BRPI0915571A8 - Processo para a fabricação de um 1,2-epóxido - Google Patents
Processo para a fabricação de um 1,2-epóxidoInfo
- Publication number
- BRPI0915571A8 BRPI0915571A8 BRPI0915571A BRPI0915571A BRPI0915571A8 BR PI0915571 A8 BRPI0915571 A8 BR PI0915571A8 BR PI0915571 A BRPI0915571 A BR PI0915571A BR PI0915571 A BRPI0915571 A BR PI0915571A BR PI0915571 A8 BRPI0915571 A8 BR PI0915571A8
- Authority
- BR
- Brazil
- Prior art keywords
- epoxide
- terminal olefin
- manufacturing
- water
- catalytic oxidation
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical group 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012431 aqueous reaction media Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/14—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by free hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCESSO PARA A FABRICAÇÃO DE UM 1,2-EPÓXIDO. A invenção diz respeito a um processo para a fabricação de um 1,2-epóxido por oxidação catalítica de uma olefina terminal com perdição de hidrogênio em que a oxidação catalítica é realizada em um sistema bifásico compreendendo uma fase orgãnica e um meio de reação aquoso, em que um complexo de manganés soltível em água é usado como catalisador de oxidação, em que uma olefina terminal é usada com uma solubilidade a 20°C de pelo menos 0,01 a 100 g em 1 litro de água, e em que a razão molar de olefina terminal para peróxido de hidrogênio está na faixa de 1:0,1 a 1:2.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08075680A EP2149569A1 (en) | 2008-08-01 | 2008-08-01 | Process for the manufacture of a 1,2-Epoxide |
| PCT/EP2009/004977 WO2010012361A1 (en) | 2008-08-01 | 2009-07-09 | Process for the manufacture of a 1, 2-epoxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0915571A2 BRPI0915571A2 (pt) | 2017-06-27 |
| BRPI0915571A8 true BRPI0915571A8 (pt) | 2017-09-26 |
Family
ID=39938238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0915571A BRPI0915571A8 (pt) | 2008-08-01 | 2009-07-09 | Processo para a fabricação de um 1,2-epóxido |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US8729282B2 (pt) |
| EP (2) | EP2149569A1 (pt) |
| JP (2) | JP5709172B2 (pt) |
| KR (2) | KR101475660B1 (pt) |
| CN (2) | CN102112456A (pt) |
| AU (1) | AU2009275560B9 (pt) |
| BR (1) | BRPI0915571A8 (pt) |
| RU (1) | RU2484088C2 (pt) |
| WO (1) | WO2010012361A1 (pt) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2149569A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of a 1,2-Epoxide |
| EP2149570A1 (en) | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex |
| EP2343288A1 (en) * | 2009-11-27 | 2011-07-13 | Momentive Specialty Chemicals Research Belgium S.A. | Process for the manufacture of propylene oxide |
| EP2354131A1 (en) * | 2010-02-02 | 2011-08-10 | Momentive Specialty Chemicals Research Belgium | Process for the manufacture of a 1,2-epoxide and a device for carrying out said process |
| EP2357180A1 (en) | 2010-02-02 | 2011-08-17 | Momentive Specialty Chemicals Research Belgium S.A. | Manufacture of epoxyethyl ethers or glycidyl ethers |
| EP2354129A1 (en) | 2010-02-02 | 2011-08-10 | Momentive Specialty Chemicals Research Belgium S.A. | Epoxidation process |
| EP2354130A1 (en) | 2010-02-02 | 2011-08-10 | Momentive Specialty Chemicals Research Belgium | Manufacture of an epoxyethyl carboxylate or glycidyl carboxylate |
| CN102453004A (zh) * | 2010-10-29 | 2012-05-16 | 中国科学院兰州化学物理研究所 | 一种环氧丁烯的合成方法 |
| EP2670741B8 (en) | 2011-02-04 | 2016-01-27 | Blue Cube IP LLC | Process for separating phases of a mixture containing an oxirane |
| CN103459378B (zh) | 2011-02-04 | 2015-05-27 | 陶氏环球技术有限责任公司 | 生产氧杂环丙烷类化合物的系统和方法 |
| WO2012106627A2 (en) | 2011-02-04 | 2012-08-09 | Dow Global Technologies Llc | Regenerating a titanium silicalite catalyst |
| EP2537836A1 (en) * | 2011-06-22 | 2012-12-26 | Momentive Specialty Chemicals Research Belgium S.A. | Apparatus and methods to preserve catalyst activity in an epoxidation process |
| EP2719692A1 (en) * | 2012-10-09 | 2014-04-16 | Momentive Specialty Chemicals Research Belgium S.A. | Catalytic epoxidation process |
| CN104119352B (zh) * | 2013-04-26 | 2016-08-17 | 中国科学院大连化学物理研究所 | 一种烯烃的不对称环氧化方法 |
| TW201700464A (zh) | 2015-02-17 | 2017-01-01 | 贏創德固賽有限責任公司 | 使用過氧化氫之使烯烴環氧化方法 |
| EP3059229A1 (en) * | 2015-02-17 | 2016-08-24 | Evonik Degussa GmbH | Method for the epoxidation of an olefin with hydrogen peroxide |
| WO2016131649A1 (en) | 2015-02-17 | 2016-08-25 | Evonik Degussa Gmbh | Method for the epoxidation of an olefin with hydrogen peroxide |
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| US8372994B2 (en) * | 2007-06-28 | 2013-02-12 | Basf Se | C10 alkanoic acid glycidyl esters and use thereof |
| KR20100031770A (ko) * | 2007-07-11 | 2010-03-24 | 스미또모 가가꾸 가부시끼가이샤 | 에폭시 화합물의 제조 장치 및 제조 방법 |
| KR20100044836A (ko) * | 2007-07-11 | 2010-04-30 | 스미또모 가가꾸 가부시끼가이샤 | 혼합 가스의 제조 방법 및 제조 장치, 그리고 에폭시 화합물의 제조 장치 및 제조 방법 |
| WO2009063487A2 (en) | 2007-08-10 | 2009-05-22 | Aditya Birla Science & Technology Co. Ltd. | An improved process for manufacture of epoxides, particularly epichlorohydrin |
| EP2103604A1 (de) * | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
| ES2336746B1 (es) | 2008-04-10 | 2011-01-25 | Universitat De Girona | Catalizadores de manganeso y su uso para la epoxidacion selectiva de olefinas. |
| US7541479B1 (en) | 2008-05-27 | 2009-06-02 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| EP2149569A1 (en) * | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of a 1,2-Epoxide |
| EP2149570A1 (en) | 2008-08-01 | 2010-02-03 | Hexion Specialty Chemicals Research Belgium S.A. | Process for the manufacture of epichlorohydrin using hydrogen peroxide and a manganese komplex |
| US7741498B2 (en) | 2008-08-29 | 2010-06-22 | Lyondell Chemical Technology, L.P. | Propylene oxide process |
| TWI549946B (zh) * | 2009-08-05 | 2016-09-21 | 陶氏全球科技公司 | 製備環氧丙烷的方法 |
| CN102471298B (zh) | 2009-08-05 | 2014-12-31 | 陶氏环球技术有限责任公司 | 用于制备环氧烷的方法 |
| CN101665474B (zh) | 2009-09-23 | 2011-11-09 | 中昊晨光化工研究院 | 从含环氧氯丙烷的废水中回收环氧氯丙烷的方法 |
| CN201713456U (zh) | 2010-04-16 | 2011-01-19 | 南亚环氧树脂(昆山)有限公司 | 一种分离ech的装置 |
| CN101993423A (zh) | 2010-10-27 | 2011-03-30 | 中国石油化工股份有限公司 | 一种环氧氯丙烷的生产方法 |
-
2008
- 2008-08-01 EP EP08075680A patent/EP2149569A1/en not_active Withdrawn
-
2009
- 2009-07-09 RU RU2011107720/04A patent/RU2484088C2/ru active
- 2009-07-09 WO PCT/EP2009/004977 patent/WO2010012361A1/en not_active Ceased
- 2009-07-09 AU AU2009275560A patent/AU2009275560B9/en active Active
- 2009-07-09 BR BRPI0915571A patent/BRPI0915571A8/pt not_active Application Discontinuation
- 2009-07-09 KR KR1020147025998A patent/KR101475660B1/ko active Active
- 2009-07-09 EP EP09802446.6A patent/EP2324000B1/en active Active
- 2009-07-09 US US13/056,793 patent/US8729282B2/en active Active
- 2009-07-09 KR KR1020117004737A patent/KR101475559B1/ko active Active
- 2009-07-09 CN CN2009801301855A patent/CN102112456A/zh active Pending
- 2009-07-09 CN CN201410155576.5A patent/CN103923038A/zh active Pending
- 2009-07-09 JP JP2011520347A patent/JP5709172B2/ja active Active
-
2014
- 2014-03-24 US US14/223,794 patent/US9199951B2/en active Active
- 2014-07-03 JP JP2014137741A patent/JP5855175B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR101475559B1 (ko) | 2014-12-22 |
| WO2010012361A1 (en) | 2010-02-04 |
| US20140296545A1 (en) | 2014-10-02 |
| US8729282B2 (en) | 2014-05-20 |
| US20110137054A1 (en) | 2011-06-09 |
| KR20140127330A (ko) | 2014-11-03 |
| US9199951B2 (en) | 2015-12-01 |
| JP5709172B2 (ja) | 2015-04-30 |
| EP2324000B1 (en) | 2015-10-28 |
| RU2484088C2 (ru) | 2013-06-10 |
| CN103923038A (zh) | 2014-07-16 |
| AU2009275560A1 (en) | 2010-02-04 |
| JP5855175B2 (ja) | 2016-02-09 |
| AU2009275560B2 (en) | 2012-12-06 |
| BRPI0915571A2 (pt) | 2017-06-27 |
| AU2009275560B9 (en) | 2013-01-17 |
| KR20110038154A (ko) | 2011-04-13 |
| EP2324000A1 (en) | 2011-05-25 |
| KR101475660B1 (ko) | 2014-12-22 |
| CN102112456A (zh) | 2011-06-29 |
| EP2149569A1 (en) | 2010-02-03 |
| RU2011107720A (ru) | 2012-09-10 |
| JP2011529862A (ja) | 2011-12-15 |
| JP2014224122A (ja) | 2014-12-04 |
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