BRPI0912921A2 - complexo metal-ligante, catalisador e processo para preparo de uma poliolefina - Google Patents
complexo metal-ligante, catalisador e processo para preparo de uma poliolefinaInfo
- Publication number
- BRPI0912921A2 BRPI0912921A2 BRPI0912921A BRPI0912921A BRPI0912921A2 BR PI0912921 A2 BRPI0912921 A2 BR PI0912921A2 BR PI0912921 A BRPI0912921 A BR PI0912921A BR PI0912921 A BRPI0912921 A BR PI0912921A BR PI0912921 A2 BRPI0912921 A2 BR PI0912921A2
- Authority
- BR
- Brazil
- Prior art keywords
- polyolefin
- catalyst
- preparing
- metal
- binder complex
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9075608P | 2008-08-21 | 2008-08-21 | |
| US15042309P | 2009-02-06 | 2009-02-06 | |
| PCT/US2009/054447 WO2010022228A2 (en) | 2008-08-21 | 2009-08-20 | Metal-ligand complexes and catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0912921A2 true BRPI0912921A2 (pt) | 2017-05-23 |
Family
ID=41130177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0912921A BRPI0912921A2 (pt) | 2008-08-21 | 2009-08-20 | complexo metal-ligante, catalisador e processo para preparo de uma poliolefina |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8372927B2 (pt) |
| EP (1) | EP2315788B1 (pt) |
| KR (1) | KR101720353B1 (pt) |
| CN (1) | CN102131837B (pt) |
| BR (1) | BRPI0912921A2 (pt) |
| ES (1) | ES2765628T3 (pt) |
| WO (1) | WO2010022228A2 (pt) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG183310A1 (en) * | 2010-02-19 | 2012-09-27 | Dow Global Technologies Llc | Process for polymerizing an olefin monomer and catalyst therefor |
| CN102822180B (zh) * | 2010-02-19 | 2016-06-15 | 陶氏环球技术有限责任公司 | 金属配体配合物和催化剂 |
| EP2753663B1 (en) | 2011-09-07 | 2020-01-08 | Dow Silicones Corporation | Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
| CN103781823B (zh) | 2011-09-07 | 2016-08-17 | 道康宁公司 | 含钛络合物和缩合反应催化剂、制备该催化剂的方法以及包含该催化剂的组合物 |
| EP2758413B1 (en) | 2011-09-20 | 2018-03-07 | Dow Corning Corporation | Iridium containing hydrosilylation catalysts and compositions containing the catalysts |
| CN103814038A (zh) | 2011-09-20 | 2014-05-21 | 道康宁公司 | 含钌硅氢加成催化剂及含有该催化剂的组合物 |
| CN103827215B (zh) | 2011-10-04 | 2016-12-21 | 道康宁公司 | 含铁(ii)络合物和缩合反应催化剂、制备该催化剂的方法及含有该催化剂的组合物 |
| US9139699B2 (en) | 2012-10-04 | 2015-09-22 | Dow Corning Corporation | Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
| US9073950B2 (en) | 2011-12-01 | 2015-07-07 | Dow Corning Corporation | Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use |
| ITMI20122199A1 (it) * | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto |
| KR101914326B1 (ko) * | 2014-08-28 | 2018-11-02 | 한화케미칼 주식회사 | 신규한 4족 전이금속 화합물 및 이의 용도 |
| EP3356374B1 (en) | 2015-09-30 | 2025-09-24 | Dow Global Technologies LLC | Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
| KR101910232B1 (ko) | 2015-12-24 | 2018-12-19 | 주식회사 엘지화학 | 신규한 전이금속 화합물을 포함하는 촉매 조성물 |
| US11098165B2 (en) | 2016-07-13 | 2021-08-24 | Dow Silicones Corporation | Metal aprotic organosilanoxide compound |
| CN109415397B (zh) | 2016-07-13 | 2021-03-30 | 美国陶氏有机硅公司 | 包含金属非质子有机硅烷氧化物化合物的制剂 |
| EP4435013A3 (en) | 2016-09-30 | 2024-12-25 | Dow Global Technologies LLC | Process for preparing multi- or dual-headed compositions useful for chain shuttling |
| TWI756272B (zh) | 2016-09-30 | 2022-03-01 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之封端多頭或雙頭組合物及其製備方法 |
| JP7053589B2 (ja) * | 2016-09-30 | 2022-04-12 | ダウ グローバル テクノロジーズ エルエルシー | チオ尿素第4族遷移金属触媒および重合系 |
| TW201840572A (zh) | 2016-09-30 | 2018-11-16 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之多頭或雙頭組合物及其製備方法 |
| CN110582518B (zh) | 2017-03-15 | 2022-08-09 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| US20200247936A1 (en) | 2017-03-15 | 2020-08-06 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
| EP3596146B1 (en) | 2017-03-15 | 2023-07-19 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| CN110612315B (zh) | 2017-03-15 | 2022-08-26 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| KR102710284B1 (ko) * | 2017-03-15 | 2024-09-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중-블록 공중합체 형성을 위한 촉매 시스템 |
| WO2019048561A1 (en) * | 2017-09-08 | 2019-03-14 | Total Research & Technology Feluy | NOVEL APPROPRIATE COMPOUNDS AS CATALYSTS FOR POLYMERIZATION REACTIONS |
| CN111164110A (zh) * | 2017-09-29 | 2020-05-15 | 陶氏环球技术有限责任公司 | 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂 |
| EP3774941B1 (en) * | 2018-03-30 | 2022-11-02 | Dow Global Technologies LLC | Binuclear olefin polymerization activators |
| US11787880B2 (en) | 2018-03-30 | 2023-10-17 | Dow Global Technologies Llc | Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations |
| JP2021519362A (ja) | 2018-03-30 | 2021-08-10 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合活性化剤 |
| JP7364585B2 (ja) | 2018-03-30 | 2023-10-18 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための二核助触媒としての高溶解性ビスホウ酸 |
| US11447586B2 (en) | 2018-03-30 | 2022-09-20 | Dow Global Technologies Llc | Olefin polymerization activators |
| JP7443328B2 (ja) | 2018-07-31 | 2024-03-05 | ダウ グローバル テクノロジーズ エルエルシー | 二座アゾリルアミド金属-配位子錯体およびオレフィン重合触媒 |
| JP7587494B2 (ja) * | 2018-09-28 | 2024-11-20 | ダウ グローバル テクノロジーズ エルエルシー | 四官能性長鎖分岐ポリオレフィン樹脂の重合プロセス |
| WO2020198196A1 (en) | 2019-03-28 | 2020-10-01 | Dow Global Technologies Llc | Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators |
| US20220213246A1 (en) * | 2019-03-29 | 2022-07-07 | Dow Global Technologies Llc | Process of polymerizing tri-functional long-chain branched olefin |
| CN113795523B (zh) | 2019-04-30 | 2024-03-08 | 陶氏环球技术有限责任公司 | 烯烃官能化活化剂 |
| BR112022019374A2 (pt) * | 2020-03-27 | 2022-11-16 | Dow Global Technologies Llc | Processo para polimerizar polímeros à base de etileno |
| US20230128663A1 (en) * | 2020-03-27 | 2023-04-27 | Dow Global Technologies Llc | Long-chain branched ethylene-based polymers |
| JP2023552277A (ja) | 2020-11-10 | 2023-12-15 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレンの表面エネルギーを増加させるためのポリオレフィン-ポリアクリレートブロックコポリマー添加剤の調製 |
| WO2022103803A1 (en) | 2020-11-10 | 2022-05-19 | Dow Global Technologies Llc | Preparation of non-polar–polar block copolymers via vinyl-terminated polyolefins |
| EP4512834A3 (en) | 2021-09-10 | 2025-05-14 | Dow Global Technologies LLC | Borate cocatalysts for polyolefin production |
| CN117999292A (zh) | 2021-09-10 | 2024-05-07 | 陶氏环球技术有限责任公司 | 用于烯烃聚合的烃溶性硼酸盐助催化剂 |
| CN116273185B (zh) * | 2023-03-01 | 2024-04-19 | 大连理工大学 | 一种固载化双功能催化剂及其在外环路反应工艺中制备环状碳酸酯的方法 |
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| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| US6919467B2 (en) | 2001-12-18 | 2005-07-19 | Univation Technologies, Llc | Imino-amide catalyst compositions for the polymerization of olefins |
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| WO2004024740A1 (en) | 2002-09-12 | 2004-03-25 | Dow Global Technologies Inc. | Preparation of metal complexes |
| WO2004074333A2 (en) * | 2003-02-18 | 2004-09-02 | Dow Global Technologies Inc. | Process for homo- or copolymerizationof conjugated olefines |
| KR100431444B1 (ko) * | 2004-01-28 | 2004-05-13 | 주식회사 엘지화학 | 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법 |
| US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| BRPI0508148B1 (pt) | 2004-03-17 | 2015-09-01 | Dow Global Technologies Inc. | Interpolímero de etileno em multibloco, derivado reticulado e composição |
| BRPI0508173B1 (pt) | 2004-03-17 | 2016-03-15 | Dow Global Technologies Inc | copolímeros em multibloco, polímero, copolímero, um derivado funcional, mistura homogênea de polímero, processo para a preparação de um copolímero em multibloco contendo propileno e processo para preparar um copolímero em multibloco contendo 4-metil-1-penteno |
| WO2005090373A1 (de) | 2004-03-17 | 2005-09-29 | Georg-August-Universität Göttingen | Sauerstoffverbrückter bimetallischer komplex, dessen herstellung und verwendung für die polymerisations-katalyse |
| CN1934150A (zh) | 2004-03-17 | 2007-03-21 | 陶氏环球技术公司 | 用于形成乙烯共聚物的包括穿梭剂的催化剂组合物 |
| EP1781716B1 (en) | 2004-06-22 | 2011-02-23 | DSM IP Assets B.V. | Process for the preparation of a polymer |
| US7067686B1 (en) | 2005-07-21 | 2006-06-27 | Univation Technologies, Llc | Synthesis of benzyl-metal compounds |
| EP2057205B1 (en) * | 2006-08-25 | 2017-02-08 | Dow Global Technologies LLC | Production of meta-block copolymers by polymer segment interchange |
-
2009
- 2009-08-20 ES ES09791725T patent/ES2765628T3/es active Active
- 2009-08-20 EP EP09791725.6A patent/EP2315788B1/en active Active
- 2009-08-20 CN CN200980132611.9A patent/CN102131837B/zh active Active
- 2009-08-20 BR BRPI0912921A patent/BRPI0912921A2/pt not_active IP Right Cessation
- 2009-08-20 KR KR1020117003752A patent/KR101720353B1/ko active Active
- 2009-08-20 WO PCT/US2009/054447 patent/WO2010022228A2/en not_active Ceased
- 2009-08-20 US US12/544,581 patent/US8372927B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| ES2765628T3 (es) | 2020-06-10 |
| WO2010022228A4 (en) | 2010-06-03 |
| US20100048842A1 (en) | 2010-02-25 |
| WO2010022228A3 (en) | 2010-04-15 |
| KR20110053335A (ko) | 2011-05-20 |
| CN102131837B (zh) | 2014-10-15 |
| EP2315788B1 (en) | 2019-11-13 |
| EP2315788A2 (en) | 2011-05-04 |
| US8372927B2 (en) | 2013-02-12 |
| KR101720353B1 (ko) | 2017-03-27 |
| CN102131837A (zh) | 2011-07-20 |
| WO2010022228A2 (en) | 2010-02-25 |
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