BRPI0912917A2 - composição de catalisador, processo de polimerização e polímero a base de propileno - Google Patents

composição de catalisador, processo de polimerização e polímero a base de propileno

Info

Publication number
BRPI0912917A2
BRPI0912917A2 BRPI0912917A BRPI0912917A BRPI0912917A2 BR PI0912917 A2 BRPI0912917 A2 BR PI0912917A2 BR PI0912917 A BRPI0912917 A BR PI0912917A BR PI0912917 A BRPI0912917 A BR PI0912917A BR PI0912917 A2 BRPI0912917 A2 BR PI0912917A2
Authority
BR
Brazil
Prior art keywords
catalyst composition
polymerization process
propylene polymer
propylene
polymer
Prior art date
Application number
BRPI0912917A
Other languages
English (en)
Inventor
Linfeng Chen
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41716257&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0912917(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from PCT/US2008/073882 external-priority patent/WO2009029487A1/en
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of BRPI0912917A2 publication Critical patent/BRPI0912917A2/pt
Publication of BRPI0912917A8 publication Critical patent/BRPI0912917A8/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
BRPI0912917A 2008-08-21 2009-02-23 Composição de catalisador BRPI0912917A8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/US2008/073882 WO2009029487A1 (en) 2007-08-24 2008-08-21 Self-limiting catalyst system with controlled aluminum rto sca ratio and method
PCT/US2009/034875 WO2010021762A1 (en) 2008-08-21 2009-02-23 Catalyst composition with mixed selectivity control agent and polymerisation method using it
US12/390,785 US7893003B2 (en) 2007-08-24 2009-02-23 Catalyst composition with mixed selectivity control agent and method

Publications (2)

Publication Number Publication Date
BRPI0912917A2 true BRPI0912917A2 (pt) 2015-10-06
BRPI0912917A8 BRPI0912917A8 (pt) 2017-09-19

Family

ID=41716257

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0912917A BRPI0912917A8 (pt) 2008-08-21 2009-02-23 Composição de catalisador

Country Status (9)

Country Link
US (3) US7893003B2 (pt)
EP (1) EP2315789B1 (pt)
JP (3) JP5628809B2 (pt)
KR (1) KR101602980B1 (pt)
CN (1) CN102186889B (pt)
BR (1) BRPI0912917A8 (pt)
MX (1) MX2011001970A (pt)
RU (1) RU2486208C2 (pt)
WO (1) WO2010021762A1 (pt)

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US8378045B2 (en) * 2008-12-31 2013-02-19 Dow Global Technologies Llc Thermoformed article with high stiffness and good optics
RU2502746C2 (ru) 2008-12-31 2013-12-27 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Прокаталитическая композиция с замещенным 1,2-фениленовым ароматическим сложнодиэфирным внутренним донором и способ
WO2011084628A1 (en) * 2009-12-21 2011-07-14 Dow Global Technologies Inc. Gas-phase polymerization process having multiple flow regimes
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US8604146B2 (en) * 2010-12-21 2013-12-10 Dow Global Technologies Llc Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same
US9434796B2 (en) 2010-12-21 2016-09-06 W. R. Grace & Co.-Conn. Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same
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KR102263502B1 (ko) 2013-12-20 2021-06-11 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 촉매 시스템
EA033164B1 (ru) 2013-12-20 2019-09-30 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефина
US20170121430A1 (en) * 2014-05-20 2017-05-04 Reliance Industries Limited Ziegler-Natta Catalyst Composition And A Process For Its Preparation
CN107922694B (zh) 2015-06-12 2023-08-15 Sabic环球技术有限责任公司 用于制造低排放聚丙烯的方法
WO2017079940A1 (zh) * 2015-11-12 2017-05-18 营口市向阳催化剂有限责任公司 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用
CN105524192B (zh) * 2015-12-09 2017-11-14 大唐国际化工技术研究院有限公司 具有高温活性抑制作用的聚丙烯催化剂组合物及其用途
CN109843933A (zh) 2016-08-30 2019-06-04 格雷斯公司 用于生产聚烯烃的催化剂体系及其制备和使用方法
CN107880172B (zh) * 2016-09-30 2020-07-24 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备与应用
WO2018067367A1 (en) 2016-10-06 2018-04-12 W.R. Grace & Co.-Conn. Procatalyst composition made with a combination of internal electron donors
RU2692246C1 (ru) * 2017-06-15 2019-06-24 Индийская Нефтяная Корпорация Лимитэд Внешний донор для полимеризации олефинов
CN111065657A (zh) * 2017-09-29 2020-04-24 东邦钛株式会社 烯烃类聚合用催化剂、烯烃类聚合用催化剂的制造方法、烯烃类聚合物的制造方法和丙烯-α-烯烃共聚物
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
CN109517099B (zh) * 2018-11-27 2021-07-30 山东鲁晶化工科技有限公司 一种外给电子体、烯烃聚合催化剂体系及其应用
CN110003367B (zh) * 2019-04-26 2020-07-17 营口市向阳催化剂有限责任公司 一种具有双功能的外给电子体的齐格勒-纳塔催化剂及其应用
KR102988796B1 (ko) * 2020-06-26 2026-07-09 릴라이언스 인더스트리즈 리미티드 치글러나타(ziegler-natta) 촉매 시스템 및 이를 이용한 중합 공정
CN113248637B (zh) * 2021-04-20 2022-07-26 国家能源集团宁夏煤业有限责任公司 外给电子体化合物、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法
CN113214416B (zh) * 2021-04-20 2022-07-26 国家能源集团宁夏煤业有限责任公司 组合外给电子体、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法
JP2024531158A (ja) * 2021-08-09 2024-08-29 ダブリュー・アール・グレース・アンド・カンパニー－コーン 沈降嵩密度が増加したポリオレフィン粒状樹脂を製造するためのプロセス
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