BRPI0821495A2 - Sistema catalisador e componente de catalisador de titânio sólido para uso na polimerização olefínica, e, métodos para preparar um suporte de catalisador e para polimerizar ou copolimerizar uma olefina - Google Patents

Sistema catalisador e componente de catalisador de titânio sólido para uso na polimerização olefínica, e, métodos para preparar um suporte de catalisador e para polimerizar ou copolimerizar uma olefina

Info

Publication number
BRPI0821495A2
BRPI0821495A2 BRPI0821495-6A BRPI0821495A BRPI0821495A2 BR PI0821495 A2 BRPI0821495 A2 BR PI0821495A2 BR PI0821495 A BRPI0821495 A BR PI0821495A BR PI0821495 A2 BRPI0821495 A2 BR PI0821495A2
Authority
BR
Brazil
Prior art keywords
catalyst
olefin
copolymerizing
polymerizing
preparing
Prior art date
Application number
BRPI0821495-6A
Other languages
English (en)
Inventor
Michael Donald Spencer
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Publication of BRPI0821495A2 publication Critical patent/BRPI0821495A2/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Epoxy Compounds (AREA)
BRPI0821495-6A 2007-12-31 2008-12-03 Sistema catalisador e componente de catalisador de titânio sólido para uso na polimerização olefínica, e, métodos para preparar um suporte de catalisador e para polimerizar ou copolimerizar uma olefina BRPI0821495A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/967,815 US8344079B2 (en) 2007-12-31 2007-12-31 Molar ratio modifications to larger polyolefin catalysts
PCT/US2008/085334 WO2009088596A1 (en) 2007-12-31 2008-12-03 Molar ratio modifications to larger polyolefin catalysts

Publications (1)

Publication Number Publication Date
BRPI0821495A2 true BRPI0821495A2 (pt) 2015-06-16

Family

ID=40380120

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0821495-6A BRPI0821495A2 (pt) 2007-12-31 2008-12-03 Sistema catalisador e componente de catalisador de titânio sólido para uso na polimerização olefínica, e, métodos para preparar um suporte de catalisador e para polimerizar ou copolimerizar uma olefina

Country Status (7)

Country Link
US (1) US8344079B2 (pt)
EP (1) EP2242776A1 (pt)
JP (1) JP2011508053A (pt)
KR (1) KR20100114888A (pt)
CN (1) CN101965369A (pt)
BR (1) BRPI0821495A2 (pt)
WO (1) WO2009088596A1 (pt)

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CN101993507B (zh) * 2009-08-13 2012-10-24 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分及其催化剂
RU2567391C2 (ru) 2009-08-21 2015-11-10 Чайна Петролеум Энд Кемикал Корпорейшн Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора
US9040444B2 (en) * 2009-12-22 2015-05-26 Reliance Industries Limited Semi continuous process for the synthesis of a catalyst for use in the manufacture of polyolefins
US8685879B2 (en) * 2011-04-29 2014-04-01 Basf Corporation Emulsion process for improved large spherical polypropylene catalysts
US8575283B1 (en) 2012-06-28 2013-11-05 Formosa Plastics Corporation, U.S.A. Heterocyclic organic compounds as electron donors for polyolefin catalysts
JP6623323B2 (ja) * 2012-12-12 2019-12-25 ブラスケム アメリカ インコーポレイテッドＢｒａｓｋｅｍ Ａｍｅｒｉｃａ，Ｉｎｃ． オレフィン重合触媒用の内部電子供与体、その作製および使用方法
RU2668082C2 (ru) * 2013-10-18 2018-09-27 Чайна Петролеум Энд Кемикал Корпорейшн Сферические носители для катализатора полимеризации олефинов, компоненты катализатора, катализатор и методы их получения
CN105934449B (zh) * 2013-12-20 2018-07-10 沙特基础工业公司 用于烯烃聚合的催化剂组合物
BR112016013799B1 (pt) * 2013-12-20 2022-02-22 Saudi Basic Industries Corporation Pró-catalisador para a polimerização de uma olefina, seu processo de preparação, uso de benzamida de fórmula x e processo de preparação de poliolefinas
EP3083711B1 (en) * 2013-12-20 2023-02-22 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
FR3020067A1 (fr) * 2014-04-18 2015-10-23 Bluestar Silicones France Procede d'enduction d'un composition silicone sur un support souple
MX2016015770A (es) * 2014-06-02 2017-04-25 Sabic Global Technologies Bv Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato.
CN105440172B (zh) * 2014-08-15 2018-03-02 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂组分的制备方法
US9714302B2 (en) * 2014-10-10 2017-07-25 W. R. Grace & Co.—Conn. Process for preparing spherical polymerization catalyst components for use in olefin polymerizations
CN107880186B (zh) * 2016-09-30 2020-05-12 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备与应用
CN108117617B (zh) * 2016-11-28 2021-05-04 任丘市利和科技发展有限公司 一种用于烯烃聚合的固体催化剂组分和催化剂
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
WO2019094347A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
CN110498872A (zh) * 2018-05-18 2019-11-26 中国石油化工股份有限公司 一种烷氧基镁颗粒、及其制备方法和应用
CN110498874A (zh) * 2018-05-18 2019-11-26 中国石油化工股份有限公司 一种烷氧基镁颗粒、及其制备方法和应用
KR102946642B1 (ko) * 2019-07-26 2026-03-31 차이나 페트로리움 앤드 케미컬 코포레이션 올레핀 중합용 촉매 시스템 및 이의 용도
CN112300302B (zh) * 2019-07-26 2023-05-09 中国石油化工股份有限公司 一种十二元环化合物及其应用
CN112724293A (zh) * 2019-10-28 2021-04-30 中国石油化工股份有限公司 固体钛/镁催化剂及其制备方法、烯烃聚合用催化剂及其应用、聚丙烯聚合物
CN116925271B (zh) * 2022-04-02 2025-08-08 中国石油化工股份有限公司 一种用于乙烯聚合的催化剂组分及其制备方法、催化剂和应用
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Also Published As

Publication number Publication date
CN101965369A (zh) 2011-02-02
EP2242776A1 (en) 2010-10-27
JP2011508053A (ja) 2011-03-10
US8344079B2 (en) 2013-01-01
US20090171044A1 (en) 2009-07-02
WO2009088596A1 (en) 2009-07-16
KR20100114888A (ko) 2010-10-26

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