessulfurizar um suprimento de hidrocarbonetos pesados

Country Status (9)

Country Link
US (2) US7820036B2 (pt)
EP (1) EP2049252B1 (pt)
JP (2) JP2009545442A (pt)
CN (1) CN101511470B (pt)
BR (1) BRPI0714518B8 (pt)
CA (1) CA2659752C (pt)
DK (1) DK2049252T3 (pt)
RU (1) RU2443472C2 (pt)
WO (1) WO2008016969A2 (pt)

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Also Published As

Publication number Publication date
CN101511470A (zh) 2009-08-19
DK2049252T3 (da) 2020-08-03
US7871513B1 (en) 2011-01-18
JP2013056333A (ja) 2013-03-28
CN101511470B (zh) 2013-07-10
US20100326890A1 (en) 2010-12-30
EP2049252B1 (en) 2020-05-27
WO2008016969A3 (en) 2008-03-27
WO2008016969A2 (en) 2008-02-07
CA2659752C (en) 2015-12-22
BRPI0714518A2 (pt) 2013-07-02
RU2443472C2 (ru) 2012-02-27
US20080135453A1 (en) 2008-06-12
JP5694264B2 (ja) 2015-04-01
BRPI0714518B1 (pt) 2017-03-28
JP2009545442A (ja) 2009-12-24
CA2659752A1 (en) 2008-02-07
US7820036B2 (en) 2010-10-26
RU2009107513A (ru) 2010-09-10
EP2049252A2 (en) 2009-04-22

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