CA1031369A - Isomerisation catalytique de methyl-2-butenenitrile-3 en pentenenitrile lineaire - Google Patents

Isomerisation catalytique de methyl-2-butenenitrile-3 en pentenenitrile lineaire

Info

Publication number: CA1031369A
Authority: CA; Canada
Prior art keywords: butenenitrile; methyl; catalytic isomerization; linear pentenenitrile; pentenenitrile
Prior art date: 1973-09-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA209,960A

Other languages

English (en)

Other versions

CA209960S (en

Inventor

William C. Seidel

Yuan-Tsan Chia

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-09-26

Filing date

1974-09-24

Publication date

1978-05-16

1974-09-24 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1978-05-16 Application granted granted Critical

1978-05-16 Publication of CA1031369A publication Critical patent/CA1031369A/fr

Status Expired legal-status Critical Current

Links

WBAXCOMEMKANRN-UHFFFAOYSA-N 2-methylbut-3-enenitrile Chemical compound C=CC(C)C#N WBAXCOMEMKANRN-UHFFFAOYSA-N 0.000 title 1
230000003197 catalytic effect Effects 0.000 title 1
238000006317 isomerization reaction Methods 0.000 title 1
ISBHMJZRKAFTGE-UHFFFAOYSA-N pent-2-enenitrile Chemical compound CCC=CC#N ISBHMJZRKAFTGE-UHFFFAOYSA-N 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

CA209,960A 1973-09-26 1974-09-24 Isomerisation catalytique de methyl-2-butenenitrile-3 en pentenenitrile lineaire Expired CA1031369A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US00401073A US3852328A (en)	1973-09-26	1973-09-26	Catalytic isomerization of 2-methyl-3-butenenitrile to a linear pentenenitrile

Publications (1)

Publication Number	Publication Date
CA1031369A true CA1031369A (fr)	1978-05-16

Family

ID=23586171

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA209,960A Expired CA1031369A (fr)	1973-09-26	1974-09-24	Isomerisation catalytique de methyl-2-butenenitrile-3 en pentenenitrile lineaire

Country Status (9)

Country	Link
US (1)	US3852328A (fr)
JP (1)	JPS5821910B2 (fr)
BE (1)	BE820307A (fr)
CA (1)	CA1031369A (fr)
DE (1)	DE2445680C2 (fr)
FR (1)	FR2244754B1 (fr)
GB (1)	GB1432716A (fr)
IT (1)	IT1022319B (fr)
NL (1)	NL7412666A (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3852329A (en) *	1973-10-02	1974-12-03	Du Pont	Process for isomerization of 2-methyl-3-butene-nitrile to a linear pentenenitrile
EP0001506A1 (fr) *	1977-10-11	1979-04-18	Imperial Chemical Industries Plc	Procédé de production de nitriles organiques
JPS55501178A (fr) *	1979-02-12	1980-12-25
US4298546A (en) *	1980-08-05	1981-11-03	E. I. Du Pont De Nemours And Company	Isomerization of 2-methyl-3-butenenitrile
JPH0515752A (ja) *	1991-07-10	1993-01-26	Ikebukuro Horo Kogyo Kk	気液撹拌方法
DE69412635T2 (de) *	1993-11-23	1999-04-15	E.I. Du Pont De Nemours And Co., Wilmington, Del.	Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefine
ATE196745T1 (de)	1994-04-14	2000-10-15	Du Pont	Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen
US5512696A (en) *	1995-07-21	1996-04-30	E. I. Du Pont De Nemours And Company	Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
TW315370B (fr) *	1994-10-07	1997-09-11	Du Pont
US5440067A (en) *	1994-11-18	1995-08-08	E. I. Dupont De Nemours And Company	Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US5821378A (en) *	1995-01-27	1998-10-13	E. I. Du Pont De Nemours And Company	Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (fr) *	1995-01-27	2002-01-05	Du Pont
DE19953058A1 (de) *	1999-11-03	2001-05-10	Basf Ag	Phosphite
FR2850966B1 (fr)	2003-02-10	2005-03-18	Rhodia Polyamide Intermediates	Procede de fabrication de composes dinitriles
FR2854892B1 (fr)	2003-05-12	2005-06-24	Rhodia Polyamide Intermediates	Procede de fabrication de dinitriles
FR2854891B1 (fr)	2003-05-12	2006-07-07	Rhodia Polyamide Intermediates	Procede de preparation de dinitriles
CA2644961A1 (fr)	2006-03-17	2007-09-27	Invista Technologies S.A.R.L.	Procede pour purifier des triorganophosphites grace au traitement a l'aide d'un adjuvant basique
US7709674B2 (en)	2006-07-14	2010-05-04	Invista North America S.A R.L	Hydrocyanation process with reduced yield losses

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3536748A (en) *	1965-11-23	1970-10-27	Du Pont	Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
GB1210969A (en) *	1967-10-26	1970-11-04	Du Pont	Isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
NL7002580A (fr) *	1969-03-03	1970-09-07
NL7017965A (fr) *	1969-12-17	1971-06-21
US3676481A (en) *	1970-06-29	1972-07-11	Du Pont	Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles in the presence of certain metal salt and/or tri(hydrocarbyl)boron promoters

1973
- 1973-09-26 US US00401073A patent/US3852328A/en not_active Expired - Lifetime
1974
- 1974-09-24 CA CA209,960A patent/CA1031369A/fr not_active Expired
- 1974-09-25 GB GB4170374A patent/GB1432716A/en not_active Expired
- 1974-09-25 DE DE2445680A patent/DE2445680C2/de not_active Expired
- 1974-09-25 BE BE148861A patent/BE820307A/fr not_active IP Right Cessation
- 1974-09-25 FR FR7432325A patent/FR2244754B1/fr not_active Expired
- 1974-09-25 JP JP49109628A patent/JPS5821910B2/ja not_active Expired
- 1974-09-25 NL NL7412666A patent/NL7412666A/xx not_active Application Discontinuation
- 1974-09-25 IT IT27714/74A patent/IT1022319B/it active

Also Published As

Publication number	Publication date
FR2244754B1 (fr)	1979-02-02
FR2244754A1 (fr)	1975-04-18
BE820307A (fr)	1975-03-25
JPS5821910B2 (ja)	1983-05-04
DE2445680C2 (de)	1985-09-19
NL7412666A (nl)	1975-04-01
JPS5059325A (fr)	1975-05-22
GB1432716A (en)	1976-04-22
IT1022319B (it)	1978-03-20
US3852328A (en)	1974-12-03
DE2445680A1 (de)	1975-03-27

Publication	Publication Date	Title
CA1021350A (en)	1977-11-22	Selective isomerization of pentenenitriles
CA1031370A (fr)	1978-05-16	Procede pour l'isomerisation de methyl-2 butenenitrile-3 en pentenenitrile lineaire
CA1005818A (en)	1977-02-22	Dehydrogenation catalyst
CA1014461A (en)	1977-07-26	Multi-bed reactors
CA955957A (en)	1974-10-08	Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
CA1028682A (fr)	1978-03-28	Catalyseur
BE820307A (fr)	1975-03-25	Isomerisation catalytique du 2-methyl-3-butenenitrile en pentenenitrile lineaire
IL44167A (en)	1979-09-30	Chiral copper-complex catalyst
CA1031371A (fr)	1978-05-16	Isomerisation cis/trans selective de pentenenitrile-2 dans une solution d'isomeres de pentenenitrile
AU6828174A (en)	1975-10-30	Catalyst
CA1027117A (fr)	1978-02-28	Reduction catalytique homogene des 6-methylenetetracyclines
CA1003228A (en)	1977-01-11	Catalytic element for catalytic converter
CA1030561A (fr)	1978-05-02	Additif utilise avec un catalyseur d'alkylation
PH12560A (en)	1979-06-15	Fluidisable catalytic charge
CA1015534A (en)	1977-08-16	Catalytic reactors
CA1012370A (en)	1977-06-21	Catalytic converter housing
AU7130374A (en)	1976-01-22	Catalyst
AU6903974A (en)	1975-11-20	Isomerization catalyst
CA1018995A (en)	1977-10-11	Catalyst for ammoxidation
AU484736B2 (en)	1975-07-17	Improvements relating to catalytic reactors
CA1027588A (fr)	1978-03-07	Additif d'alcoylation incorpore a un catalyseur
CA955956A (en)	1974-10-08	Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
AU471842B2 (en)	1975-03-06	Catalyst carrier
CA1020150A (en)	1977-11-01	Catalysts
CA1030944A (fr)	1978-05-09	Catalyseur au nickel