BRPI0821418A2 - Sistema e aparelho para regenerar um catalisador líquido iônico - Google Patents
Sistema e aparelho para regenerar um catalisador líquido iônicoInfo
- Publication number
- BRPI0821418A2 BRPI0821418A2 BRPI0821418-2A BRPI0821418A BRPI0821418A2 BR PI0821418 A2 BRPI0821418 A2 BR PI0821418A2 BR PI0821418 A BRPI0821418 A BR PI0821418A BR PI0821418 A2 BRPI0821418 A2 BR PI0821418A2
- Authority
- BR
- Brazil
- Prior art keywords
- regenerating
- ionic liquid
- liquid catalyst
- catalyst
- ionic
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 239000002608 ionic liquid Substances 0.000 title 1
- 230000001172 regenerating effect Effects 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
- B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
- B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0298—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature the ionic liquids being characterised by the counter-anions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/56—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30203—Saddle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30215—Toroid or ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30223—Cylinder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/003,577 US7955999B2 (en) | 2007-12-28 | 2007-12-28 | System and apparatus for ionic liquid catalyst regeneration |
| PCT/US2008/084121 WO2009085448A1 (en) | 2007-12-28 | 2008-11-20 | System and apparatus for ionic liquid catalyst regeneration |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0821418A2 true BRPI0821418A2 (pt) | 2015-06-16 |
Family
ID=40799214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0821418-2A BRPI0821418A2 (pt) | 2007-12-28 | 2008-11-20 | Sistema e aparelho para regenerar um catalisador líquido iônico |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US7955999B2 (pt) |
| EP (1) | EP2227328B1 (pt) |
| KR (1) | KR101456737B1 (pt) |
| CN (1) | CN101925409B (pt) |
| AU (1) | AU2008343662B2 (pt) |
| BR (1) | BRPI0821418A2 (pt) |
| MY (1) | MY150209A (pt) |
| WO (1) | WO2009085448A1 (pt) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8658426B2 (en) * | 2008-11-26 | 2014-02-25 | Chevron U.S.A. Inc. | Monitoring of ionic liquid catalyst deactivation |
| US8889934B2 (en) | 2008-12-15 | 2014-11-18 | Chevron U.S.A. Inc. | Process for hydrocarbon conversion using, a method to make, and compositions of, an acid catalyst |
| US20100147740A1 (en) * | 2008-12-16 | 2010-06-17 | Chevron U.S.A Inc | Recovery and use of conjunct polymers from ionic liquid catalysts |
| US8012899B2 (en) * | 2008-12-23 | 2011-09-06 | Chevron U.S.A. Inc. | Recycling of ionic liquid catalyst |
| US20110282114A1 (en) | 2010-05-14 | 2011-11-17 | Chevron U.S.A. Inc. | Method of feeding reactants in a process for the production of alkylate gasoline |
| US8729329B2 (en) | 2010-06-28 | 2014-05-20 | Chevron U.S.A. Inc. | Supported liquid phase ionic liquid catalyst process |
| US8471086B2 (en) | 2010-06-28 | 2013-06-25 | Chevron U.S.A. Inc. | Process to control product selectivity |
| US8388903B2 (en) | 2010-06-28 | 2013-03-05 | Chevron U.S.A. Inc. | Supported ionic liquid reactor |
| CN102206003B (zh) * | 2011-05-05 | 2013-01-23 | 江苏大学 | 用于污水净化的改性浮石填料的制备方法 |
| US8921636B2 (en) * | 2011-09-12 | 2014-12-30 | Chevron U.S.A. Inc. | Conversion of HF alkylation units for ionic liquid catalyzed alkylation processes |
| US8920755B2 (en) * | 2011-09-12 | 2014-12-30 | Chevron U.S.A. Inc. | Conversion of HF alkylation units for ionic liquid catalyzed alkylation processes |
| EP2797693A1 (en) | 2011-12-30 | 2014-11-05 | Shell Internationale Research Maatschappij B.V. | Process for regeneration of ionic liquid catalyst |
| US9302199B2 (en) * | 2012-07-31 | 2016-04-05 | Chevron U.S.A. Inc. | Alkylation process with recycle of hydrogen and recovery of hydrogen chloride |
| CA2909469A1 (en) | 2013-04-19 | 2014-11-20 | Reliance Industries Limited | A process for regenerating ionic compound |
| US20160067668A1 (en) | 2014-09-09 | 2016-03-10 | Chevron U.S.A. Inc. | Cost-effective materials for process units using acidic ionic liquids |
| KR101626015B1 (ko) * | 2014-09-19 | 2016-06-01 | 아주대학교산학협력단 | 폐촉매 회수장치 |
| US9776877B2 (en) | 2014-12-11 | 2017-10-03 | Uop Llc | Separation of conjunct polymer from volatile regenerant for ionic liquid regeneration |
| JP6228246B2 (ja) * | 2015-03-03 | 2017-11-08 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | エテンのオリゴマー化に使用される不均一系触媒の再生 |
| US10596498B2 (en) * | 2015-04-30 | 2020-03-24 | Uop Llc | Active coalescer to remove fine liquid droplets |
| US10435491B2 (en) | 2015-08-19 | 2019-10-08 | Chevron Phillips Chemical Company Lp | Method for making polyalphaolefins using ionic liquid catalyzed oligomerization of olefins |
| KR102010760B1 (ko) | 2015-10-26 | 2019-08-14 | 주식회사 엘지화학 | 광학 소자 |
| KR102258279B1 (ko) | 2015-12-02 | 2021-05-31 | 주식회사 엘지화학 | 광학 소자 |
| CN105457973B (zh) * | 2015-12-23 | 2017-07-14 | 中国石油大学(北京) | 对氯铝酸类离子液体废催化剂进行处理的方法及处理系统 |
| KR102118377B1 (ko) | 2016-01-06 | 2020-06-03 | 주식회사 엘지화학 | 액정 소자 |
| US10888857B2 (en) * | 2018-06-18 | 2021-01-12 | Uop Llc | Ionic liquid catalyst regeneration with reduced hydrogen amounts |
| CN110339796B (zh) * | 2019-06-28 | 2021-04-02 | 中北大学 | 一种用于硫酸烷基化法制备烷基化汽油的反应装置和方法 |
| KR102097815B1 (ko) | 2019-08-07 | 2020-04-07 | 주식회사 엘지화학 | 광학 소자 |
| CN115260034A (zh) * | 2021-12-13 | 2022-11-01 | 江苏索普化工股份有限公司 | 一种工业化离子液体催化剂生产乙酸乙酯原始开停车方法 |
| CN117209638B (zh) * | 2023-11-08 | 2024-02-13 | 传化智联股份有限公司 | 一种两性离子稀土元素烷基催化剂及其制备方法和应用 |
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| US4014801A (en) * | 1974-09-30 | 1977-03-29 | Marathon Oil Company | Process for breaking polymer-containing emulsions |
| US4122245A (en) | 1977-08-19 | 1978-10-24 | The United States Of America As Represented By The Secretary Of The Air Force | AlCl3 /1-alkyl pyridinium chloride room temperature electrolytes |
| US4463072A (en) | 1983-11-30 | 1984-07-31 | Allied Corporation | Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte |
| US4463071A (en) | 1983-11-30 | 1984-07-31 | Allied Corporation | Secondary batteries using room-temperature molten non-aqueous electrolytes containing 1,2,3-trialkylimidazolium halides or 1,3-dialkylimidazolium halide |
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| US4996317A (en) * | 1988-08-05 | 1991-02-26 | Kraft General Foods, Inc. | Caffeine recovery from supercritical carbon dioxide |
| FR2659871B1 (fr) | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | Composition liquide non aqueuse a caractere ionique et son utilisation comme solvant. invention de mm. yves chauvin, dominique commereuc, isabelle guibard, andre hirschauer, helene olivier, lucien saussine. |
| US5414186A (en) * | 1992-08-05 | 1995-05-09 | Mobil Oil Corporation | Liquid acid alkylation catalyst and isoparaffin-olefin alkylation process |
| FR2725919B1 (fr) | 1994-10-24 | 1996-12-13 | Inst Francais Du Petrole | Composition catalytique et procede pour l'alkylation d'hydrocarbures aliphatiques |
| US5593569A (en) | 1995-01-09 | 1997-01-14 | Kerr-Mcgee | Hydrocracking processes using a homogenous catalysis system comprising a metal halide Lewis acid, a Bronsted acid and an alkane |
| US5731101A (en) | 1996-07-22 | 1998-03-24 | Akzo Nobel Nv | Low temperature ionic liquids |
| US6096680A (en) | 1996-10-28 | 2000-08-01 | Albemarle Corporation | Liquid clathrate compositions |
| FR2761618B1 (fr) | 1997-04-08 | 1999-05-14 | Inst Francais Du Petrole | Composition catalytique et procede pour l'alkylation d'hydrocarbures aliphatiques |
| US6193786B1 (en) * | 1998-12-11 | 2001-02-27 | Pacific Gas And Electric Company | Portable oil degasification apparatus |
| NL1021362C2 (nl) | 2001-08-31 | 2003-08-05 | Inst Francais Du Petrole | Katalysator- en oplosmiddelsamenstelling en katalysewerkwijzen waarbij deze samenstelling wordt toegepast. |
| EP1403236A1 (en) | 2002-09-25 | 2004-03-31 | Haldor Topsoe A/S | Process of paraffin hydrocarbon isomerisation catalysed by an ionic liquid in the presence of a cyclic hydrocarbon additive |
| EP1402950A1 (en) | 2002-09-25 | 2004-03-31 | Haldor Topsoe A/S | Catalyst and process of paraffin hydrocarbon conversion |
| CN1203032C (zh) | 2002-11-12 | 2005-05-25 | 石油大学(北京) | 以复合离子液体为催化剂制备烷基化油剂的方法 |
| US7128881B2 (en) * | 2004-04-30 | 2006-10-31 | Petrik Viktor I | Configurations and methods for water purification |
| US7534922B2 (en) * | 2004-12-13 | 2009-05-19 | Ticona Gmbh | Processes for the manufacture of acetals |
| US7432409B2 (en) * | 2004-12-21 | 2008-10-07 | Chevron U.S.A. Inc. | Alkylation process using chloroaluminate ionic liquid catalysts |
| US20060247482A1 (en) * | 2005-04-29 | 2006-11-02 | Chevron Phillips Chemical Company | Method and system to recycle non-isomerized monomer in an ionic liquid catalyzed chemical reaction |
| US7566429B2 (en) * | 2005-06-14 | 2009-07-28 | Sandia Corporation | Catalytic reactive separation system for energy-efficient production of cumene |
| US7732363B2 (en) * | 2005-12-20 | 2010-06-08 | Chevron U.S.A. Inc. | Regeneration of acidic catalysts |
| US7691771B2 (en) | 2005-12-20 | 2010-04-06 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst by hydrogenation using a supported catalyst |
| US7737067B2 (en) * | 2005-12-20 | 2010-06-15 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst |
| US7727925B2 (en) | 2005-12-20 | 2010-06-01 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst by hydrogenation using metal and acid |
| US7651970B2 (en) * | 2005-12-20 | 2010-01-26 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst by hydrogenation using a metal or metal alloy catalyst |
| US8524965B2 (en) * | 2005-12-21 | 2013-09-03 | Chevron Oronite Company Llc | Method of making an alkylated aromatic using acidic ionic liquid catalyst |
| US7825055B2 (en) * | 2006-04-21 | 2010-11-02 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen |
| US7674739B2 (en) * | 2006-04-21 | 2010-03-09 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst using a metal in the absence of added hydrogen |
| US7732364B2 (en) | 2007-12-28 | 2010-06-08 | Chevron U.S.A. Inc. | Process for ionic liquid catalyst regeneration |
-
2007
- 2007-12-28 US US12/003,577 patent/US7955999B2/en active Active
-
2008
- 2008-11-20 KR KR1020107016903A patent/KR101456737B1/ko not_active Expired - Fee Related
- 2008-11-20 BR BRPI0821418-2A patent/BRPI0821418A2/pt not_active IP Right Cessation
- 2008-11-20 AU AU2008343662A patent/AU2008343662B2/en not_active Ceased
- 2008-11-20 WO PCT/US2008/084121 patent/WO2009085448A1/en not_active Ceased
- 2008-11-20 CN CN200880125391.2A patent/CN101925409B/zh not_active Expired - Fee Related
- 2008-11-20 EP EP08868096.2A patent/EP2227328B1/en not_active Not-in-force
- 2008-11-20 MY MYPI2010003009A patent/MY150209A/en unknown
-
2010
- 2010-03-17 US US12/725,520 patent/US20100278699A1/en not_active Abandoned
- 2010-03-18 US US12/727,180 patent/US8088338B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20090170687A1 (en) | 2009-07-02 |
| MY150209A (en) | 2013-12-13 |
| US8088338B2 (en) | 2012-01-03 |
| WO2009085448A1 (en) | 2009-07-09 |
| EP2227328A1 (en) | 2010-09-15 |
| CN101925409A (zh) | 2010-12-22 |
| AU2008343662A1 (en) | 2009-07-09 |
| US20100172806A1 (en) | 2010-07-08 |
| EP2227328B1 (en) | 2013-04-10 |
| EP2227328A4 (en) | 2011-12-21 |
| US7955999B2 (en) | 2011-06-07 |
| AU2008343662B2 (en) | 2012-02-23 |
| CN101925409B (zh) | 2014-04-23 |
| US20100278699A1 (en) | 2010-11-04 |
| KR20100098576A (ko) | 2010-09-07 |
| KR101456737B1 (ko) | 2014-10-31 |
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