BRPI1004843A2 - sistema catalisador para a produÇço de biodiesel - Google Patents

sistema catalisador para a produÇço de biodiesel Download PDF

Info

Publication number: BRPI1004843A2
Authority: BR; Brazil
Prior art keywords: transesterification; acid; catalyst; catalyst system; employed
Prior art date: 2010-11-23

Application number

BRPI1004843-0A

Other languages

English (en)

Portuguese (pt)

Inventor

Manfred Neumann

Original Assignee

Evonik Degussa Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2010-11-23

Filing date

2010-11-23

Publication date

2013-03-12

2010-11-23 Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh

2010-11-23 Priority to BRPI1004843-0A priority Critical patent/BRPI1004843A2/pt

2011-11-23 Priority to ARP110104359A priority patent/AR083964A1/es

2011-11-23 Priority to CO11160780A priority patent/CO6680098A1/es

2013-03-12 Publication of BRPI1004843A2 publication Critical patent/BRPI1004843A2/pt

Links

239000003054 catalyst Substances 0.000 title claims abstract description 66
239000003225 biodiesel Substances 0.000 title claims abstract description 32
238000004519 manufacturing process Methods 0.000 title abstract description 10
238000005809 transesterification reaction Methods 0.000 claims abstract description 51
239000003960 organic solvent Substances 0.000 claims abstract description 7
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
150000001340 alkali metals Chemical class 0.000 claims abstract description 6
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 6
150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 6
238000006555 catalytic reaction Methods 0.000 claims abstract description 5
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 42
238000000034 method Methods 0.000 claims description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 25
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims description 15
235000014113 dietary fatty acids Nutrition 0.000 claims description 14
229930195729 fatty acid Natural products 0.000 claims description 14
239000000194 fatty acid Substances 0.000 claims description 14
150000003626 triacylglycerols Chemical class 0.000 claims description 13
239000000203 mixture Substances 0.000 claims description 8
BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 6
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 4
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 3
QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 claims description 3
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
RPDAUEIUDPHABB-UHFFFAOYSA-N potassium ethoxide Chemical compound [K+].CC[O-] RPDAUEIUDPHABB-UHFFFAOYSA-N 0.000 claims 2
229960004592 isopropanol Drugs 0.000 claims 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 22
239000002253 acid Substances 0.000 description 17
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125000004432 carbon atom Chemical group C* 0.000 description 10
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238000006243 chemical reaction Methods 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
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OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 7
125000005456 glyceride group Chemical group 0.000 description 7
235000019484 Rapeseed oil Nutrition 0.000 description 5
239000003925 fat Substances 0.000 description 5
235000019197 fats Nutrition 0.000 description 5
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238000005191 phase separation Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
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DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 2
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125000005907 alkyl ester group Chemical group 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
KHAVLLBUVKBTBG-UHFFFAOYSA-N dec-9-enoic acid Chemical compound OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 2
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IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
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239000007788 liquid Substances 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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239000007858 starting material Substances 0.000 description 2
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AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
239000008169 grapeseed oil Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
239000010460 hemp oil Substances 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
229960004488 linolenic acid Drugs 0.000 description 1
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229960002446 octanoic acid Drugs 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
235000015277 pork Nutrition 0.000 description 1
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 1
235000020236 pumpkin seed Nutrition 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000008159 sesame oil Substances 0.000 description 1
235000011803 sesame oil Nutrition 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
SUBJHSREKVAVAR-UHFFFAOYSA-N sodium;methanol;methanolate Chemical compound [Na+].OC.[O-]C SUBJHSREKVAVAR-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
DPUOLQHDNGRHBS-MDZDMXLPSA-N trans-Brassidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-MDZDMXLPSA-N 0.000 description 1
229940121343 tricaprilin Drugs 0.000 description 1
VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
229940117972 triolein Drugs 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
239000010497 wheat germ oil Substances 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

Fats And Perfumes (AREA)
Catalysts (AREA)

BRPI1004843-0A 2010-11-23 2010-11-23 sistema catalisador para a produÇço de biodiesel BRPI1004843A2 (pt)

Priority Applications (3)

Application Number	Priority Date	Filing Date	Title
BRPI1004843-0A BRPI1004843A2 (pt)	2010-11-23	2010-11-23	sistema catalisador para a produÇço de biodiesel
ARP110104359A AR083964A1 (es)	2010-11-23	2011-11-23	Sistema catalizador para la preparacion de biodiesel
CO11160780A CO6680098A1 (es)	2010-11-23	2011-11-23	Sistema catalizador para la producción de biodiesel

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
BRPI1004843-0A BRPI1004843A2 (pt)	2010-11-23	2010-11-23	sistema catalisador para a produÇço de biodiesel

Publications (1)

Publication Number	Publication Date
BRPI1004843A2 true BRPI1004843A2 (pt)	2013-03-12

Family

ID=47831289

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI1004843-0A BRPI1004843A2 (pt)	2010-11-23	2010-11-23	sistema catalisador para a produÇço de biodiesel

Country Status (3)

Country	Link
AR (1)	AR083964A1 (es)
BR (1)	BRPI1004843A2 (es)
CO (1)	CO6680098A1 (es)

2010
- 2010-11-23 BR BRPI1004843-0A patent/BRPI1004843A2/pt not_active IP Right Cessation
2011
- 2011-11-23 AR ARP110104359A patent/AR083964A1/es unknown
- 2011-11-23 CO CO11160780A patent/CO6680098A1/es unknown

Also Published As

Publication number	Publication date
CO6680098A1 (es)	2013-05-31
AR083964A1 (es)	2013-04-10

Legal Events

Date	Code	Title	Description
2013-03-12	B03A	Publication of an application: publication of a patent application or of a certificate of addition of invention
2016-09-27	B08F	Application fees: dismissal - article 86 of industrial property law	Free format text: REFERENTE A 6A ANUIDADE.
2017-01-17	B08K	Lapse as no evidence of payment of the annual fee has been furnished to inpi (acc. art. 87)	Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2386 DE 27-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.

Publication	Publication Date	Title
BRPI1104603A2 (pt)	2015-03-31	Sistemas de catalisador para a fabricação de biodiesel
Fereidooni et al.	2018	Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH
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Shahbaz et al.	2011	Eutectic solvents for the removal of residual palm oil-based biodiesel catalyst
Uprety et al.	2016	Biodiesel production using heterogeneous catalysts including wood ash and the importance of enhancing byproduct glycerol purity
Jagadale et al.	2012	Review of various reaction parameters and other factors affecting on production of chicken fat based biodiesel
Nakpong et al.	2010	Optimization of biodiesel production from Jatropha curcas L. oil via alkali-catalyzed methanolysis
Biktashev et al.	2011	Transesterification of rapeseed and palm oils in supercritical methanol and ethanol
BRPI0418062B1 (pt)	2016-06-28	processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico
BRPI0714716B1 (pt)	2017-03-14	método para produção de um combustível ou um solvente a partir de uma fonte de ácido graxo
Rengasamy et al.	2014	Biodiesel production from Pongamia pinnata oil using synthesized iron nanocatalyst
KR20090125248A (ko)	2009-12-04	변형된 구조의 트리글리세리드에 기반한 연료 또는 연료 첨가물의 용도 및 그 제조 방법
Olutoye et al.	2011	Synthesis of fatty acid methyl ester from crude jatropha (Jatropha curcas Linnaeus) oil using aluminium oxide modified Mg–Zn heterogeneous catalyst
BRPI1010343A2 (pt)	2012-12-18	processo de produção de biodiesel integrado
ES2926282T3 (es)	2022-10-25	Método de producción de biodiésel
BR102012017990A2 (pt)	2013-07-30	gliceratos de metais alcalinos e alcalino-terrosos para desacidificaÇço e secagem de Ésteres de Ácido graxo
ES2524461T3 (es)	2014-12-09	Procedimiento para la preparación de biodiésel mediante transesterificación ácida así como el uso de un ácido sulfónico como catalizador en la preparación de biodiesel
Dieng et al.	2019	Production and characterization of biodiesel from rapeseed oil through optimization of transesterification reaction conditions
Ejigu et al.	2010	Moringa stenopetala seed oil as a potential feedstock for biodiesel production in Ethiopia
Sanchez et al.	2013	Optimization of biodiesel production process using sunflower oil and tetramethyl ammonium hydroxide as catalyst
WO2007025360A2 (en)	2007-03-08	Catalytic process for the transesterification of vegetable oils and fats using basic solid catalizers
García et al.	2011	Methanolysis and ethanolysis of animal fats: a comparative study of the influence of alcohols
Patni et al.	2013	Use of Sunflower and Cottonseed Oil to prepare Biodiesel by catalyst assisted Transesterification
JP2008260819A (ja)	2008-10-30	バイオディーゼル燃料の製造方法
Ilham	2009	Analysis of parameters for fatty acid methyl esters production from refined palm oil for use as biodiesel in the single-and two-stage processes