BRPI0721866A2 - "sistema catalisador para oligomerização seletiva de etileno, método para produzir 1-hexeno mediante a trimerização seletiva de etileno e método para produzir 1-octeno mediante a tetramerização seletiva de etileno" - Google Patents
"sistema catalisador para oligomerização seletiva de etileno, método para produzir 1-hexeno mediante a trimerização seletiva de etileno e método para produzir 1-octeno mediante a tetramerização seletiva de etileno"Info
- Publication number
- BRPI0721866A2 BRPI0721866A2 BRPI0721866-4A2A BRPI0721866A BRPI0721866A2 BR PI0721866 A2 BRPI0721866 A2 BR PI0721866A2 BR PI0721866 A BRPI0721866 A BR PI0721866A BR PI0721866 A2 BRPI0721866 A2 BR PI0721866A2
- Authority
- BR
- Brazil
- Prior art keywords
- selective ethylene
- producing
- hylene
- selective
- catalyst system
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 3
- 239000005977 Ethylene Substances 0.000 title 3
- 238000004519 manufacturing process Methods 0.000 title 2
- 239000003054 catalyst Substances 0.000 title 1
- 238000006384 oligomerization reaction Methods 0.000 title 1
- 238000005829 trimerization reaction Methods 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
- B01J2531/002—Materials
- B01J2531/007—Promoter-type Additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/107—Alkenes with six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070082457A KR101057576B1 (ko) | 2007-08-16 | 2007-08-16 | 선택적 에틸렌 올리머고화 촉매계 |
| PCT/KR2007/006797 WO2009022770A1 (en) | 2007-08-16 | 2007-12-24 | Ethylene oligomerization catalyst systems having enhanced selectivity |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0721866A2 true BRPI0721866A2 (pt) | 2014-02-18 |
| BRPI0721866A8 BRPI0721866A8 (pt) | 2017-12-26 |
| BRPI0721866B1 BRPI0721866B1 (pt) | 2018-10-09 |
Family
ID=40350812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0721866A BRPI0721866B1 (pt) | 2007-08-16 | 2007-12-24 | método para produzir 1-hexeno mediante a trimerização seletiva de etileno e método para produzir 1-octeno mediante a tetramerização seletiva de etileno |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8309779B2 (pt) |
| JP (1) | JP2010536538A (pt) |
| KR (1) | KR101057576B1 (pt) |
| CN (1) | CN102083867B (pt) |
| BR (1) | BRPI0721866B1 (pt) |
| CA (1) | CA2694065C (pt) |
| RU (1) | RU2456077C2 (pt) |
| WO (1) | WO2009022770A1 (pt) |
Families Citing this family (48)
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|---|---|---|---|---|
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
| MY161612A (en) | 2009-10-16 | 2017-04-28 | Sasol Tech (Proprietary) Ltd | Separation of components from a multi-component hydrocarbon stream which includes ethylene |
| SG174116A1 (en) * | 2010-03-03 | 2011-10-28 | Sk Innovation Co Ltd | Highly active and selective ethylene oligomerization catalyst and method of preparing hexene or octene using the same |
| KR101471156B1 (ko) * | 2011-06-14 | 2014-12-10 | 주식회사 엘지화학 | 선택적 에틸렌 올리고머화 촉매계 |
| KR101846031B1 (ko) * | 2012-03-16 | 2018-04-05 | 에스케이이노베이션 주식회사 | 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계 |
| SG11201407269TA (en) | 2012-05-09 | 2014-12-30 | Sasol Tech Pty Ltd | A process for oligomerising a hydrocarbon to form at least one co-monomer product |
| KR102057361B1 (ko) | 2012-05-09 | 2019-12-18 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 다성분 탄화수소 스트림으로부터의 성분의 분리 |
| SG11201407130XA (en) | 2012-05-09 | 2014-11-27 | Sasol Tech Pty Ltd | Tetramerisation of ethylene |
| ES2750659T3 (es) | 2012-05-09 | 2020-03-26 | Sasol Tech Pty Ltd | Tetramerización de etileno |
| KR101513145B1 (ko) * | 2012-05-10 | 2015-04-17 | 주식회사 엘지화학 | 리간드 화합물, 크롬 화합물 및 이를 포함하는 촉매계 |
| KR101483248B1 (ko) | 2012-11-15 | 2015-01-16 | 주식회사 엘지화학 | 리간드 화합물, 유기크롬 화합물, 에틸렌 올리고머화용 촉매계, 이의 제조 방법 및 이를 이용한 에틸렌 올리고머화 방법 |
| RU2525118C1 (ru) * | 2013-03-28 | 2014-08-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитическая система процесса тримеризации этилена в альфа-олефины |
| CN105263890B (zh) | 2013-05-09 | 2017-12-05 | 沙索技术有限公司 | 乙烯的四聚方法 |
| KR102663266B1 (ko) | 2013-05-09 | 2024-05-03 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 에틸렌의 1-헥센 및 1-옥텐의 혼합물로의 올리고머화 방법 |
| WO2014181247A1 (en) | 2013-05-09 | 2014-11-13 | Sasol Technology (Proprietary) Limited | Oligomerisation of ethylene to mixtures of 1-hexene and 1-octene |
| RU2549833C1 (ru) * | 2014-02-18 | 2015-04-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитический комплекс селективной тримеризации этилена в 1-гексен |
| CN106164103B (zh) | 2014-06-18 | 2018-05-25 | 株式会社Lg化学 | 配体化合物、有机铬化合物、用于烯烃低聚的催化剂体系以及使用所述催化剂体系的用于烯烃低聚的方法 |
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| CN105562096B (zh) * | 2014-10-08 | 2018-08-17 | 中国石油化工股份有限公司 | 一种乙烯四聚催化剂组合物及乙烯四聚方法 |
| CN105566026A (zh) * | 2014-10-08 | 2016-05-11 | 中国石油化工股份有限公司 | 一种乙烯三聚的方法 |
| CN105562098B (zh) * | 2014-10-08 | 2018-03-02 | 中国石油化工股份有限公司 | 一种乙烯齐聚催化剂组合物及其应用 |
| CN105562095B (zh) * | 2014-10-08 | 2018-06-15 | 中国石油化工股份有限公司 | 一种乙烯四聚催化剂组合物及乙烯四聚方法 |
| CN105566037B (zh) * | 2014-10-13 | 2018-03-02 | 中国石油化工股份有限公司 | 一种乙烯四聚的方法 |
| CN105566036B (zh) * | 2014-10-13 | 2018-05-11 | 中国石油化工股份有限公司 | 一种乙烯四聚的方法 |
| CN105566040B (zh) * | 2014-10-14 | 2018-11-02 | 中国石油化工股份有限公司 | 一种乙烯齐聚连续反应方法 |
| CN105566039B (zh) * | 2014-10-14 | 2018-05-11 | 中国石油化工股份有限公司 | 一种乙烯齐聚连续反应方法 |
| CN105566043B (zh) * | 2014-10-14 | 2018-04-10 | 中国石油化工股份有限公司 | 一种乙烯齐聚反应的方法 |
| CN105566038B (zh) * | 2014-10-14 | 2018-05-11 | 中国石油化工股份有限公司 | 一种乙烯齐聚连续反应方法 |
| CN105566046B (zh) * | 2014-10-15 | 2018-03-02 | 中国石油化工股份有限公司 | 一种乙烯四聚的方法 |
| CN105566045B (zh) * | 2014-10-15 | 2018-03-02 | 中国石油化工股份有限公司 | 一种乙烯四聚的方法 |
| CN105566044B (zh) * | 2014-10-15 | 2018-05-11 | 中国石油化工股份有限公司 | 一种乙烯齐聚的方法 |
| RS61699B1 (sr) * | 2014-11-25 | 2021-05-31 | Versalis Spa | Fosfinski kompleks vanadijuma, katalitički sistem koji sadrži navedeni fosfinski kompleks vanadijuma i postupak za (ko)polimerizaciju konjugovanih diena |
| KR101654432B1 (ko) | 2014-11-28 | 2016-09-05 | 롯데케미칼 주식회사 | 1-헥센 및 1-옥텐의 제조방법 |
| KR101757369B1 (ko) | 2014-12-11 | 2017-07-12 | 주식회사 엘지화학 | 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
| JP6500488B2 (ja) * | 2015-02-24 | 2019-04-17 | 三菱ケミカル株式会社 | 触媒組成物 |
| KR101757370B1 (ko) * | 2015-06-01 | 2017-07-12 | 주식회사 엘지화학 | 1-옥텐 조성물 |
| KR101757835B1 (ko) | 2015-06-12 | 2017-07-13 | 주식회사 엘지화학 | 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
| KR101749542B1 (ko) | 2015-09-03 | 2017-06-21 | 한택규 | 에틸렌의 선택적 올리고머화 반응 공정 |
| KR101761830B1 (ko) | 2015-10-21 | 2017-07-26 | 주식회사 엘지화학 | 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 |
| KR101982789B1 (ko) | 2015-12-04 | 2019-05-27 | 주식회사 엘지화학 | 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
| KR102428767B1 (ko) | 2016-07-14 | 2022-08-04 | 에스케이이노베이션 주식회사 | 에틸렌의 올리고머화 방법 |
| WO2018012792A1 (en) | 2016-07-14 | 2018-01-18 | Sk Innovation Co., Ltd. | Oligomerization of ethylene |
| EP3650429A4 (en) | 2017-07-06 | 2021-03-31 | Mitsui Chemicals, Inc. | OLEFIN POLYMERIZATION CATALYST AND METHOD FOR MANUFACTURING OLEFINE MULTIMER IN THE PRESENT OF THE SIGNED CATALYST |
| CN108031493B (zh) * | 2017-12-11 | 2020-11-06 | 天津科技大学 | 用于乙烯选择性齐聚的催化剂体系及乙烯齐聚反应方法 |
| KR102581907B1 (ko) * | 2018-01-02 | 2023-09-22 | 에스케이이노베이션 주식회사 | 파라핀을 제조하는 방법 |
| CN115724883B (zh) * | 2021-08-25 | 2025-12-09 | 中国石油化工股份有限公司 | 一种含氟基配体、含氟基金属配合物及乙烯齐聚催化剂组合物 |
| CN116082397B (zh) * | 2023-01-04 | 2026-02-27 | 万华化学集团股份有限公司 | 一种双膦配体衍生物的合成及其催化应用 |
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| CA2115639C (en) * | 1993-03-03 | 2004-10-19 | Feng-Jung Wu | Ethylene trimerization |
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| CN1225095A (zh) * | 1996-06-14 | 1999-08-04 | 宾夕法尼亚州研究基金会 | 由含环状手性膦配位体的过渡金属配合物催化的不对称合成 |
| US6207868B1 (en) * | 1997-06-13 | 2001-03-27 | The Penn State Research Foundation | Asymmetric synthesis catalyzed by transition metal complexes with chiral ligands |
| ES2199591T3 (es) * | 1998-09-04 | 2004-02-16 | Personal Chemistry I Uppsala Ab | Reacciones de sustitucion alilica. |
| CH694251A5 (de) * | 1999-07-14 | 2004-10-15 | Eprova Ag | Herstellung von Tetrahydropterin und Derivaten. |
| BR0015901A (pt) * | 1999-11-26 | 2002-10-22 | Sasol Tech Pty Ltd | Processos de oligomerização de olefina para converter olefinas em hidrocarbonetos de cadeia mais longa, e de trimerização para a trimerização de olefinas, e, lubrificante de polialfaolefina |
| AU2001263526A1 (en) * | 2000-05-04 | 2001-11-12 | Sasol Technology (Pty) Ltd. | A halopyrrole ligand for use in a catalyst system |
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| KR20060002742A (ko) * | 2002-12-20 | 2006-01-09 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 올레핀의 사량체화 |
| JP2006511625A (ja) * | 2002-12-20 | 2006-04-06 | サソル テクノロジー （ピーティーワイ） リミテッド | オレフィンの四量体化 |
| US7273959B2 (en) * | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| CN101052605B (zh) * | 2004-06-18 | 2011-12-21 | Sasol技术股份有限公司 | 烯属化合物在脂族介质中的低聚 |
| US7259123B2 (en) * | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
| US8003839B2 (en) * | 2006-02-03 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Process for generating linear apha olefin comonomers |
| US8404915B2 (en) * | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
-
2007
- 2007-08-16 KR KR1020070082457A patent/KR101057576B1/ko active Active
- 2007-12-24 RU RU2010105127/04A patent/RU2456077C2/ru active
- 2007-12-24 BR BRPI0721866A patent/BRPI0721866B1/pt active IP Right Grant
- 2007-12-24 WO PCT/KR2007/006797 patent/WO2009022770A1/en not_active Ceased
- 2007-12-24 CA CA2694065A patent/CA2694065C/en active Active
- 2007-12-24 US US12/733,156 patent/US8309779B2/en active Active
- 2007-12-24 CN CN2007801002801A patent/CN102083867B/zh active Active
- 2007-12-24 JP JP2010520919A patent/JP2010536538A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0721866A8 (pt) | 2017-12-26 |
| RU2456077C2 (ru) | 2012-07-20 |
| CA2694065C (en) | 2014-09-23 |
| US8309779B2 (en) | 2012-11-13 |
| JP2010536538A (ja) | 2010-12-02 |
| BRPI0721866B1 (pt) | 2018-10-09 |
| CA2694065A1 (en) | 2009-02-19 |
| KR20090017929A (ko) | 2009-02-19 |
| KR101057576B1 (ko) | 2011-08-17 |
| CN102083867A (zh) | 2011-06-01 |
| US20100145124A1 (en) | 2010-06-10 |
| CN102083867B (zh) | 2013-11-13 |
| WO2009022770A1 (en) | 2009-02-19 |
| RU2010105127A (ru) | 2011-09-27 |
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