BRPI1015095A2 - composição, processos para preparar uma composição e um material de poli-isocianurato , e, material de poli-isocianurato - Google Patents

composição, processos para preparar uma composição e um material de poli-isocianurato , e, material de poli-isocianurato

Info

Publication number
BRPI1015095A2
BRPI1015095A2 BRPI1015095A BRPI1015095A BRPI1015095A2 BR PI1015095 A2 BRPI1015095 A2 BR PI1015095A2 BR PI1015095 A BRPI1015095 A BR PI1015095A BR PI1015095 A BRPI1015095 A BR PI1015095A BR PI1015095 A2 BRPI1015095 A2 BR PI1015095A2
Authority
BR
Brazil
Prior art keywords
composition
polyisocyanurate material
preparing
processes
polyisocyanurate
Prior art date
Application number
BRPI1015095A
Other languages
English (en)
Inventor
Christiaan Debien
Christian Esbelin
Hans Verbeke
Original Assignee
Hunstman Internat Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunstman Internat Llc filed Critical Hunstman Internat Llc
Publication of BRPI1015095A2 publication Critical patent/BRPI1015095A2/pt
Publication of BRPI1015095B1 publication Critical patent/BRPI1015095B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/003—Polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/285—Nitrogen containing compounds
    • C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4045—Mixtures of compounds of group C08G18/58 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4028—Isocyanates; Thioisocyanates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
BRPI1015095-1A 2009-04-21 2010-04-06 Composição, processos para preparar uma composição e um material de poli-isocianurato , e, material de poli-isocianurato BRPI1015095B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09158307 2009-04-21
EP09158307.0 2009-04-21
PCT/EP2010/054492 WO2010121898A1 (en) 2009-04-21 2010-04-06 Polyisocyanate composition

Publications (2)

Publication Number Publication Date
BRPI1015095A2 true BRPI1015095A2 (pt) 2016-05-03
BRPI1015095B1 BRPI1015095B1 (pt) 2019-09-17

Family

ID=40941571

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI1015095-1A BRPI1015095B1 (pt) 2009-04-21 2010-04-06 Composição, processos para preparar uma composição e um material de poli-isocianurato , e, material de poli-isocianurato

Country Status (10)

Country Link
US (1) US9018333B2 (pt)
EP (1) EP2421906B1 (pt)
JP (1) JP5410595B2 (pt)
KR (1) KR101718174B1 (pt)
CN (1) CN102405244B (pt)
BR (1) BRPI1015095B1 (pt)
CA (1) CA2755856C (pt)
PL (1) PL2421906T3 (pt)
RU (1) RU2490284C2 (pt)
WO (1) WO2010121898A1 (pt)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014503668A (ja) * 2011-01-31 2014-02-13 ハンツマン・インターナショナル・エルエルシー エポキシ樹脂組成物
JP2014533751A (ja) * 2011-11-22 2014-12-15 ハンツマン・インターナショナル・エルエルシー エポキシ樹脂を含む硬化性ポリイソシアネート組成物
CA2857613C (en) * 2011-12-28 2016-07-12 Huntsman International Llc Curable composition comprising a polyisocyanate composition
EP2644270A1 (en) * 2012-03-29 2013-10-02 Huntsman International Llc Polyisocyanate trimerization catalyst composition
EP2687551A1 (en) * 2012-07-17 2014-01-22 Huntsman International Llc Intermediate polyisocyanurate comprising materials
EP2805976A1 (en) 2013-05-24 2014-11-26 Huntsman International Llc Aldehyde comprising compositions suitable for making curable polyisocyanate compositions
EP2808353A1 (en) * 2013-05-31 2014-12-03 Huntsman International Llc A method for improving toughness of polyisocyanate polyaddition reaction products
DK3074445T3 (da) 2013-11-29 2021-03-29 Basf Se Polyurethansystem med lang forarbejdningsstid og hurtig hærdning
EP2993195A1 (en) 2014-09-05 2016-03-09 Huntsman International Llc A method for improving fracture toughness of polyisocyanurate comprising reaction products
US10781353B2 (en) 2015-05-27 2020-09-22 Basf Se Use of a composition for stabilizing a geological formation in oil fields, gas fields, water pumping fields, mining or tunnel constructions
JP6869191B2 (ja) 2015-05-28 2021-05-12 ビーエイエスエフ・ソシエタス・エウロパエアBasf Se 優れた機械的特性を含むポリウレタン−ポリイソシアヌレート化合物
US10640618B2 (en) 2015-05-29 2020-05-05 Basf Se Polyurethane-polyisocyanurate resins for fiber composite materials with a longer open time
CN107787338B (zh) * 2015-06-18 2021-04-20 亨茨曼国际有限公司 聚氨酯催化剂的原位形成
MX2018001547A (es) 2015-08-07 2018-05-02 Huntsman Int Llc Metodo para mejorar la resistencia a la fractura de productos de reaccion que comprenden de poliisocianurato.
JP6934704B2 (ja) * 2016-03-14 2021-09-15 旭化成株式会社 ポリイソシアネート組成物、塗料組成物及び塗装体の製造方法
EP3456753A1 (en) * 2017-09-15 2019-03-20 Covestro Deutschland AG Method for the production of thermplastic polyoxazolidinone polymers
WO2019068529A1 (en) * 2017-10-06 2019-04-11 Basf Se DISPERSIBLE POLYISOCYANATES IN WATER
WO2020074293A1 (en) 2018-10-09 2020-04-16 Basf Se A process for preparing a prepreg binder composition, a prepreg and use thereof
WO2020165135A1 (en) 2019-02-11 2020-08-20 Basf Se Acrylic copolymer capsule designed to open up at < 90°c for controlled release of in-situ forming pu/pir catalyst
US12162973B2 (en) 2019-03-28 2024-12-10 Basf Se Process for producing polyurethane-polyisocyanurate elastomers, sealing materials and adhesives having a long pot life
EP3750934A1 (en) * 2019-06-12 2020-12-16 Covestro Deutschland AG Method for the production of isocyanate-group terminated polyoxazolidinones
CN114206975A (zh) 2019-08-19 2022-03-18 巴斯夫欧洲公司 具有突出力学性能的聚氨酯-聚异氰脲酸酯化合物
JPWO2022102467A1 (pt) * 2020-11-16 2022-05-19

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GB1340068A (en) 1970-09-22 1973-12-05 Insituform Pipes & Structures Lining of surfaces defining passageways
US3846315A (en) * 1973-06-27 1974-11-05 Chevron Res Grease thickened with polyurea metal salts and alkaline earth metal aliphatic monocarboxylate
SU744015A1 (ru) * 1977-07-19 1980-06-30 Предприятие П/Я Г-4302 Состав дл покрытий
US4366012A (en) 1981-02-05 1982-12-28 Insituform International Inc. Impregnation process
GB8400365D0 (en) 1984-01-07 1984-02-08 Edgealpha Ltd Lining of pipelines and passageways
US4658007A (en) 1985-05-07 1987-04-14 The Dow Chemical Company Polyisocyanurate-based polyoxazolidone polymers and process for their preparation
DE3932958A1 (de) 1989-10-03 1991-04-11 Bayer Ag Verfahren zur herstellung licht- und abgasbestaendiger puh-elastomerfaeden und -folien und elastomerfaeden entsprechender zusammensetzung
IT1252690B (it) * 1991-11-26 1995-06-23 Donegani Guido Ist Composizioni reattive liquide comprendenti poliisocianati, epossidi e soluzioni di alogenuri di metalli alcalini in composti poliossialchilenici
DE69318369T2 (de) * 1992-10-22 1999-01-28 Ajinomoto Co., Inc., Tokio/Tokyo Polythiol-Epoxidharz-Mischung mit längerer Verarbeitungszeit
DE19548770A1 (de) * 1995-12-23 1997-06-26 Basf Ag Mikrozelluläres, harnstoffgruppenhaltiges Polyurethanelastomer
DE10039837C2 (de) * 2000-08-16 2003-03-20 Byk Chemie Gmbh Verfahren zur Herstellung einer lagerstabilen, rheologisch wirksamen Harnstoffurethan-Lösung mit breiter Verträglichkeit
US6399698B1 (en) * 2000-10-26 2002-06-04 Pittsburg State University Process for the synthesis of epoxidized natural oil-based isocyanate prepolymers for application in polyurethanes
DE10150737A1 (de) * 2001-10-15 2003-04-30 Hilti Ag Mehrkomponenten-Ortschaumsystem und dessen Verwendung
JP2003261818A (ja) * 2002-03-12 2003-09-19 Kansai Paint Co Ltd 高固形分塗料組成物
UA68225C2 (en) * 2003-11-21 2006-11-15 Roman Oleksandrovy Veselovskyi Polyisocyanate composition for concrete impregnation and method for concrete impregnation
US7473738B2 (en) * 2004-09-30 2009-01-06 Johnson & Johnson Vision Care, Inc. Lactam polymer derivatives
RU2434027C2 (ru) 2006-02-21 2011-11-20 Хантсмэн Интернэшнл Ллс Способ производства полиизоциануратного композиционного материала
CA2640381A1 (en) * 2006-03-14 2007-09-20 Huntsman International Llc Composition made from a diisocyanate and a monoamine and process for preparing it
DE102008029858A1 (de) * 2008-04-23 2009-10-29 Byk-Chemie Gmbh Stabile Dispersionen von anorganischen Nanopartikeln

Also Published As

Publication number Publication date
PL2421906T3 (pl) 2017-08-31
WO2010121898A1 (en) 2010-10-28
BRPI1015095B1 (pt) 2019-09-17
US20120046436A1 (en) 2012-02-23
EP2421906A1 (en) 2012-02-29
CN102405244B (zh) 2016-10-05
RU2490284C2 (ru) 2013-08-20
US9018333B2 (en) 2015-04-28
EP2421906B1 (en) 2017-01-25
RU2011147117A (ru) 2013-05-27
CA2755856A1 (en) 2010-10-28
CN102405244A (zh) 2012-04-04
JP2012524824A (ja) 2012-10-18
KR20120017023A (ko) 2012-02-27
KR101718174B1 (ko) 2017-03-20
CA2755856C (en) 2013-07-02
JP5410595B2 (ja) 2014-02-05

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/04/2010, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/04/2010, OBSERVADAS AS CONDICOES LEGAIS

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2769 DE 30-01-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.